FR3019827B1 - Composition et procede pour materiau composite avec impregnation par polyamide semi-cristallin, issu d'un prepolymere et d'un allongeur de chaine - Google Patents

Composition et procede pour materiau composite avec impregnation par polyamide semi-cristallin, issu d'un prepolymere et d'un allongeur de chaine Download PDF

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Publication number
FR3019827B1
FR3019827B1 FR1453349A FR1453349A FR3019827B1 FR 3019827 B1 FR3019827 B1 FR 3019827B1 FR 1453349 A FR1453349 A FR 1453349A FR 1453349 A FR1453349 A FR 1453349A FR 3019827 B1 FR3019827 B1 FR 3019827B1
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FR
France
Prior art keywords
composite material
composition
prepolymer
semi
polyamide
Prior art date
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Active
Application number
FR1453349A
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English (en)
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FR3019827A1 (fr
Inventor
Gilles Hochstetter
Thierry Briffaud
Mathieu Capelot
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Arkema France SA
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Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1453349A priority Critical patent/FR3019827B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to PCT/FR2015/051017 priority patent/WO2015159020A1/fr
Priority to US15/304,676 priority patent/US20170037199A1/en
Priority to JP2016562821A priority patent/JP2017511419A/ja
Priority to EP15725735.3A priority patent/EP3131948A1/fr
Priority to CN201580020088.6A priority patent/CN106232676A/zh
Priority to KR1020167031719A priority patent/KR20160147822A/ko
Publication of FR3019827A1 publication Critical patent/FR3019827A1/fr
Application granted granted Critical
Publication of FR3019827B1 publication Critical patent/FR3019827B1/fr
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/48—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52—Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/28—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/44—Polyester-amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/48—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/12—Polyester-amides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/06—Polyamides derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/12—Polyester-amides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Reinforced Plastic Materials (AREA)
  • Polyamides (AREA)

Abstract

L'invention concerne une composition de moulage en particulier pour matériau composite thermoplastique, comprenant au moins un polyamide semi-cristallin, polymère issu de la polyaddition de a) au moins un prépolymère polyamide ayant n fonctions identiques X parmi carboxy, amine, hydroxyle et de b) au moins un allongeur réactif non polymérique porteur de deux fonctions Y identiques réactives avec lesdites fonctions X avec n allant de 1 à 3, polymère et prépolymère a) étant de composition spécifique comprenant au moins deux motifs amides A de 55-95% mol et B de 5-45% mol avec A correspondant à x.T où x est une diamine aliphatique linéaire en C9-C18 et B correspondant à x'.T ou x' peut être B1) : diamine aliphatique ramifiée spécifique dépendant de x ou B2) : MXD ou B3) : diamine aliphatique linéaire qui dépend de x, ledit polyamide ayant une Tg d'au moins 90°C et une Tf inférieure ou égale à 280°C. L'invention couvre également un procédé de fabrication dudit matériau composite, l'utilisation de la composition de l'invention pour des pièces de matériau composite ainsi que lesdites pièces.
FR1453349A 2014-04-15 2014-04-15 Composition et procede pour materiau composite avec impregnation par polyamide semi-cristallin, issu d'un prepolymere et d'un allongeur de chaine Active FR3019827B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1453349A FR3019827B1 (fr) 2014-04-15 2014-04-15 Composition et procede pour materiau composite avec impregnation par polyamide semi-cristallin, issu d'un prepolymere et d'un allongeur de chaine
US15/304,676 US20170037199A1 (en) 2014-04-15 2015-04-15 Composition and method for composite material impregnated with semi-crystalline polyamide, obtained from a prepolymer and a chain extender
JP2016562821A JP2017511419A (ja) 2014-04-15 2015-04-15 プレポリマーおよび鎖延長剤から得た半結晶性ポリアミドに含浸される複合材料のための組成物および方法
EP15725735.3A EP3131948A1 (fr) 2014-04-15 2015-04-15 Composition et procédé pour matériau composite avec imprégnation par polyamide semi-cristallin, issu d'un prepolymere et d'un allongeur de chaîne
PCT/FR2015/051017 WO2015159020A1 (fr) 2014-04-15 2015-04-15 Composition et procédé pour matériau composite avec imprégnation par polyamide semi-cristallin, issu d'un prepolymere et d'un allongeur de chaîne
CN201580020088.6A CN106232676A (zh) 2014-04-15 2015-04-15 用于浸渍有由预聚物和扩链剂获得的半结晶聚酰胺的复合材料的成分和方法
KR1020167031719A KR20160147822A (ko) 2014-04-15 2015-04-15 예비중합체 및 사슬 연장제로부터 수득된 반-결정질 폴리아미드로 함침된 복합 재료를 위한 조성물 및 방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1453349A FR3019827B1 (fr) 2014-04-15 2014-04-15 Composition et procede pour materiau composite avec impregnation par polyamide semi-cristallin, issu d'un prepolymere et d'un allongeur de chaine

Publications (2)

Publication Number Publication Date
FR3019827A1 FR3019827A1 (fr) 2015-10-16
FR3019827B1 true FR3019827B1 (fr) 2020-10-09

Family

ID=51225706

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1453349A Active FR3019827B1 (fr) 2014-04-15 2014-04-15 Composition et procede pour materiau composite avec impregnation par polyamide semi-cristallin, issu d'un prepolymere et d'un allongeur de chaine

Country Status (7)

Country Link
US (1) US20170037199A1 (fr)
EP (1) EP3131948A1 (fr)
JP (1) JP2017511419A (fr)
KR (1) KR20160147822A (fr)
CN (1) CN106232676A (fr)
FR (1) FR3019827B1 (fr)
WO (1) WO2015159020A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2997089B1 (fr) 2012-10-23 2015-11-13 Arkema France Materiau composite thermoplastique a base de polyamide semi-cristallin et procede de fabrication
FR3019824B1 (fr) 2014-04-15 2017-10-13 Arkema France Procede pour materiau composite avec impregnation par polymere thermoplastique, issu d'un prepolymere et d'un allongeur de chaine
FR3019826B1 (fr) 2014-04-15 2017-10-20 Arkema France Composition thermoplastique a base de polyamide polymere issu d'un prepolymere et d'un allongeur de chaine et procede de fabrication
FR3019822B1 (fr) 2014-04-15 2017-10-20 Arkema France Procede de fabrication d'un materiau thermoplastique a base de polyamide semi-cristallin
FR3044956B1 (fr) * 2015-12-10 2018-06-15 Arkema France Procede pour un materiau composite de matrice en polyamide, renforce fibres, a partir de composition precurseur reactive de prepolymere
CN111057233B (zh) * 2019-12-29 2023-05-05 无锡殷达尼龙有限公司 一种共聚半芳香族聚酰胺及其制备方法
CN115594967B (zh) * 2022-10-27 2024-03-26 北京化工大学 一种长碳链聚酰胺发泡材料及其制备方法

Family Cites Families (17)

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Publication number Priority date Publication date Assignee Title
FR2603891B1 (fr) 1986-09-17 1990-12-14 Atochem Procede de fabrication de materiau composite a base de polyamide renforcee de fibres longues
FR2653436A1 (fr) 1989-10-24 1991-04-26 Atochem Copolyesters aromatiques thermotropes et leur procede de preparation.
FR2685700B1 (fr) 1991-12-31 1995-02-24 Atochem Nouveaux polyamides et objets obtenus a partir de ceux-ci.
FR2694008B1 (fr) 1992-07-24 1994-10-21 Atochem Elf Sa Polymères et copolymères issus de l'addition d'oligomères à terminaisons di-amino et di-hydroxy et de bisoxazinones ou de bisoxazolinones, et leur procédé d'obtention.
FR2694009B1 (fr) 1992-07-24 1994-10-21 Atochem Elf Sa Polymères et copolymères issus de l'addition d'oligomères à terminaisons di-carboxy et de bisoxazines ou bisoxazolines, et leur procédé d'obtention.
FR2733757B1 (fr) 1995-04-27 1997-06-20 Atochem Elf Sa Polymeres et copolymeres issus de l'addition d'oligomeres a terminaisons di-carboxy et de bisimidazolines, et leur procede d'obtention
KR100862438B1 (ko) * 2006-10-09 2008-10-08 현대자동차주식회사 블록킹된 디이소시아네이트 유도체를 쇄연장제로 사용하여폐 나일론의 분자량을 증가시키는 방법
DE502008000140D1 (de) 2007-05-03 2009-11-26 Ems Patent Ag Teilaromatische Polyamidformmassen und deren Verwendungen
JP5369676B2 (ja) * 2008-12-26 2013-12-18 東レ株式会社 ポリアミド樹脂
DE102009027611A1 (de) 2009-07-10 2011-01-13 Evonik Degussa Gmbh Formmasse auf Basis eines Terephthalsäure- sowie Trimethylhexamethylendiamin-Einheit enthaltenden Copolyamids
CN102234373A (zh) * 2010-04-30 2011-11-09 北京化工大学 扩链制备可生物降解聚酯酰胺的方法
EP2386397B2 (fr) * 2010-05-11 2020-04-29 Basf Se Procédé de pultrusion
US20110306718A1 (en) 2010-05-11 2011-12-15 Basf Se Pultrusion process
KR101279978B1 (ko) * 2010-10-18 2013-07-05 제일모직주식회사 폴리아미드 수지
FR2981653B1 (fr) * 2011-10-25 2014-08-22 Arkema France Materiau composite thermoplastique renforce de fibres synthetiques et procede de fabrication
FR2991331B1 (fr) * 2012-06-01 2015-05-15 Arkema France Materiau composite thermoplastique a base de fibres naturelles
FR2997089B1 (fr) * 2012-10-23 2015-11-13 Arkema France Materiau composite thermoplastique a base de polyamide semi-cristallin et procede de fabrication

Also Published As

Publication number Publication date
WO2015159020A1 (fr) 2015-10-22
US20170037199A1 (en) 2017-02-09
FR3019827A1 (fr) 2015-10-16
EP3131948A1 (fr) 2017-02-22
CN106232676A (zh) 2016-12-14
JP2017511419A (ja) 2017-04-20
KR20160147822A (ko) 2016-12-23

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