GB2116063B - Catalyst and process for producing methacrylic acid - Google Patents

Catalyst and process for producing methacrylic acid

Info

Publication number
GB2116063B
GB2116063B GB08307118A GB8307118A GB2116063B GB 2116063 B GB2116063 B GB 2116063B GB 08307118 A GB08307118 A GB 08307118A GB 8307118 A GB8307118 A GB 8307118A GB 2116063 B GB2116063 B GB 2116063B
Authority
GB
United Kingdom
Prior art keywords
catalyst
methacrylic acid
producing methacrylic
producing
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB08307118A
Other versions
GB8307118D0 (en
GB2116063A (en
Inventor
Sargis Khoobiar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Halcon SD Group Inc
Original Assignee
Halcon SD Group Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/973,354 external-priority patent/US4374757A/en
Priority claimed from US05/972,745 external-priority patent/US4252682A/en
Priority claimed from US05/972,743 external-priority patent/US4252681A/en
Priority claimed from US05/973,495 external-priority patent/US4252683A/en
Priority claimed from US06/027,633 external-priority patent/US4261858A/en
Priority claimed from US06/027,634 external-priority patent/US4261859A/en
Priority claimed from US06/027,632 external-priority patent/US4240930A/en
Priority claimed from US06/027,635 external-priority patent/US4261860A/en
Priority claimed from US06/047,860 external-priority patent/US4377501A/en
Priority claimed from US06/081,406 external-priority patent/US4271040A/en
Application filed by Halcon SD Group Inc filed Critical Halcon SD Group Inc
Publication of GB8307118D0 publication Critical patent/GB8307118D0/en
Publication of GB2116063A publication Critical patent/GB2116063A/en
Publication of GB2116063B publication Critical patent/GB2116063B/en
Application granted granted Critical
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/885—Molybdenum and copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
GB08307118A 1978-12-26 1983-03-15 Catalyst and process for producing methacrylic acid Expired GB2116063B (en)

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
US05/973,354 US4374757A (en) 1978-12-26 1978-12-26 Catalyst and process for producing methacrylic acid
US05/973,495 US4252683A (en) 1978-12-26 1978-12-26 Catalyst for producing methacrylic acid
US05/972,743 US4252681A (en) 1978-12-26 1978-12-26 Catalyst for producing methacrylic acid
US05/972,745 US4252682A (en) 1978-12-26 1978-12-26 Catalyst for producing methacrylic acid
US06/027,634 US4261859A (en) 1979-04-06 1979-04-06 Catalyst for producing methacrylic acid
US06/027,632 US4240930A (en) 1979-04-06 1979-04-06 Catalyst and process for producing methacrylic acid
US06/027,635 US4261860A (en) 1979-04-06 1979-04-06 Catalyst for producing methacrylic acid
US06/027,633 US4261858A (en) 1979-04-06 1979-04-06 Catalyst for producing methacrylic acid
US06/047,860 US4377501A (en) 1978-12-26 1979-06-12 Catalyst and process for producing methacrylic acid
US06/081,406 US4271040A (en) 1978-12-26 1979-10-03 Catalyst and process for producing methacrylic acid

Publications (3)

Publication Number Publication Date
GB8307118D0 GB8307118D0 (en) 1983-04-20
GB2116063A GB2116063A (en) 1983-09-21
GB2116063B true GB2116063B (en) 1984-02-01

Family

ID=27580733

Family Applications (3)

Application Number Title Priority Date Filing Date
GB7944392A Expired GB2040717B (en) 1978-12-26 1979-12-24 Catalyst and process for producing methacrylic acid
GB08307118A Expired GB2116063B (en) 1978-12-26 1983-03-15 Catalyst and process for producing methacrylic acid
GB08307119A Expired GB2121309B (en) 1978-12-26 1983-03-15 Catalyst and process for producing methacrylic acid

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB7944392A Expired GB2040717B (en) 1978-12-26 1979-12-24 Catalyst and process for producing methacrylic acid

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB08307119A Expired GB2121309B (en) 1978-12-26 1983-03-15 Catalyst and process for producing methacrylic acid

Country Status (7)

Country Link
BR (1) BR7908476A (en)
DE (1) DE2952455C2 (en)
FR (1) FR2445310A1 (en)
GB (3) GB2040717B (en)
IT (1) IT1164100B (en)
MX (1) MX154396A (en)
NL (1) NL7909142A (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3030243A1 (en) * 1980-08-09 1982-03-18 Basf Ag, 6700 Ludwigshafen OXIDATION CATALYST, IN PARTICULAR FOR THE PRODUCTION OF METHACRYLIC ACID BY GAS PHASE OXIDATION OF METHACROLEIN
NL8202791A (en) * 1981-07-17 1983-02-16 Halcon Sd Group Inc METHOD FOR PREPARING METHACRYLIC ACID.
US4511548A (en) * 1981-12-18 1985-04-16 The Standard Oil Company Ammoxidation of methanol to produce hydrogen cyanide
DE3208571A1 (en) * 1982-03-10 1983-09-22 Basf Ag, 6700 Ludwigshafen OXIDATION CATALYST, ESPECIALLY FOR THE PRODUCTION OF METHACRYLIC ACID BY GAS PHASE OXIDATION OF METHACROLEIN
DE3208572A1 (en) * 1982-03-10 1983-09-22 Basf Ag, 6700 Ludwigshafen METHOD AND CATALYST FOR PRODUCING METHACRYLIC ACID
JPS59115750A (en) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd Catalyst for synthesis of methacrylic acid
DE19630832A1 (en) * 1996-07-31 1998-02-05 Hoechst Ag Process for the selective production of acetic acid

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2460541C3 (en) * 1973-12-29 1979-10-18 Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan) Oxide catalyst containing phosphorus, molybdenum and vanadium and optionally copper, cobalt, zirconium, bismuth, antimony and / or arsenic and its use for the production of methacrylic acid
JPS5827255B2 (en) * 1974-05-31 1983-06-08 三菱レイヨン株式会社 Method for producing unsaturated fatty acids
US4000088A (en) * 1974-06-03 1976-12-28 Nippon Kayaku Co., Ltd. Oxidation catalyst for the manufacture of methacrylic acid
FR2273586A1 (en) * 1974-06-07 1976-01-02 Nippon Kayaku Kk Oxidn. catalyst for methacrolein conversion - to methacrylic acid, contg. molybdenum, phosphorus, antimony, copper and chromium
IN145044B (en) * 1975-01-13 1978-08-19 Standard Oil Co Ohio
GB1489559A (en) * 1975-03-03 1977-10-19 Mitsubishi Rayon Co Catalytic process for the preparation of acrylic acid or methacrylic acid
JPS51115414A (en) * 1975-04-03 1976-10-12 Mitsubishi Rayon Co Ltd Process for preparation of unsaturated fatty acids
US4118419A (en) * 1975-12-03 1978-10-03 Mitsubishi Rayon Company, Ltd. Catalytic process for the preparation of an unsaturated carboxylic acid

Also Published As

Publication number Publication date
DE2952455C2 (en) 1988-07-28
GB2121309B (en) 1984-06-06
FR2445310A1 (en) 1980-07-25
GB8307119D0 (en) 1983-04-20
GB8307118D0 (en) 1983-04-20
MX154396A (en) 1987-08-07
BR7908476A (en) 1980-09-23
GB2040717A (en) 1980-09-03
FR2445310B1 (en) 1984-05-25
GB2116063A (en) 1983-09-21
GB2040717B (en) 1983-09-14
IT7951168A0 (en) 1979-12-21
NL7909142A (en) 1980-06-30
DE2952455A1 (en) 1980-07-17
GB2121309A (en) 1983-12-21
IT1164100B (en) 1987-04-08

Similar Documents

Publication Publication Date Title
DE2961540D1 (en) A process for producing methacrylic acid and a catalyst
GB2041234B (en) Catalysts and process for producing methacrylic acid
GB2045635B (en) Process for producing methacrolein and methacrylic acid
GB2046252B (en) Process for producing methacrylic acid
GB2044764B (en) Process for producing acrolein and acrylic acid
GB2013610B (en) Microcapsules and process for their manufacture
GB2063861B (en) Process for producing acrylic acid
GB1545976A (en) Process for producing methacrylic acid and catalysts therefor
GB2023597B (en) Process for producing methacrolein
DE3475596D1 (en) Process and catalyst for preparing methacrylic acid
GB2010693B (en) Process for producing methacrylic acid and a catalyst
EP0088327A3 (en) Process and catalyst for the preparation of methacrylic acid
GB2038656B (en) Process for producing methacrolein
HU179804B (en) Process for producing 7-bracket-substituted-bracket closed-amino-3-substituted-thiometnyl-ceph-3-eme-4-carboxylic acids
GB2033775B (en) Catalysts and process for the production of methacrolein catalysts
YU41151B (en) Process for producing aleic acid anhydride
DE2962547D1 (en) A process for producing methacrolein and methacrylic acid
GB2001255B (en) Process for producing methacrylic acid
GB2116063B (en) Catalyst and process for producing methacrylic acid
DE3060058D1 (en) Process for producing methacrylic acid
GB1539839A (en) Process for the manufacture of methacrylic acid and a catalyst
GB2001256B (en) Process for producing methacrylic acid
GB2096601B (en) Process for producing methacrylic acid
GB2037604B (en) Process for producing methacrylic acid
GB2024201B (en) Process for producing methacrylic acid

Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19921224