FR2419277A1 - Procede de preparation de para-nitrodiphenylamines - Google Patents
Procede de preparation de para-nitrodiphenylaminesInfo
- Publication number
- FR2419277A1 FR2419277A1 FR7905935A FR7905935A FR2419277A1 FR 2419277 A1 FR2419277 A1 FR 2419277A1 FR 7905935 A FR7905935 A FR 7905935A FR 7905935 A FR7905935 A FR 7905935A FR 2419277 A1 FR2419277 A1 FR 2419277A1
- Authority
- FR
- France
- Prior art keywords
- nitrodiphenylamines
- solubilizing agents
- para
- preparing para
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
- C07C209/06—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms
- C07C209/10—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to carbon atoms of six-membered aromatic rings or from amines having nitrogen atoms bound to carbon atoms of six-membered aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
L'invention a pour objet un procédé de synthèse de paranitrodiphénylamines dans lequel on fait réagir un para-halonitrobenzène avec une amine aromatique choisie parmi les formanilides et les anilines (substituées et non-substituées) en présence d'une matière basique (pour éliminer l'acide). Selon l'invention on incorpore au milieu réactionnel certains agents solubilisants. Ces agents solubilisants sont des polyéthers linéaires, ramifiés ou cycliques. Les avantages obtenus sont notamment : rendement supérieur de la réaction, quantité plus faible de sous-produits, réaction plus rapide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/884,502 US4155936A (en) | 1978-03-08 | 1978-03-08 | Para-nitrodiphenylamines synthesis using Polyethers and macrocyclic esters as solubilizing agents |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2419277A1 true FR2419277A1 (fr) | 1979-10-05 |
FR2419277B1 FR2419277B1 (fr) | 1985-03-22 |
Family
ID=25384762
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7905935A Granted FR2419277A1 (fr) | 1978-03-08 | 1979-03-08 | Procede de preparation de para-nitrodiphenylamines |
Country Status (9)
Country | Link |
---|---|
US (1) | US4155936A (fr) |
JP (1) | JPS54125622A (fr) |
BR (1) | BR7901339A (fr) |
CA (1) | CA1119198A (fr) |
DE (1) | DE2908804A1 (fr) |
FR (1) | FR2419277A1 (fr) |
GB (1) | GB2015992B (fr) |
IT (1) | IT1114460B (fr) |
MX (1) | MX150947A (fr) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4304939A (en) * | 1978-11-02 | 1981-12-08 | Uop Inc. | Preparation of N-phenyl-N-alkylphenylenediamines |
US4391992A (en) * | 1979-08-24 | 1983-07-05 | American Cyanamid Company | N-Denitration of N,2,6-trinitroanilines with phase transfer catalysts |
FR2501676A1 (fr) * | 1981-03-11 | 1982-09-17 | Rhone Poulenc Spec Chim | Procede de n-alkylation de composes organiques azotes |
US4521622A (en) * | 1983-02-15 | 1985-06-04 | Japan Synthetic Rubber Co., Ltd. | Process for producing aromatic amine |
DE3308658A1 (de) * | 1983-03-11 | 1984-09-13 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von 4-nitrodiphenylaminen |
DE3443679A1 (de) * | 1984-11-30 | 1986-06-05 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von 4-nitrodiphenylaminen |
US4683332A (en) * | 1985-05-20 | 1987-07-28 | The Goodyear Tire & Rubber Company | Para-nitrodiphenylamine synthesis |
DE3924092C1 (fr) * | 1989-07-20 | 1990-11-29 | Hoechst Ag, 6230 Frankfurt, De | |
US5252737A (en) * | 1992-05-22 | 1993-10-12 | Monsanto Company | Process for preparing N-aliphatic substituted p-phenylenediamines |
US5331099A (en) * | 1992-05-22 | 1994-07-19 | Monsanto Company | Process for preparing p-nitroaromatic amides and products thereof |
US5552531A (en) * | 1992-05-22 | 1996-09-03 | Monsanto Company | Process for preparing substituted aromatic azo compounds |
US5233010A (en) * | 1992-10-15 | 1993-08-03 | Monsanto Company | Process for preparing isocyanate and carbamate ester products |
US5451702A (en) * | 1993-04-26 | 1995-09-19 | Monsanto Company | Process for preparing substituted aromatic amines |
US5380946A (en) * | 1993-07-30 | 1995-01-10 | Monsanto Company | Process for preparing p-nitroaromatic amides and products thereof |
US5382691A (en) * | 1993-11-05 | 1995-01-17 | Monsanto Company | Process for preparing substituted aromatic amines |
US5574187A (en) * | 1994-10-06 | 1996-11-12 | Uniroyal Chemical Company, Inc. | Process of preparing para substituted phenylamines |
US5420354A (en) * | 1994-10-06 | 1995-05-30 | Uniroyal Chemical Company, Inc. | Process of preparing para phenylamines |
US5840982A (en) * | 1998-06-04 | 1998-11-24 | Uniroyal Chemical Company, Inc. | Process for preparing para-phenylenediamine derivatives |
DE10025756C2 (de) * | 2000-05-25 | 2003-02-20 | Cognis Deutschland Gmbh | Lösungsvermittler |
US6495723B1 (en) | 2000-06-21 | 2002-12-17 | Flexsys America | Zeolite support loaded with a base material for use in the coupling of aniline and nitrobenzene |
DE102005033732B4 (de) * | 2005-05-27 | 2014-02-13 | Grünenthal GmbH | Trennung stereoisomerer N,N-Dialkylamino-2-alkyl-3-hydroxy-3-phenyl-alkane |
US7683017B2 (en) * | 2007-06-20 | 2010-03-23 | Chevron Oronite Company Llc | Synergistic lubricating oil composition containing a mixture of a nitro-substituted diarylamine and a diarylamine |
IN2014KN01593A (fr) | 2012-03-07 | 2015-10-23 | Nocil Ltd | |
US20240124683A1 (en) | 2022-09-28 | 2024-04-18 | The Goodyear Tire & Rubber Company | Rubber - forming additives from biomass through syngas production |
US20240117149A1 (en) | 2022-09-28 | 2024-04-11 | The Goodyear Tire & Rubber Company | Rubber - forming additives from end of life tires through syngas production |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1056619B (de) * | 1956-11-29 | 1959-05-06 | Bayer Ag | Verfahren zur Herstellung von 4-Nitro-diarylaminen |
FR1208123A (fr) * | 1959-02-17 | 1960-02-22 | Bayer Ag | Procédé de préparation de 4-nitro-diarylamines |
GB834510A (en) * | 1958-03-31 | 1960-05-11 | Goodyear Tire & Rubber | Condensation of an aromatic amine with a halonitrobenzene to provide a nitrophenyl amine |
US3313854A (en) * | 1961-11-20 | 1967-04-11 | Universal Oil Prod Co | Preparation of para-nitrodiphenylamines utilizing a copper oxide catalyst |
DE2719365A1 (de) * | 1977-04-30 | 1978-11-02 | Technochemie Gmbh | Verfahren zur herstellung von dialkylamino-alkylchlorid-hydrochloriden |
EP0004623A1 (fr) * | 1978-04-06 | 1979-10-17 | Bayer Ag | Procédé pour la préparation d'amines aromatiques |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3055940A (en) * | 1957-11-05 | 1962-09-25 | Us Rubber Co | Preparation of nitrodiphenylamines by catalyzed condensation |
DE2534851C3 (de) * | 1975-08-05 | 1984-10-18 | Studiengesellschaft Kohle mbH, 4330 Mülheim | Verfahren zum Löslichmachen von anorganischen oder organischen Alkalimetallsalzen in organischen Lösungsmitteln durch Komplexbildung mit Polyäthylenglykoldiäthern und deren Verwendung |
DE2633811C2 (de) * | 1976-07-28 | 1983-11-10 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Nitrodiphenylaminen |
-
1978
- 1978-03-08 US US05/884,502 patent/US4155936A/en not_active Expired - Lifetime
-
1979
- 1979-01-31 CA CA000320630A patent/CA1119198A/fr not_active Expired
- 1979-02-22 GB GB7906302A patent/GB2015992B/en not_active Expired
- 1979-02-23 MX MX176712A patent/MX150947A/es unknown
- 1979-03-05 IT IT48214/79A patent/IT1114460B/it active
- 1979-03-06 BR BR7901339A patent/BR7901339A/pt unknown
- 1979-03-07 DE DE19792908804 patent/DE2908804A1/de active Granted
- 1979-03-08 FR FR7905935A patent/FR2419277A1/fr active Granted
- 1979-03-08 JP JP2724579A patent/JPS54125622A/ja active Granted
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1056619B (de) * | 1956-11-29 | 1959-05-06 | Bayer Ag | Verfahren zur Herstellung von 4-Nitro-diarylaminen |
GB834510A (en) * | 1958-03-31 | 1960-05-11 | Goodyear Tire & Rubber | Condensation of an aromatic amine with a halonitrobenzene to provide a nitrophenyl amine |
FR1208123A (fr) * | 1959-02-17 | 1960-02-22 | Bayer Ag | Procédé de préparation de 4-nitro-diarylamines |
US3313854A (en) * | 1961-11-20 | 1967-04-11 | Universal Oil Prod Co | Preparation of para-nitrodiphenylamines utilizing a copper oxide catalyst |
DE2719365A1 (de) * | 1977-04-30 | 1978-11-02 | Technochemie Gmbh | Verfahren zur herstellung von dialkylamino-alkylchlorid-hydrochloriden |
EP0004623A1 (fr) * | 1978-04-06 | 1979-10-17 | Bayer Ag | Procédé pour la préparation d'amines aromatiques |
Non-Patent Citations (1)
Title |
---|
EXBK/77 * |
Also Published As
Publication number | Publication date |
---|---|
DE2908804A1 (de) | 1979-09-13 |
GB2015992A (en) | 1979-09-19 |
DE2908804C2 (fr) | 1987-01-15 |
GB2015992B (en) | 1982-07-14 |
CA1119198A (fr) | 1982-03-02 |
JPS54125622A (en) | 1979-09-29 |
MX150947A (es) | 1984-08-24 |
BR7901339A (pt) | 1979-10-09 |
IT7948214A0 (it) | 1979-03-05 |
FR2419277B1 (fr) | 1985-03-22 |
JPS6227060B2 (fr) | 1987-06-12 |
US4155936A (en) | 1979-05-22 |
IT1114460B (it) | 1986-01-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |