FR2391245A1 - Plastisols a base de copolymeres de methacrylate de methyle - Google Patents

Plastisols a base de copolymeres de methacrylate de methyle

Info

Publication number
FR2391245A1
FR2391245A1 FR7814563A FR7814563A FR2391245A1 FR 2391245 A1 FR2391245 A1 FR 2391245A1 FR 7814563 A FR7814563 A FR 7814563A FR 7814563 A FR7814563 A FR 7814563A FR 2391245 A1 FR2391245 A1 FR 2391245A1
Authority
FR
France
Prior art keywords
weight
copolymer
methacrylate
plastisols
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7814563A
Other languages
English (en)
Other versions
FR2391245B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roehm GmbH Darmstadt
Original Assignee
Roehm GmbH Darmstadt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roehm GmbH Darmstadt filed Critical Roehm GmbH Darmstadt
Publication of FR2391245A1 publication Critical patent/FR2391245A1/fr
Application granted granted Critical
Publication of FR2391245B1 publication Critical patent/FR2391245B1/fr
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C09D133/12—Homopolymers or copolymers of methyl methacrylate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902—Core-shell

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Paints Or Removers (AREA)
  • Sealing Material Composition (AREA)

Abstract

Ces plastisols sont à base d'un copolymère de méthacrylate de méthyle et d'un plastifiant organique dans un rapport quantitatif de 10 : 3 à 1 : 10, ainsi que de charges. Le copolymère est un polymère d'émulsion qui est formé d'une matière de noyau compatible avec le plastifiant, composée de : A. 15 à 100 % en poids d'un ester alcoylique d'acide acrylique contenant au moins 3 atomes de carbonç dans le radical alcoyle et/ou d'un ester alcoylique d'acide méthacrylique contenant au moins 2 atomes de carbone dans le radical alcoyle et/ou de styrène, et le cas échéant; B. Jusqu'à 85 % en poids d'acrylate ou méthacrylate de méthyle, d'acrylate d'éthyle, et C. Jusqu'à 20 % en poids d'autres monomères susceptibles de polymérisation radicalaire, et d'un homopolymère du méthacrylate de méthyle ou d'un copolymère formé pour 80 % en poids au moins de ce dernier et ayant une température de vitrification supérieure à 50 degrés C, servant de matière d'enveloppe. Les plastifiants sont de préférence des esters de l'acide phtalique. Ces plastisols conviennent pour le revêtement d'objet par immersion, pulvérisation, enduction à la brosse ou à la racle; ils peuvent être utilisés comme pâte d'étanchéité ou de masticage; par gélification dans des moules appropriés, on peut aussi fabriquer des pièces profilées.
FR7814563A 1977-05-20 1978-05-17 Plastisols a base de copolymeres de methacrylate de methyle Expired FR2391245B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2722752A DE2722752C3 (de) 1977-05-20 1977-05-20 Plastisole auf Basis von Methylmethacrylat-Mischpolymerisaten

Publications (2)

Publication Number Publication Date
FR2391245A1 true FR2391245A1 (fr) 1978-12-15
FR2391245B1 FR2391245B1 (fr) 1985-05-31

Family

ID=6009429

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7814563A Expired FR2391245B1 (fr) 1977-05-20 1978-05-17 Plastisols a base de copolymeres de methacrylate de methyle

Country Status (9)

Country Link
US (1) US4199486A (fr)
JP (1) JPS53144950A (fr)
BR (1) BR7803195A (fr)
DE (1) DE2722752C3 (fr)
FR (1) FR2391245B1 (fr)
GB (1) GB1581493A (fr)
IT (1) IT1107884B (fr)
NL (1) NL183893C (fr)
SE (1) SE426400B (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0007391A1 (fr) * 1978-07-31 1980-02-06 Röhm Gmbh Poudre polymère pour compositions de revêtement, composition et procédé de revêtement de chlorure de polyvinyle plastifié
EP0076368A2 (fr) * 1981-10-01 1983-04-13 Röhm Gmbh Plastisols fabriqués à partir de copolymérisats du méthylméthacrylate et leur utilisation
EP0557944A1 (fr) * 1992-02-25 1993-09-01 Takeda Chemical Industries, Ltd. Polymère coeur-enveloppe et plastisol à partir de celui-ci

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2949954A1 (de) * 1979-12-12 1981-06-19 Röhm GmbH, 6100 Darmstadt Pvc-plastisol
US4325856A (en) * 1980-01-02 1982-04-20 The Dow Chemical Company Sequential emulsion polymerization process
US4391928A (en) * 1981-09-04 1983-07-05 Nl Industries, Inc. Opacifying polymeric particle and uses
US4497917A (en) * 1982-09-29 1985-02-05 Eastman Kodak Company Latex composition comprising core-shell polymer particles
DE3308925A1 (de) * 1983-03-12 1984-09-13 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung lagerstabiler plastisole und organosole
US4659334A (en) * 1984-07-10 1987-04-21 Petrolite Corporation Particulate compositions used in petroleum systems comprising encapsulated materials
US4588640A (en) * 1984-07-10 1986-05-13 Petrolite Corporation Particulate compositions
US4916171A (en) * 1984-07-25 1990-04-10 Rohm And Haas Company Polymers comprising alkali-insoluble core/alkali-soluble shell and copositions thereof
DE3723668A1 (de) * 1987-07-17 1989-01-26 Roehm Gmbh Staubarmes spruehgetrocknetes emulsionspolymerisat und verfahren zu seiner herstellung und anwendung
DE3816710A1 (de) * 1988-05-17 1989-11-23 Pegulan Werke Ag Verwendung von acrylat-plastisolen zur herstellung von laufschichten fuer pvc-bodenbelaege
DE3902557A1 (de) * 1989-01-28 1990-08-02 Roehm Gmbh Waessriges polyacrylat-system fuer die schlusslackierung von polyvinylchlorid-oberflaechen
DE4013318A1 (de) * 1990-04-26 1991-10-31 Teroson Gmbh Zweischichtige beschichtung und verfahren zu deren herstellung
DE4034725A1 (de) * 1990-10-31 1992-05-07 Teroson Gmbh Plastisolzusammensetzung
US5668209A (en) * 1990-10-31 1997-09-16 Teroson Gmbh Plastisol composition
GB9118890D0 (en) * 1991-09-04 1991-10-23 Grace W R & Co Container closure
GB9122594D0 (en) * 1991-10-24 1991-12-04 Ici Plc Plastisol compositions
TW227009B (fr) * 1992-06-05 1994-07-21 Shell Internat Res Schappej B V
JPH06322225A (ja) * 1993-05-14 1994-11-22 Toyo Seikan Kaisha Ltd ポットライフに優れたプラスチゾル組成物
EP0624606B2 (fr) † 1993-05-14 2003-08-27 Mitsui Takeda Chemicals, Inc. Polymère coeur-enveloppe et plastisol à partir de celui-ci
JP2739805B2 (ja) * 1993-05-14 1998-04-15 東洋製罐株式会社 耐クリープ性に優れたアクリル系プラスチゾル組成物
DE19542746A1 (de) 1995-11-16 1997-05-22 Roehm Gmbh Plastisole auf der Grundlage von durch Weichmacherzusatz weichgemachte Polymermassen
DE19650939C1 (de) * 1996-12-07 1998-06-04 Roehm Gmbh Plastisole auf der Basis von Methylmethacrylat- Copolymerisaten
EP0951507B1 (fr) * 1996-12-31 2002-02-27 Avecia Limited Compositions de plastisol
JP3621885B2 (ja) 1998-07-01 2005-02-16 三菱レイヨン株式会社 アクリル系重合体微粒子及びそれを用いたプラスチゾル
FR2791353B1 (fr) 1999-03-23 2001-05-25 Chavanoz Ind Composition plastique ignifugeante, fil et structure textile enduits avec cette derniere
DE19928352A1 (de) * 1999-06-21 2000-12-28 Roehm Gmbh Verbesserte Poly(meth)acrylatptastisole und Verfahren zu ihrer Herstellung
JP3684198B2 (ja) * 1999-09-20 2005-08-17 三菱レイヨン株式会社 アクリル系プラスチゾル用重合体微粒子およびその製造方法、並びに非ハロゲン系プラスチゾル組成物およびそれを用いた物品
DE10029735B4 (de) * 2000-06-23 2006-09-21 Röhm GmbH & Co. KG Schäumbare Poly(meth)acrylatplastisole sowie ihre Verwendung
US7514497B2 (en) * 2000-10-09 2009-04-07 C.H. Erbsloeh Kg Method for the production of at least one body and a pourable mixture for use in such a method
JP4077323B2 (ja) * 2001-05-23 2008-04-16 三菱レイヨン株式会社 プラスチゾル組成物及びそれを用いた成形品及び物品
CN1209425C (zh) * 2001-07-04 2005-07-06 三菱丽阳株式会社 塑料溶胶组合物、凝胶化膜及物品
JP4491236B2 (ja) 2001-12-21 2010-06-30 ヘンケル・テロソン・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング 熱可塑性ポリマーで変性した膨張性エポキシ樹脂系システム
CN1324054C (zh) * 2002-07-23 2007-07-04 可隆株式会社 用于涂层的丙烯酸类聚合物溶胶的制备
DE10302298A1 (de) 2003-01-22 2004-08-05 Henkel Kgaa Hitzehärtbare, thermisch expandierbare Zusammensetzung mit hohem Expansionsgrad
JP5162096B2 (ja) * 2003-07-31 2013-03-13 三菱レイヨン株式会社 成形材料用樹脂組成物およびそれを用いた成形品
KR100775564B1 (ko) 2003-09-30 2007-11-09 니폰 쇼쿠바이 컴파니 리미티드 제진재용 수성 에멀젼
DE102004030404A1 (de) * 2004-06-23 2006-01-19 Röhm GmbH & Co. KG Plastisole auf Basis eines Methylmethacrylat-Mischpolymerisats
DE102004035937A1 (de) 2004-07-23 2006-02-16 Röhm GmbH & Co. KG Plastisole mit verringerter Wasseraufnahme
DE102004037472A1 (de) * 2004-07-30 2006-03-23 Röhm GmbH & Co. KG Additive für Epoxid-Harze
KR100752503B1 (ko) 2005-05-31 2007-08-27 주식회사 엘지화학 염화비닐 수지용 가공조제 및 그 제조방법
WO2006062366A1 (fr) * 2004-12-08 2006-06-15 Lg Chem, Ltd. Additif pour pvc et procede de fabrication correspondant
JP5161566B2 (ja) * 2006-02-23 2013-03-13 三菱レイヨン株式会社 （メタ）アクリル系重合体粒子、その製造方法、プラスチゾル及び物品
CN101489777B (zh) * 2006-05-22 2014-02-12 纳诺麦克有限公司 涂有金属的非金属纳米粒子/微粒子及其方法和应用
US8288447B2 (en) 2006-06-07 2012-10-16 Henkel Ag & Co. Kgaa Foamable compositions based on epoxy resins and polyesters
DE102006057145A1 (de) * 2006-11-22 2008-05-29 Evonik Röhm Gmbh Verfahren zur Herstellung verbesserter Bindemittel für Plastisole
JP5597923B2 (ja) 2007-01-23 2014-10-01 三菱レイヨン株式会社 プラスチゾル組成物及びこれを用いた物品
DE102007040304A1 (de) 2007-08-24 2009-02-26 Evonik Röhm Gmbh Verbesserte Bindemittel für Plastisole
DE102007061503A1 (de) 2007-12-18 2009-06-25 Henkel Ag & Co. Kgaa Flammfeste Plastisole enthaltend Blähgraphit
DE102007061509A1 (de) 2007-12-18 2009-06-25 Henkel Ag & Co. Kgaa Flammfeste Plastisole
US8653171B2 (en) * 2010-02-22 2014-02-18 Polyone Corporation Plastisol compositions that are essentially free of polyvinyl halides and phthalates
WO2014209968A1 (fr) 2013-06-25 2014-12-31 Polyone Corporation Compositions de plastisol comportant un réseau polymère interpénétré (ipn) à résine acrylique-résine uréthanique
EP3438219A4 (fr) * 2016-03-30 2019-10-30 Zeon Corporation Sol pour application par pulvérisation, corps moulé en résine de chlorure de vinyle avec couche appliquée par pulvérisation ainsi que procédé de fabrication de celui-ci, et stratifié

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2306249A1 (fr) * 1975-04-04 1976-10-29 Smith & Mclaurin Compositions adhesives et procedes de leur preparation

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US2600122A (en) * 1949-06-04 1952-06-10 Us Rubber Co Process of forming plastisols
US3745196A (en) * 1969-05-26 1973-07-10 Rohm & Haas Low-temperature and oil-resistant core-shell acrylic polymers
CA1030687A (fr) * 1972-09-26 1978-05-02 Hideyoshi Tugukuni Compose pulverulent de revetement et methode de preparation connexe
US3787522A (en) * 1972-11-01 1974-01-22 Ford Motor Co Acrylate polymer particles comprising a core,an outer shell,and an intermediate layer
DE2264224C3 (de) * 1972-12-30 1981-11-19 Röhm GmbH, 6100 Darmstadt Herstellung eines vernetzten Polystyrol-Emulsionspolymerisats und seine Verwendung zum Trüben von Kunststoffen auf Methacrylatbasis
JPS521958B2 (fr) * 1973-08-15 1977-01-19
DE2454235C3 (de) * 1974-11-15 1982-01-07 Teroson Gmbh, 6900 Heidelberg Plastisole auf der Basis von Acrylat-Polymerisaten
JPS5936645B2 (ja) * 1975-05-06 1984-09-05 三菱レイヨン株式会社 多層構造重合体組成物の製造法
US3985703A (en) * 1975-06-24 1976-10-12 Rohm And Haas Company Process for manufacture of acrylic core/shell polymers
DE2543542C2 (de) * 1975-09-30 1986-10-02 Röhm GmbH, 6100 Darmstadt Verfahren zur Herstellung eines Plastisols
US4125700A (en) * 1977-03-22 1978-11-14 E. I. Du Pont De Nemours And Company Preparation of methyl methacrylate polymer powders for use in plastisols

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2306249A1 (fr) * 1975-04-04 1976-10-29 Smith & Mclaurin Compositions adhesives et procedes de leur preparation

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0007391A1 (fr) * 1978-07-31 1980-02-06 Röhm Gmbh Poudre polymère pour compositions de revêtement, composition et procédé de revêtement de chlorure de polyvinyle plastifié
EP0076368A2 (fr) * 1981-10-01 1983-04-13 Röhm Gmbh Plastisols fabriqués à partir de copolymérisats du méthylméthacrylate et leur utilisation
EP0076368A3 (en) * 1981-10-01 1984-03-28 Rohm Gmbh Plastisols of copolymers of methylmethacrylate, and their use
EP0557944A1 (fr) * 1992-02-25 1993-09-01 Takeda Chemical Industries, Ltd. Polymère coeur-enveloppe et plastisol à partir de celui-ci

Also Published As

Publication number Publication date
BR7803195A (pt) 1979-01-02
IT7868159A0 (it) 1978-05-19
DE2722752A1 (de) 1978-11-23
US4199486A (en) 1980-04-22
JPS53144950A (en) 1978-12-16
IT1107884B (it) 1985-12-02
DE2722752C3 (de) 1987-10-22
SE426400B (sv) 1983-01-17
GB1581493A (en) 1980-12-17
FR2391245B1 (fr) 1985-05-31
JPS623868B2 (fr) 1987-01-27
DE2722752B2 (de) 1979-04-12
NL183893C (nl) 1989-02-16
NL183893B (nl) 1988-09-16
SE7805769L (sv) 1979-02-05
NL7805388A (nl) 1978-11-22

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