FR2395286A1 - Procede pour ameliorer la maniabilite de caoutchoucs greffes acryliques - Google Patents
Procede pour ameliorer la maniabilite de caoutchoucs greffes acryliquesInfo
- Publication number
- FR2395286A1 FR2395286A1 FR7809745A FR7809745A FR2395286A1 FR 2395286 A1 FR2395286 A1 FR 2395286A1 FR 7809745 A FR7809745 A FR 7809745A FR 7809745 A FR7809745 A FR 7809745A FR 2395286 A1 FR2395286 A1 FR 2395286A1
- Authority
- FR
- France
- Prior art keywords
- degrees
- graft rubber
- workability
- particles
- improving
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000002245 particle Substances 0.000 abstract 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- 230000009477 glass transition Effects 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- -1 alkyl methacrylate Chemical compound 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/16—Powdering or granulating by coagulating dispersions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/005—Processes for mixing polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
L'invention se rapporte aux matières polymères. Elle concerne un procédé pour améliorer la maniabilité d'un caoutchouc greffé acrylique élastique composé de particules ayant une couche extérieure constituée d'un polymère de méthacrylate d'alcoyle ayant une température de transition vitreuse supérieure à 25 degrés C, selon lequel on mélange le caoutchouc greffé acrylique tandis qu'il est encore dans son milieu de polymérisation en émulsion avec une solution d'un sel ionisable, et on agite le mélange résultant à une température comprise entre 30 et 70 degrés C jusqu'à ce que les particules de caoutchouc greffé coagulent, puis on ajoute une dispersion d'une résine de méthacrylate de méthyle qui a une température de transition vitreuse supérieure à 25 degrés C, et on agite le mélange résultant à une température comprise entre 60 et 120 degrés C, après quoi on isole les matières coagulées. Utilisation par l'industrie des matières polymères.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/808,396 US4097553A (en) | 1977-06-20 | 1977-06-20 | Acrylic graft copolymers blended with acrylic resins |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2395286A1 true FR2395286A1 (fr) | 1979-01-19 |
FR2395286B1 FR2395286B1 (fr) | 1983-03-25 |
Family
ID=25198646
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7809745A Granted FR2395286A1 (fr) | 1977-06-20 | 1978-04-03 | Procede pour ameliorer la maniabilite de caoutchoucs greffes acryliques |
Country Status (6)
Country | Link |
---|---|
US (1) | US4097553A (fr) |
JP (1) | JPS547458A (fr) |
DE (1) | DE2809817A1 (fr) |
FR (1) | FR2395286A1 (fr) |
GB (1) | GB1568469A (fr) |
NL (1) | NL7802045A (fr) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5848584B2 (ja) * | 1978-12-29 | 1983-10-29 | 呉羽化学工業株式会社 | グラフト共重合体の製造方法 |
DE3150730A1 (de) * | 1981-12-22 | 1983-06-30 | Röhm GmbH, 6100 Darmstadt | Verfahren zur herstellung blockfester, weicher polymerperlen |
DE3312541A1 (de) * | 1983-04-07 | 1984-10-11 | Bayer Ag, 5090 Leverkusen | Pfropfpolymerisat enthaltende polymerisatpulver |
ES2046458T3 (es) * | 1988-01-29 | 1994-02-01 | Imperial Chemical Industries Plc | Dispersiones de particulas compuestas. |
GB8916944D0 (en) * | 1989-07-25 | 1989-09-13 | Ici Plc | Composite particle dispersions |
JP2873107B2 (ja) * | 1991-03-29 | 1999-03-24 | 三菱レイヨン株式会社 | ゴム含有グラフト共重合体粒子の製造方法 |
GB9108219D0 (en) * | 1991-04-18 | 1991-06-05 | Ici America Inc | Anti-blocking suspension of polymers |
DE4114641A1 (de) * | 1991-05-04 | 1992-11-05 | Basf Ag | Emulsionspfropfcopolymerisate |
JPH05262953A (ja) * | 1992-03-19 | 1993-10-12 | Mitsubishi Rayon Co Ltd | ゴム含有グラフト共重合体粒子の製造方法 |
JP2001106741A (ja) * | 1999-09-27 | 2001-04-17 | Rohm & Haas Co | 被覆用ポリマー |
DE60028711T2 (de) | 1999-12-23 | 2007-05-24 | Rohm And Haas Co. | Additive für Kunststoffe, die Herstellung und Mischungen |
RU2184125C1 (ru) * | 2000-11-30 | 2002-06-27 | Институт катализа им. Г.К.Борескова СО РАН | Водная гетерополимерная дисперсия для изготовления покрытий и способ ее получения |
EP1433799A3 (fr) * | 2002-12-23 | 2004-07-14 | Ucb, S.A. | Polymère acrylique à blocs dans la forme d'une étoile |
EP1911771A1 (fr) * | 2006-10-09 | 2008-04-16 | Cytec Surface Specialties, S.A. | Dispersion aqueuse d'un polymère et procédé pour sa production |
JP4793313B2 (ja) | 2007-04-16 | 2011-10-12 | ソニー株式会社 | 光情報記録媒体ならびにその記録および/または再生方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3502604A (en) * | 1965-12-15 | 1970-03-24 | Mitsubishi Rayon Co | Impact resistant resin compositions and method of production thereof |
FR2084780A5 (fr) * | 1970-03-18 | 1971-12-17 | Mitsubishi Rayon Co | |
FR2159882A6 (en) * | 1970-04-13 | 1973-06-22 | Rohm & Haas | Transparent or translucent impact-resistant polyalkylmethacrylate blends |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3793402A (en) * | 1971-11-05 | 1974-02-19 | F Owens | Low haze impact resistant compositions containing a multi-stage,sequentially produced polymer |
-
1977
- 1977-06-20 US US05/808,396 patent/US4097553A/en not_active Expired - Lifetime
-
1978
- 1978-02-23 NL NL7802045A patent/NL7802045A/xx not_active Application Discontinuation
- 1978-02-28 JP JP2166778A patent/JPS547458A/ja active Granted
- 1978-03-07 DE DE19782809817 patent/DE2809817A1/de not_active Withdrawn
- 1978-04-03 FR FR7809745A patent/FR2395286A1/fr active Granted
- 1978-04-28 GB GB17010/78A patent/GB1568469A/en not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3502604A (en) * | 1965-12-15 | 1970-03-24 | Mitsubishi Rayon Co | Impact resistant resin compositions and method of production thereof |
FR2084780A5 (fr) * | 1970-03-18 | 1971-12-17 | Mitsubishi Rayon Co | |
FR2159882A6 (en) * | 1970-04-13 | 1973-06-22 | Rohm & Haas | Transparent or translucent impact-resistant polyalkylmethacrylate blends |
Also Published As
Publication number | Publication date |
---|---|
GB1568469A (en) | 1980-05-29 |
JPS547458A (en) | 1979-01-20 |
FR2395286B1 (fr) | 1983-03-25 |
JPS6157341B2 (fr) | 1986-12-06 |
NL7802045A (nl) | 1978-12-22 |
US4097553A (en) | 1978-06-27 |
DE2809817A1 (de) | 1979-01-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |