FR2399482A1 - Precipitation selective de nickel et de cobalt a partir d'une solution de sulfate acide - Google Patents
Precipitation selective de nickel et de cobalt a partir d'une solution de sulfate acideInfo
- Publication number
- FR2399482A1 FR2399482A1 FR7822441A FR7822441A FR2399482A1 FR 2399482 A1 FR2399482 A1 FR 2399482A1 FR 7822441 A FR7822441 A FR 7822441A FR 7822441 A FR7822441 A FR 7822441A FR 2399482 A1 FR2399482 A1 FR 2399482A1
- Authority
- FR
- France
- Prior art keywords
- nickel
- cobalt
- selective precipitation
- sulphate solution
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910017052 cobalt Inorganic materials 0.000 title abstract 4
- 239000010941 cobalt Substances 0.000 title abstract 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title abstract 4
- 238000001556 precipitation Methods 0.000 title abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 title abstract 2
- 230000002378 acidificating effect Effects 0.000 title abstract 2
- 229910021653 sulphate ion Inorganic materials 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 6
- 229910052759 nickel Inorganic materials 0.000 abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 abstract 2
- 238000002386 leaching Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 abstract 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/11—Sulfides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
- C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Précipitation sélective de nickel et de cobalt à partir d'une solution de sulfate acide. L'invention propose un procédé pour précipiter efficacement du sulfure de nickel en partant d'une solution de sulfate de nickel acide ayant un pH variant entre 1,5 et 4, contenant environ 1 à 40 gpl de nickel, contenant facultativement du cobalt, et contenant un sel de sulfate soluble inerte suffisant pour tamponner la solution afin de contrôler le pH dans une gamme de 1,5 à 4 pendant la précipitation de sulfure de nickel à une température et une pression relativement basses. Applicable de manière générale à la récupération du nickel et du cobalt à partir de solutions acides diluées obtenues par lessivage de la matière première à l'acide sulfurique.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/820,595 US4110400A (en) | 1977-08-01 | 1977-08-01 | Selective precipitation of nickel and cobalt sulfides from acidic sulfate solution |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2399482A1 true FR2399482A1 (fr) | 1979-03-02 |
FR2399482B1 FR2399482B1 (fr) | 1985-08-02 |
Family
ID=25231247
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7822441A Expired FR2399482B1 (fr) | 1977-08-01 | 1978-07-28 | Precipitation selective de nickel et de cobalt a partir d'une solution de sulfate acide |
Country Status (8)
Country | Link |
---|---|
US (1) | US4110400A (fr) |
JP (1) | JPS5442327A (fr) |
AU (1) | AU530924B2 (fr) |
BR (1) | BR7804785A (fr) |
CA (1) | CA1103935A (fr) |
DE (1) | DE2833297C2 (fr) |
FR (1) | FR2399482B1 (fr) |
GB (1) | GB2001943B (fr) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4214901A (en) * | 1979-02-16 | 1980-07-29 | Amax Inc. | Hydrometallurgical refining of nickeliferous sulfides |
CA1214335A (fr) * | 1982-06-21 | 1986-11-25 | Robert M. Rownd | Recyclage hydrodynamique des semis de sulfure metallique sous pression |
US4547347A (en) * | 1983-12-02 | 1985-10-15 | Amax Inc. | Granulometric control of nickel sulfide precipitate |
US5994041A (en) * | 1985-04-06 | 1999-11-30 | Eastman Kodak Company | Process for buffering concentrated aqueous slurries |
FI75868C (fi) * | 1986-10-03 | 1988-08-08 | Outokumpu Oy | Saett att utfaella och avskilja metaller. |
US5559035A (en) * | 1992-08-24 | 1996-09-24 | Umpqua Research Company | Solid phase calibration standards |
US5609998A (en) * | 1994-12-29 | 1997-03-11 | Eastman Kodak Company | Process for dispersing concentrated aqueous slurries |
US6395061B1 (en) | 2000-03-07 | 2002-05-28 | Bhp Minerals International Inc. | Process for organic acid bioleaching of ore |
CA2460116A1 (fr) * | 2001-09-14 | 2003-03-27 | Alexander Beckmann | Procede pour extraire du cobalt et du nickel contenus dans des minerais et des concentres de minerais |
AU2003249789B2 (en) * | 2002-08-15 | 2009-06-04 | Wmc Resources Ltd | Recovering nickel |
AU2002950815A0 (en) * | 2002-08-15 | 2002-09-12 | Wmc Resources Ltd | Recovery nickel |
US8747678B2 (en) * | 2006-03-31 | 2014-06-10 | Bioteq Environmental Technologies Inc. | Nickel sulphide precipitation process |
CN100423825C (zh) * | 2006-08-18 | 2008-10-08 | 丁四宜 | 硫化氢吸收利用装置 |
MX2010003363A (es) | 2007-09-26 | 2010-09-07 | Bioteq Environmental Technolog | Remocion selectiva de sulfato por intercambio de aniones exclusivo de corrientes de desecho de agua dura. |
JP5125543B2 (ja) * | 2008-01-23 | 2013-01-23 | 住友金属鉱山株式会社 | ニッケル及びコバルトを含む硫化物の製造方法 |
WO2009100537A1 (fr) * | 2008-02-12 | 2009-08-20 | Bioteq Environmental Technologies Inc. | Procédés de fabrication de h2s à l'aide de bactéries réductrices de soufre |
JP5572928B2 (ja) * | 2008-07-25 | 2014-08-20 | 住友金属鉱山株式会社 | ニッケル酸化鉱石の湿式製錬方法 |
AU2009262353A1 (en) * | 2008-06-27 | 2009-12-30 | Bhp Billiton Ssm Development Pty Ltd | Process for forming high density sulfides |
JP4888580B2 (ja) * | 2010-04-22 | 2012-02-29 | 住友金属鉱山株式会社 | 貯液装置及びその圧力制御方法 |
JP5359989B2 (ja) * | 2010-05-18 | 2013-12-04 | 住友金属鉱山株式会社 | 生成硫化物の付着防止方法 |
WO2016051098A1 (fr) | 2014-10-02 | 2016-04-07 | Elektron Gri | Procédé industriel de traitement d'un produit contenant de l'amiante et ses applications |
JP2016194124A (ja) * | 2015-04-01 | 2016-11-17 | 住友金属鉱山株式会社 | ニッケル及びコバルトの混合硫化物の製造方法、ニッケル酸化鉱石の湿式製錬方法 |
CN105543503B (zh) * | 2015-12-28 | 2017-08-04 | 中南大学 | 硫酸锌电解液中分离回收钴的方法 |
RU2621548C1 (ru) * | 2016-03-03 | 2017-06-06 | Федеральное государственное бюджетное учреждение науки Институт металлургии Уральского отделения Российской академии наук (ИМЕТ УрО РАН) | Способ переработки никельсодержащих растворов |
RU2674538C1 (ru) * | 2018-07-25 | 2018-12-11 | Федеральное государственное бюджетное учреждение науки Институт металлургии Уральского отделения Российской академии наук (ИМЕТ УрО РАН) | Способ переработки сульфатных никельсодержащих растворов |
UA128234C2 (uk) * | 2018-12-21 | 2024-05-15 | Юмікор | Спосіб видобування металів з поліметалічних конкрецій |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2020325A (en) * | 1933-12-15 | 1935-11-12 | New Jersey Zinc Co | Method of producing precipitates |
US2726953A (en) * | 1954-06-21 | 1955-12-13 | Chemical Construction Corp | Selective nucleated precipitation from acidic solutions |
US2872306A (en) * | 1956-05-29 | 1959-02-03 | Freeport Sulphur Co | Recovery of cobalt and nickel from ores |
GB998230A (fr) * | 1962-07-25 | 1900-01-01 | ||
US3933976A (en) * | 1974-02-08 | 1976-01-20 | Amax Inc. | Nickel-cobalt separation |
US3991159A (en) * | 1975-01-09 | 1976-11-09 | Amax Inc. | High temperature neutralization of laterite leach slurry |
US4024218A (en) * | 1975-11-03 | 1977-05-17 | Cominco Ltd. | Process for hydrometallurgical upgrading |
-
1977
- 1977-08-01 US US05/820,595 patent/US4110400A/en not_active Expired - Lifetime
-
1978
- 1978-07-13 CA CA307,355A patent/CA1103935A/fr not_active Expired
- 1978-07-24 AU AU38283/78A patent/AU530924B2/en not_active Expired
- 1978-07-25 BR BR7804785A patent/BR7804785A/pt unknown
- 1978-07-28 FR FR7822441A patent/FR2399482B1/fr not_active Expired
- 1978-07-28 DE DE2833297A patent/DE2833297C2/de not_active Expired
- 1978-07-31 GB GB7831728A patent/GB2001943B/en not_active Expired
- 1978-08-01 JP JP9322178A patent/JPS5442327A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
GB2001943A (en) | 1979-02-14 |
US4110400A (en) | 1978-08-29 |
CA1103935A (fr) | 1981-06-30 |
AU530924B2 (en) | 1983-08-04 |
AU3828378A (en) | 1980-01-31 |
DE2833297A1 (de) | 1979-02-22 |
DE2833297C2 (de) | 1984-07-12 |
JPS5442327A (en) | 1979-04-04 |
GB2001943B (en) | 1982-02-24 |
FR2399482B1 (fr) | 1985-08-02 |
BR7804785A (pt) | 1979-03-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |