FR2421884A1 - Procede de preparation de maleimides substitues a l'azote - Google Patents

Procede de preparation de maleimides substitues a l'azote

Info

Publication number
FR2421884A1
FR2421884A1 FR7908609A FR7908609A FR2421884A1 FR 2421884 A1 FR2421884 A1 FR 2421884A1 FR 7908609 A FR7908609 A FR 7908609A FR 7908609 A FR7908609 A FR 7908609A FR 2421884 A1 FR2421884 A1 FR 2421884A1
Authority
FR
France
Prior art keywords
maleimides
aliphatic
nitrogen
cycloaliphatic
substitutes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7908609A
Other languages
English (en)
Other versions
FR2421884B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of FR2421884A1 publication Critical patent/FR2421884A1/fr
Application granted granted Critical
Publication of FR2421884B1 publication Critical patent/FR2421884B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/44—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members
    • C07D207/444—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5
    • C07D207/448—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. maleimide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/44—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members
    • C07D207/444—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5
    • C07D207/448—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. maleimide
    • C07D207/452—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. maleimide with hydrocarbon radicals, substituted by hetero atoms, directly attached to the ring nitrogen atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pyrrole Compounds (AREA)

Abstract

L'invention concerne un procédé de préparation de maléimides substitués à l'azote. Pour préparer des maléimides de formule I dans laquelle n est égal 1, à 2 ou à 3, R**1 et R**2 représentent chacun un atome d'hydrogène ou un radical méthyle et A représente un radical aliphatique, cycloaliphatique, aliphatique-cycloaliphatique ou aliphatique-aromatique, par déshydratation cyclisante d'un acide maléamique de formule II en présence d'anhydrides d'acides carboxyliques inférieurs, on utilise, comme solvant, un solvant aprotique polaire dont la molécule contient un groupe N-alkyl-carboxamide et, comme catalyseur, un composé métallique et on opère entre 40 et 100 degrés C.
FR7908609A 1978-04-06 1979-04-05 Procede de preparation de maleimides substitues a l'azote Granted FR2421884A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH370678A CH634558A5 (de) 1978-04-06 1978-04-06 Verfahren zur herstellung von aliphatischen n-substituierten maleinimiden.

Publications (2)

Publication Number Publication Date
FR2421884A1 true FR2421884A1 (fr) 1979-11-02
FR2421884B1 FR2421884B1 (fr) 1983-02-11

Family

ID=4261768

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7908609A Granted FR2421884A1 (fr) 1978-04-06 1979-04-05 Procede de preparation de maleimides substitues a l'azote

Country Status (7)

Country Link
US (1) US4229351A (fr)
JP (1) JPS54148776A (fr)
CA (1) CA1124730A (fr)
CH (1) CH634558A5 (fr)
DE (1) DE2913300C2 (fr)
FR (1) FR2421884A1 (fr)
GB (1) GB2018253B (fr)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6019902B2 (ja) * 1979-03-28 1985-05-18 三井東圧化学株式会社 イソプロペニルフェニルマレイミド誘導体の２量体
JPS5896066A (ja) * 1981-12-03 1983-06-07 Mitsui Toatsu Chem Inc 脂肪族マレイミドの製造方法
US4515962A (en) * 1982-08-05 1985-05-07 Ciba Geigy Corporation Allyl or methallyl-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid imides and bisimides
US4604437A (en) * 1984-01-31 1986-08-05 Ciba-Geigy Corporation Polymer from substituted, unsaturated, bicyclic imide
JPS6263562A (ja) * 1985-08-07 1987-03-20 Nippon Shokubai Kagaku Kogyo Co Ltd マレイミド類の製法
DE3789557T2 (de) * 1986-07-31 1994-11-03 Nippon Catalytic Chem Ind Verfahren zur Herstellung von Maleimid.
JPH0639461B2 (ja) * 1988-03-25 1994-05-25 株式会社日本触媒 マレイミド類の製造方法
US5262524A (en) * 1990-03-09 1993-11-16 Hybritech Incorporated Method for the synthesis of trifunctional maleimide-antibody complex
US5091542A (en) * 1990-03-09 1992-02-25 Hybritech Incorporated Tris-maleimido compounds as intermediates in trifunctional antibody synthesis
DE69228840T2 (de) * 1991-01-16 1999-09-16 Akzo Nobel N.V., Arnheim/Arnhem Verfahren zur Herstellung von Citraconsäureimiden
EP0495544B1 (fr) * 1991-01-16 1999-04-07 Akzo Nobel N.V. Procédé pour la préparation de citraconimides
US7645899B1 (en) 1994-09-02 2010-01-12 Henkel Corporation Vinyl compounds
US6852814B2 (en) * 1994-09-02 2005-02-08 Henkel Corporation Thermosetting resin compositions containing maleimide and/or vinyl compounds
JP3085185B2 (ja) * 1996-03-14 2000-09-04 日本メクトロン株式会社 ビスマレイミド化合物およびその製造法
US20080200573A1 (en) * 2005-08-08 2008-08-21 Albemarle Corporation Flame Retarded Styrenic Foams and Foam Precursors
JP2014062050A (ja) * 2012-09-19 2014-04-10 Fujifilm Corp 多価官能マレイミド系重合性化合物、これを含む硬化組成物およびインク組成物
RU2520479C1 (ru) * 2012-12-10 2014-06-27 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Чувашский государственный университет имени И.Н. Ульянова" Эпоксидный клей
JP6388909B2 (ja) 2013-03-28 2018-09-12 エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ キシリレンビスマレイミドをベースとする硬化性混合物
CN103834168B (zh) * 2014-02-25 2016-09-07 广东生益科技股份有限公司 一种无卤阻燃型树脂组合物
JP6952968B2 (ja) * 2015-09-29 2021-10-27 ユニチカ株式会社 マレイミドの製造方法
CN106916282B (zh) 2015-12-28 2019-07-26 广东生益科技股份有限公司 一种环氧树脂组合物以及使用其的预浸料和层压板
CN110437122A (zh) * 2019-08-06 2019-11-12 山东阳谷华泰化工股份有限公司 一种橡胶抗硫化返原剂1,3-双马来酰亚胺正丙烷及其合成方法
CN112062703B (zh) * 2020-08-17 2021-07-23 中国科学院长春应用化学研究所 一种用于含氟聚合物辐照交联敏化剂、其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3018290A (en) * 1959-11-12 1962-01-23 Union Carbide Corp Preparation of maleimides
BE754723A (fr) * 1969-08-12 1971-02-11 Rhone Poulenc Sa Procede de preparation de
US4138406A (en) * 1973-11-22 1979-02-06 Ciba-Geigy Corporation Manufacture of maleimides via cyclizing dehydration
CH581105A5 (fr) * 1973-11-22 1976-10-29 Ciba Geigy Ag
JPS5159851A (ja) * 1974-11-20 1976-05-25 Hitachi Chemical Co Ltd Bisuimidonoseizoho
CH597184A5 (fr) * 1976-04-09 1978-03-31 Ciba Geigy Ag
JPS5952660B2 (ja) * 1976-08-16 1984-12-20 三井東圧化学株式会社 ポリマレイミドの製造方法

Also Published As

Publication number Publication date
DE2913300C2 (de) 1987-04-09
FR2421884B1 (fr) 1983-02-11
GB2018253B (en) 1982-12-08
JPS6343388B2 (fr) 1988-08-30
DE2913300A1 (de) 1979-10-18
CA1124730A (fr) 1982-06-01
US4229351A (en) 1980-10-21
GB2018253A (en) 1979-10-17
JPS54148776A (en) 1979-11-21
CH634558A5 (de) 1983-02-15

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