FR2434823A1 - Procede de production de polymeres d'a-olefines et catalyseur pour sa mise en oeuvre - Google Patents
Procede de production de polymeres d'a-olefines et catalyseur pour sa mise en oeuvreInfo
- Publication number
- FR2434823A1 FR2434823A1 FR7921051A FR7921051A FR2434823A1 FR 2434823 A1 FR2434823 A1 FR 2434823A1 FR 7921051 A FR7921051 A FR 7921051A FR 7921051 A FR7921051 A FR 7921051A FR 2434823 A1 FR2434823 A1 FR 2434823A1
- Authority
- FR
- France
- Prior art keywords
- solid product
- catalyst
- electron
- producing
- reacting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
L'invention concerne un procédé de production de polymères d' alpha -oléfines, qui permet de régler la répartition du poids moléculaire dans une gamme plus étroite, avec un rendement plus élevé et une cristallinité meilleure des produits. L'invention concerne également un catalyseur utilisé dans ce procédé. Le constituant solide du catalyseur est obtenu en faisant réagir un halogénure d'un métal trivalent avec un hydroxyde, un oxyde, un carbonate d'un métal divalent, un composé double contenant l'un quelconque de ces composés ou un hydrate d'un composé contenant un métal divalent, afin de produire un produit solide I; en faisant réagir un ou plusieurs donneurs d'électrons et un ou plusieurs accepteurs d'électrons, séparément ou simultanément, en 1 à 10 stades, mais en utilisant TiCl4 comme accepteur d'électrons dans au moins un de ces stades, avec le produit solide I afin d'obtenir un produit solide II; puis en combinant un composé d'organo aluminium et un donneur d'électrons avec le produit solide II.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10679778A JPS5534238A (en) | 1978-08-31 | 1978-08-31 | Preparation of alpha-olefin polymer |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2434823A1 true FR2434823A1 (fr) | 1980-03-28 |
FR2434823B1 FR2434823B1 (fr) | 1985-05-10 |
Family
ID=14442867
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7921051A Granted FR2434823A1 (fr) | 1978-08-31 | 1979-08-21 | Procede de production de polymeres d'a-olefines et catalyseur pour sa mise en oeuvre |
Country Status (6)
Country | Link |
---|---|
US (1) | US4321345A (fr) |
JP (1) | JPS5534238A (fr) |
CS (1) | CS236452B2 (fr) |
DE (1) | DE2920799C2 (fr) |
FR (1) | FR2434823A1 (fr) |
GB (1) | GB2029424B (fr) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1141093A (fr) * | 1979-05-17 | 1983-02-08 | Brian L. Goodall | Compositions catalytiques pour la polymerisation d'olefines, et methode de polymerisation d'olefines utilisant ces compositions |
DE3068239D1 (en) * | 1979-11-20 | 1984-07-19 | Shell Int Research | Preparation of catalyst components and polymerization of olefins employing such catalyst components |
JPS56133303A (en) * | 1980-03-22 | 1981-10-19 | Chisso Corp | Production of alpha-olefin polymer |
US4410672A (en) * | 1980-04-23 | 1983-10-18 | Showa Denko Kabushiki Kaisha | Polymerization catalysts and process for the production of ethylenic polymers by use thereof |
US4425257A (en) * | 1980-05-02 | 1984-01-10 | Phillips Petroleum Company | Supported high efficiency polyolefin catalyst component and methods of making and using the same |
US4618661A (en) * | 1980-05-02 | 1986-10-21 | Phillips Petroleum Company | Supported high efficiency polyolefin catalyst component and methods of making and using the same |
US6777508B1 (en) | 1980-08-13 | 2004-08-17 | Basell Poliolefine Italia S.P.A. | Catalysts for the polymerization of olefins |
IT1209255B (it) * | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
JPS57102907A (en) * | 1980-12-18 | 1982-06-26 | Sumitomo Chem Co Ltd | High-crystallinity propylene polymer for injection molding |
US4774300A (en) * | 1982-08-20 | 1988-09-27 | Phillips Petroleum Company | Supported polyolefin catalyst components and methods of making and using the same |
DE3233140A1 (de) * | 1982-09-07 | 1984-03-08 | Basf Farben + Fasern Ag, 2000 Hamburg | Selbstvernetzendes, hitzehaertbares bindemittel |
US4439538A (en) * | 1982-09-24 | 1984-03-27 | Stauffer Chemical Company | Supported catalyst for polymerizing olefins |
JPS6031504A (ja) * | 1983-07-29 | 1985-02-18 | Nippon Oil Co Ltd | ポリオレフインの製造方法 |
US4981928A (en) * | 1983-08-04 | 1991-01-01 | Exxon Research And Engineering Company | Supported polyolefin catalyst for polymerization of ethylene under high temperatures |
JPS6067508A (ja) * | 1983-09-22 | 1985-04-17 | Toa Nenryo Kogyo Kk | オレフインの重合方法 |
USH179H (en) | 1984-11-28 | 1986-12-02 | Polybutylene | |
DE3628121A1 (de) * | 1986-08-19 | 1988-03-03 | Herberts Gmbh | Fremdvernetzende bindemittelkombination fuer mit wasser verduennbare lacke, kathodisch abscheidbares elektrotauchlackueberzugsmittel und dessen verwendung |
IL95567A (en) * | 1989-10-18 | 1994-02-27 | Himont Inc | Multi-metal catalysts, their preparation and polymers produced with their help |
JP2888639B2 (ja) * | 1992-04-20 | 1999-05-10 | エクソン・ケミカル・パテンツ・インク | エチレン/分枝鎖オレフィンのコポリマー |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2143346A1 (fr) * | 1971-06-25 | 1973-02-02 | Montedison Spa | |
FR2206334A1 (en) * | 1972-11-13 | 1974-06-07 | Chisso Corp | Ethylene (co)polymerisation using catalyst obtained simply - without dehydrochlorination, for high yields and ease of control and catalyst residue removal |
FR2270271A1 (fr) * | 1974-05-08 | 1975-12-05 | Chisso Corp | |
FR2351132A1 (fr) * | 1976-05-14 | 1977-12-09 | Phillips Petroleum Co | Procede de production de catalyseurs de polymerisation d'olefines avec lavage d'un reducteur magnesien prepare en l'absence de diluant de formation en complexe, et nouveaux produits ainsi obtenus |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3900454A (en) * | 1968-02-03 | 1975-08-19 | Chisso Corp | Method for polymerizing monomers comprising alpha-olefin |
US4103078A (en) * | 1969-08-01 | 1978-07-25 | Chisso Corporation | Method for producing polymers of alpha-olefin |
NL7114641A (fr) * | 1970-10-29 | 1972-05-03 | ||
US4107413A (en) * | 1971-06-25 | 1978-08-15 | Montedison S.P.A. | Process for the stereoregular polymerization of alpha olefins |
US4107414A (en) * | 1971-06-25 | 1978-08-15 | Montecatini Edison S.P.A. | Process for the stereoregular polymerization of alpha olefins |
US4027087A (en) * | 1972-10-30 | 1977-05-31 | Chisso Corporation | Method for producing ethylene polymers |
US4071672A (en) * | 1972-11-10 | 1978-01-31 | Mitsui Petrochemical Industries Ltd. | Process for polymerizing or copolymerizing olefins |
JPS565404B2 (fr) * | 1975-02-14 | 1981-02-04 | ||
US3992322A (en) * | 1975-04-11 | 1976-11-16 | Universal Oil Products Company | Preparation of polymerization catalyst systems |
IT1039828B (it) * | 1975-07-09 | 1979-12-10 | Montedison Spa | Componenti di catalizzatori perla polimerizzazione di olefine e catalizzatori da essi ottenuti |
JPS5219790A (en) * | 1975-08-08 | 1977-02-15 | Chisso Corp | Process for the preparation of ethylene polymer |
IT1054410B (it) * | 1975-11-21 | 1981-11-10 | Mitsui Petrochemical Ind | Catalizzatori per la polimerizzazione delle alfa olefine |
JPS52104593A (en) * | 1976-03-01 | 1977-09-02 | Mitsui Petrochem Ind Ltd | Polymerization of olefins |
JPS5329295A (en) * | 1976-08-31 | 1978-03-18 | Chisso Corp | Modifying method for ethylene polymerization catalyst component |
JPS5330681A (en) * | 1976-09-02 | 1978-03-23 | Mitsui Petrochem Ind Ltd | Preparation of polyalpha-olefin |
JPS5379984A (en) * | 1976-12-24 | 1978-07-14 | Mitsui Petrochem Ind Ltd | Copolymer and production |
JPS53143684A (en) * | 1977-05-20 | 1978-12-14 | Mitsui Petrochem Ind Ltd | Polymerization of olefin |
JPS598363B2 (ja) * | 1978-08-22 | 1984-02-24 | チッソ株式会社 | α−オレフイン重合体を製造する方法 |
-
1978
- 1978-08-31 JP JP10679778A patent/JPS5534238A/ja active Granted
-
1979
- 1979-03-15 US US06/021,570 patent/US4321345A/en not_active Expired - Lifetime
- 1979-05-17 GB GB7917283A patent/GB2029424B/en not_active Expired
- 1979-05-22 DE DE2920799A patent/DE2920799C2/de not_active Expired
- 1979-05-30 CS CS793723A patent/CS236452B2/cs unknown
- 1979-08-21 FR FR7921051A patent/FR2434823A1/fr active Granted
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2143346A1 (fr) * | 1971-06-25 | 1973-02-02 | Montedison Spa | |
FR2206334A1 (en) * | 1972-11-13 | 1974-06-07 | Chisso Corp | Ethylene (co)polymerisation using catalyst obtained simply - without dehydrochlorination, for high yields and ease of control and catalyst residue removal |
FR2270271A1 (fr) * | 1974-05-08 | 1975-12-05 | Chisso Corp | |
FR2351132A1 (fr) * | 1976-05-14 | 1977-12-09 | Phillips Petroleum Co | Procede de production de catalyseurs de polymerisation d'olefines avec lavage d'un reducteur magnesien prepare en l'absence de diluant de formation en complexe, et nouveaux produits ainsi obtenus |
Also Published As
Publication number | Publication date |
---|---|
DE2920799C2 (de) | 1986-11-20 |
DE2920799A1 (de) | 1980-03-06 |
FR2434823B1 (fr) | 1985-05-10 |
JPS6226321B2 (fr) | 1987-06-08 |
GB2029424A (en) | 1980-03-19 |
CS236452B2 (en) | 1985-05-15 |
JPS5534238A (en) | 1980-03-10 |
US4321345A (en) | 1982-03-23 |
GB2029424B (en) | 1983-05-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |