FR2409255A1 - Procede pour la cyclisation d'esters de l'acide g-chlorocarboxylique - Google Patents
Procede pour la cyclisation d'esters de l'acide g-chlorocarboxyliqueInfo
- Publication number
- FR2409255A1 FR2409255A1 FR7831874A FR7831874A FR2409255A1 FR 2409255 A1 FR2409255 A1 FR 2409255A1 FR 7831874 A FR7831874 A FR 7831874A FR 7831874 A FR7831874 A FR 7831874A FR 2409255 A1 FR2409255 A1 FR 2409255A1
- Authority
- FR
- France
- Prior art keywords
- cyclization
- represent
- ester
- general formula
- condensing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C69/757—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
CE PROCEDE CONCERNE LA CYCLISATION D'ESTER DE L'ACIDE CHLOROCARBOXYLIQUE DE FORMULE GENERALE: (CF DESSIN DANS BOPI) DANS LAQUELLE R, R, R, R, R ET R SONT IDENTIQUES OU DIFFERENTS ET REPRESENTENT UN RADICAL ALKYLE LINEAIRE OU RAMIFIE EN C A C, OU DANS LAQUELLE ILS PEUVENT EGALEMENT, A L'EXCEPTION DE R, REPRESENTER UN ATOME D'HYDROGENE, CETTE CYCLISATION DEVANT FOURNIR DES ACIDES CYCLOPROPANECARBOXYLIQUES, EVENTUELLEMENT SUBSTITUES, ET LEURS ESTERS, DE FORMULE GENERALE: (CF DESSIN DANS BOPI) DANS LAQUELLE LES SYMBOLES R A R ONT LA SIGNIFICATION DONNEE CI-DESSUS ET DANS LAQUELLE R PEUT EN OUTRE REPRESENTER UN ATOME D'HYDROGENE, LA CYCLISATION S'EFFECTUANT AU MOYEN D'UN AGENT DE CONDENSATION BASIQUE ET ETANT EVENTUELLEMENT SUIVIE D'UNE SAPONIFICATION DE L'ESTER. IL EST CARACTERISE EN CE QU'ON UTILISE, COMME AGENT DE CONDENSATION, UN ALCOOLATE ALCALIN ANHYDRE, EN CE QUE LA CYCLISATION S'EFFECTUE DANS UN SOLVANT ORGANIQUE INERTE ET EN CE QU'ON ELIMINE PAR DISTILLATION EN CONTINU L'ALCOOL QUI SE FORME LORS DE LA REACTION.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19772751133 DE2751133A1 (de) | 1977-11-16 | 1977-11-16 | Verfahren zum cyclisieren von gamma-chlorcarbonsaeureestern |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2409255A1 true FR2409255A1 (fr) | 1979-06-15 |
Family
ID=6023826
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7831874A Withdrawn FR2409255A1 (fr) | 1977-11-16 | 1978-11-10 | Procede pour la cyclisation d'esters de l'acide g-chlorocarboxylique |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS5479254A (fr) |
BE (1) | BE872029A (fr) |
DE (1) | DE2751133A1 (fr) |
FR (1) | FR2409255A1 (fr) |
GB (1) | GB2008110A (fr) |
IL (1) | IL55932A0 (fr) |
IT (1) | IT1109289B (fr) |
NL (1) | NL7808602A (fr) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2941211C2 (de) * | 1979-10-11 | 1982-11-25 | Degussa Ag, 6000 Frankfurt | Verfahren zum gegebenenfalls kontinuierlichen Cyclisieren von γ-Chlorcarbonsäureestern |
EP0031932B1 (fr) * | 1979-12-22 | 1987-07-01 | Hüls Troisdorf Aktiengesellschaft | Lactones substituées, dérivés d'acide pentanoique et procédé pour leur préparation |
DE3537813C1 (de) * | 1985-10-24 | 1987-02-05 | Degussa | Verfahren zur Herstellung von 1-Methylcyclopropancarboxaldehyd |
DE3538133A1 (de) * | 1985-10-26 | 1987-04-30 | Huels Chemische Werke Ag | Verfahren zur herstellung von reinen, chlorfreien cyclopropancarbonsaeureestern |
GB8615313D0 (en) * | 1986-06-23 | 1986-07-30 | Ici Plc | Chemical process |
CA2056840A1 (fr) * | 1990-12-17 | 1992-06-18 | Thomas Meul | Methode de preparation d'acide dimethylcyclopropanecarboxylique |
DE4222497A1 (de) * | 1992-07-09 | 1994-01-13 | Huels Chemische Werke Ag | Verfahren zur Herstellung von chlorfreiem Cyclopropancarbonsäuremethylester |
JP3140698B2 (ja) * | 1996-11-26 | 2001-03-05 | ダイセル化学工業株式会社 | 4−ヒドロキシ−2−ピロリジノンの製造方法ならびに精製方法 |
US6252089B1 (en) | 1997-11-25 | 2001-06-26 | Daicel Chemical Industries, Ltd. | Method of producing 4-hydroxy-2-pyrrolidinone and method of purifying the same |
US6552217B2 (en) * | 2000-08-01 | 2003-04-22 | Eastman Chemical Company | Process for the preparation of alkyl 1-methylcyclopropanecarboxylate |
-
1977
- 1977-11-16 DE DE19772751133 patent/DE2751133A1/de active Pending
-
1978
- 1978-08-18 NL NL7808602A patent/NL7808602A/xx not_active Application Discontinuation
- 1978-11-08 GB GB7843736A patent/GB2008110A/en not_active Withdrawn
- 1978-11-10 FR FR7831874A patent/FR2409255A1/fr not_active Withdrawn
- 1978-11-14 BE BE6046669A patent/BE872029A/fr unknown
- 1978-11-14 JP JP13948078A patent/JPS5479254A/ja active Pending
- 1978-11-14 IL IL55932A patent/IL55932A0/xx unknown
- 1978-11-15 IT IT51913/78A patent/IT1109289B/it active
Also Published As
Publication number | Publication date |
---|---|
IL55932A0 (en) | 1979-01-31 |
JPS5479254A (en) | 1979-06-25 |
GB2008110A (en) | 1979-05-31 |
IT1109289B (it) | 1985-12-16 |
BE872029A (fr) | 1979-05-14 |
NL7808602A (nl) | 1979-05-18 |
DE2751133A1 (de) | 1979-05-17 |
IT7851913A0 (it) | 1978-11-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |