FR2445310A1 - Catalyseur et procede de production de l'acide methacrylique par oxydation de la methacroleine en phase vapeur - Google Patents
Catalyseur et procede de production de l'acide methacrylique par oxydation de la methacroleine en phase vapeurInfo
- Publication number
- FR2445310A1 FR2445310A1 FR7931595A FR7931595A FR2445310A1 FR 2445310 A1 FR2445310 A1 FR 2445310A1 FR 7931595 A FR7931595 A FR 7931595A FR 7931595 A FR7931595 A FR 7931595A FR 2445310 A1 FR2445310 A1 FR 2445310A1
- Authority
- FR
- France
- Prior art keywords
- oxidation
- methacrylic acid
- catalyst
- methacroleine
- steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 title abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 title 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- 229910052792 caesium Inorganic materials 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 229910052702 rhenium Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 229910052701 rubidium Inorganic materials 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8878—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/885—Molybdenum and copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8871—Rare earth metals or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8872—Alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/972,743 US4252681A (en) | 1978-12-26 | 1978-12-26 | Catalyst for producing methacrylic acid |
US05/973,495 US4252683A (en) | 1978-12-26 | 1978-12-26 | Catalyst for producing methacrylic acid |
US05/972,745 US4252682A (en) | 1978-12-26 | 1978-12-26 | Catalyst for producing methacrylic acid |
US05/973,354 US4374757A (en) | 1978-12-26 | 1978-12-26 | Catalyst and process for producing methacrylic acid |
US06/027,632 US4240930A (en) | 1979-04-06 | 1979-04-06 | Catalyst and process for producing methacrylic acid |
US06/027,635 US4261860A (en) | 1979-04-06 | 1979-04-06 | Catalyst for producing methacrylic acid |
US06/027,634 US4261859A (en) | 1979-04-06 | 1979-04-06 | Catalyst for producing methacrylic acid |
US06/027,633 US4261858A (en) | 1979-04-06 | 1979-04-06 | Catalyst for producing methacrylic acid |
US06/047,860 US4377501A (en) | 1978-12-26 | 1979-06-12 | Catalyst and process for producing methacrylic acid |
US06/081,406 US4271040A (en) | 1978-12-26 | 1979-10-03 | Catalyst and process for producing methacrylic acid |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2445310A1 true FR2445310A1 (fr) | 1980-07-25 |
FR2445310B1 FR2445310B1 (it) | 1984-05-25 |
Family
ID=27580733
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7931595A Granted FR2445310A1 (fr) | 1978-12-26 | 1979-12-24 | Catalyseur et procede de production de l'acide methacrylique par oxydation de la methacroleine en phase vapeur |
Country Status (7)
Country | Link |
---|---|
BR (1) | BR7908476A (it) |
DE (1) | DE2952455C2 (it) |
FR (1) | FR2445310A1 (it) |
GB (3) | GB2040717B (it) |
IT (1) | IT1164100B (it) |
MX (1) | MX154396A (it) |
NL (1) | NL7909142A (it) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2509722A1 (fr) * | 1981-07-17 | 1983-01-21 | Halcon Sd Group Inc | Procede d'oxydation catalytique, en phase vapeur, de la methacroleine en acide methacrylique par de l'oxygene moleculaire |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3030243A1 (de) * | 1980-08-09 | 1982-03-18 | Basf Ag, 6700 Ludwigshafen | Oxidationskatalysator insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein |
US4511548A (en) * | 1981-12-18 | 1985-04-16 | The Standard Oil Company | Ammoxidation of methanol to produce hydrogen cyanide |
DE3208571A1 (de) * | 1982-03-10 | 1983-09-22 | Basf Ag, 6700 Ludwigshafen | Oxidationskatalysator, insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein |
DE3208572A1 (de) * | 1982-03-10 | 1983-09-22 | Basf Ag, 6700 Ludwigshafen | Verfahren und katalysator zur herstellung von methacrylsaeure |
JPS59115750A (ja) * | 1982-12-22 | 1984-07-04 | Nippon Shokubai Kagaku Kogyo Co Ltd | メタクリル酸合成用触媒 |
DE19630832A1 (de) | 1996-07-31 | 1998-02-05 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2273586A1 (fr) * | 1974-06-07 | 1976-01-02 | Nippon Kayaku Kk | Catalyseur d'oxydation pour produire l'acide methacrylique |
FR2275436A1 (fr) * | 1974-05-31 | 1976-01-16 | Mitsubishi Rayon Co | Procede pour la preparation de l'acide acrylique ou de l'acide methacrylique |
FR2297082A1 (fr) * | 1975-01-13 | 1976-08-06 | Standard Oil Co | Catalyseurs d'oxydation |
FR2306188A1 (fr) * | 1975-04-03 | 1976-10-29 | Mitsubishi Rayon Co | Procede de preparation d'un acide carboxylique insature |
US4000088A (en) * | 1974-06-03 | 1976-12-28 | Nippon Kayaku Co., Ltd. | Oxidation catalyst for the manufacture of methacrylic acid |
FR2333770A1 (fr) * | 1975-12-03 | 1977-07-01 | Mitsubishi Rayon Co | Procede catalytique de fabrication d'acides carboxyliques insatures et produits obtenus par ce procede |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2460541C3 (de) * | 1973-12-29 | 1979-10-18 | Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan) | Phosphor, Molybdän und Vanadium sowie gegebenenfalls Kupfer, Kobalt, Zirkon, Wismut, Antimon und/oder Arsen enthaltender Oxydkatalysator und dessen Verwendung zur Herstellung von Methacrylsäure |
GB1489559A (en) * | 1975-03-03 | 1977-10-19 | Mitsubishi Rayon Co | Catalytic process for the preparation of acrylic acid or methacrylic acid |
-
1979
- 1979-12-19 NL NL7909142A patent/NL7909142A/nl not_active Application Discontinuation
- 1979-12-21 IT IT51168/79A patent/IT1164100B/it active
- 1979-12-21 BR BR7908476A patent/BR7908476A/pt unknown
- 1979-12-24 FR FR7931595A patent/FR2445310A1/fr active Granted
- 1979-12-24 GB GB7944392A patent/GB2040717B/en not_active Expired
- 1979-12-27 DE DE2952455A patent/DE2952455C2/de not_active Expired
-
1980
- 1980-01-02 MX MX180602A patent/MX154396A/es unknown
-
1983
- 1983-03-15 GB GB08307118A patent/GB2116063B/en not_active Expired
- 1983-03-15 GB GB08307119A patent/GB2121309B/en not_active Expired
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2275436A1 (fr) * | 1974-05-31 | 1976-01-16 | Mitsubishi Rayon Co | Procede pour la preparation de l'acide acrylique ou de l'acide methacrylique |
US4000088A (en) * | 1974-06-03 | 1976-12-28 | Nippon Kayaku Co., Ltd. | Oxidation catalyst for the manufacture of methacrylic acid |
FR2273586A1 (fr) * | 1974-06-07 | 1976-01-02 | Nippon Kayaku Kk | Catalyseur d'oxydation pour produire l'acide methacrylique |
FR2297082A1 (fr) * | 1975-01-13 | 1976-08-06 | Standard Oil Co | Catalyseurs d'oxydation |
FR2306188A1 (fr) * | 1975-04-03 | 1976-10-29 | Mitsubishi Rayon Co | Procede de preparation d'un acide carboxylique insature |
FR2333770A1 (fr) * | 1975-12-03 | 1977-07-01 | Mitsubishi Rayon Co | Procede catalytique de fabrication d'acides carboxyliques insatures et produits obtenus par ce procede |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2509722A1 (fr) * | 1981-07-17 | 1983-01-21 | Halcon Sd Group Inc | Procede d'oxydation catalytique, en phase vapeur, de la methacroleine en acide methacrylique par de l'oxygene moleculaire |
Also Published As
Publication number | Publication date |
---|---|
GB8307118D0 (en) | 1983-04-20 |
IT1164100B (it) | 1987-04-08 |
GB2040717A (en) | 1980-09-03 |
DE2952455A1 (de) | 1980-07-17 |
GB2040717B (en) | 1983-09-14 |
GB2121309B (en) | 1984-06-06 |
GB2116063B (en) | 1984-02-01 |
GB2116063A (en) | 1983-09-21 |
BR7908476A (pt) | 1980-09-23 |
GB8307119D0 (en) | 1983-04-20 |
FR2445310B1 (it) | 1984-05-25 |
GB2121309A (en) | 1983-12-21 |
DE2952455C2 (de) | 1988-07-28 |
IT7951168A0 (it) | 1979-12-21 |
MX154396A (es) | 1987-08-07 |
NL7909142A (nl) | 1980-06-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |