GB834510A - Condensation of an aromatic amine with a halonitrobenzene to provide a nitrophenyl amine - Google Patents

Condensation of an aromatic amine with a halonitrobenzene to provide a nitrophenyl amine

Info

Publication number
GB834510A
GB834510A GB23289/58A GB2328958A GB834510A GB 834510 A GB834510 A GB 834510A GB 23289/58 A GB23289/58 A GB 23289/58A GB 2328958 A GB2328958 A GB 2328958A GB 834510 A GB834510 A GB 834510A
Authority
GB
United Kingdom
Prior art keywords
amine
aromatic amine
nitrophenyl
aromatic
halonitrobenzene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23289/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodyear Tire and Rubber Co
Original Assignee
Goodyear Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Goodyear Tire and Rubber Co filed Critical Goodyear Tire and Rubber Co
Publication of GB834510A publication Critical patent/GB834510A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/06Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms
    • C07C209/10Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to carbon atoms of six-membered aromatic rings or from amines having nitrogen atoms bound to carbon atoms of six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/49Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton
    • C07C211/50Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton with at least two amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises a process for condensing an aromatic amine with a halo nitrobenzene to provide a nitrophenyl amine by reacting at least one aromatic amine with at least one nitro halobenzene in the presence of a catalytic amount of cuprous cyanide. Aromatic amines specified are those of general formula R-NH2 where R is <FORM:0834510/IV (b)/1> or indenyl, acenaphthyl or fluorenyl, R1 is hydrogen, hydroxyl, C1-C9 alkyl or alkoxy, C5-C6 cycloalkyl or halogen, X is 1-3 or in the case of naphthalene 1-5, and the corresponding diamines, triamines and polyamines. Halo nitrobenzenes specified are those of general formula <FORM:0834510/IV (b)/2> where R is halogen, R1, hydrogen or C1-C9 alkyl, and Y is 1-2. Carbonates, bicarbonates and oxides of alkali metals, and an inert solvent may also be present in the reaction medium.
GB23289/58A 1958-03-31 1958-07-21 Condensation of an aromatic amine with a halonitrobenzene to provide a nitrophenyl amine Expired GB834510A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US834510XA 1958-03-31 1958-03-31

Publications (1)

Publication Number Publication Date
GB834510A true GB834510A (en) 1960-05-11

Family

ID=22178419

Family Applications (1)

Application Number Title Priority Date Filing Date
GB23289/58A Expired GB834510A (en) 1958-03-31 1958-07-21 Condensation of an aromatic amine with a halonitrobenzene to provide a nitrophenyl amine

Country Status (1)

Country Link
GB (1) GB834510A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2419277A1 (en) * 1978-03-08 1979-10-05 Goodyear Tire & Rubber PROCESS FOR PREPARING PARA-NITRODIPHENYLAMINES
EP0110810A1 (en) * 1982-11-26 1984-06-13 The Goodyear Tire & Rubber Company Para-nitrodiphenylamine synthesis

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2419277A1 (en) * 1978-03-08 1979-10-05 Goodyear Tire & Rubber PROCESS FOR PREPARING PARA-NITRODIPHENYLAMINES
EP0110810A1 (en) * 1982-11-26 1984-06-13 The Goodyear Tire & Rubber Company Para-nitrodiphenylamine synthesis

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