FR2386508A1 - Procede de preparation de l'ethylene-glycol - Google Patents

Procede de preparation de l'ethylene-glycol

Info

Publication number
FR2386508A1
FR2386508A1 FR7810375A FR7810375A FR2386508A1 FR 2386508 A1 FR2386508 A1 FR 2386508A1 FR 7810375 A FR7810375 A FR 7810375A FR 7810375 A FR7810375 A FR 7810375A FR 2386508 A1 FR2386508 A1 FR 2386508A1
Authority
FR
France
Prior art keywords
group
mixed
platinoid
preparing ethylene
glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
FR7810375A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of FR2386508A1 publication Critical patent/FR2386508A1/fr
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procédé de préparation de l'éthylène-glycol à partir d'acide glycolique. On fait réagir l'acide glycolique avec l'hydrogène en présence d'un catalyseur d'hydrogénation renfermant : - soit un platinoïde (groupe VIII) en mélange avec un élément du groupe VIIb, - soit un platinoïde en mélange avec un élément du groupe Ib, - soit un élément du groupe VIIb en mélange avec un élément du groupe Ib, - soit un platinoïde en mélange à la fois avec un élément du groupe VIIb et avec un élément du groupe Ib, chacun des éléments en question étant à l'état libre ou sous la forme d'un de ses composés.
FR7810375A 1977-04-07 1978-04-07 Procede de preparation de l'ethylene-glycol Pending FR2386508A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19772715666 DE2715666A1 (de) 1977-04-07 1977-04-07 Verfahren zur herstellung von aethylenglykol

Publications (1)

Publication Number Publication Date
FR2386508A1 true FR2386508A1 (fr) 1978-11-03

Family

ID=6005913

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7810375A Pending FR2386508A1 (fr) 1977-04-07 1978-04-07 Procede de preparation de l'ethylene-glycol

Country Status (9)

Country Link
US (1) US4214106A (fr)
JP (1) JPS53124206A (fr)
BE (1) BE865808A (fr)
CA (1) CA1098544A (fr)
DE (1) DE2715666A1 (fr)
FR (1) FR2386508A1 (fr)
GB (1) GB1599598A (fr)
IT (1) IT1094292B (fr)
NL (1) NL7803695A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0373938A2 (fr) * 1988-12-15 1990-06-20 Hoechst Celanese Corporation Catalyseur résistant au formaldéhyde pour l'hydrogénation et l'hydrogénolyse d'aldéhydes, acétals ou esters

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4317918A (en) * 1979-11-05 1982-03-02 Sumitomo Chemical Co., Ltd. Process for preparing alcohols
US4321414A (en) * 1980-08-26 1982-03-23 The Halcon Sd Group, Inc. Catalytic hydrogenation of glycolaldehyde to produce ethylene glycol
JPS57123143A (en) * 1981-01-26 1982-07-31 Ube Ind Ltd Production of glycolic ester
DE3312639A1 (de) * 1982-04-12 1983-10-13 W.R. Grace & Co., 10036 New York, N.Y. Teilchenfoermiger katalysator, verfahren zu seiner herstellung und seine verwendung
GB8310797D0 (en) * 1983-04-21 1983-05-25 British Petroleum Co Plc Vapour phase hydrogenation of esters
US4851593A (en) * 1987-10-13 1989-07-25 Sherex Chemical Company Dihydroxy or polyhydroxy compounds and process for producing same
GB8917157D0 (en) * 1989-07-27 1989-09-13 Bp Chem Int Ltd Chemical process
DE19720657A1 (de) * 1997-05-16 1998-11-19 Basf Ag Verfahren zur Herstellung von aliphatischen Alkoholen
DE19803888A1 (de) * 1998-01-31 1999-08-05 Bayer Ag Verfahren zur Herstellung von Ruthenium enthaltenden Katalysatoren und deren Verwendung bei Hydrierungen
DE10241292A1 (de) 2002-09-04 2004-03-18 Basf Ag Verfahren zur Herstellung optisch aktiver 2-Amino-, 2-Hydroxy oder 2-Alkoxy-1-alkohole
US6887821B2 (en) * 2003-04-01 2005-05-03 The Boeing Company High-temperature catalyst for catalytic combustion and decomposition
US7510995B2 (en) * 2003-04-01 2009-03-31 United Technologies Corporation Application of a mixed metal oxide catalyst to a metallic substrate
US7615671B2 (en) 2007-11-30 2009-11-10 Eastman Chemical Company Hydrogenation process for the preparation of 1,2-diols
US9108895B2 (en) 2012-10-26 2015-08-18 Eastman Chemical Company Promoted ruthenium catalyst for the improved hydrogenation of carboxylic acids to the corresponding alcohols
US10435349B2 (en) 2017-08-02 2019-10-08 Eastman Chemical Company Iron-catalyzed cross-coupling of methanol with secondary or tertiary alcohols to produce formate esters
US10266467B2 (en) 2017-08-02 2019-04-23 Eastman Chemical Company Synthesis of glycols via transfer hydrogenation of alpha-functional esters with alcohols
US10544077B2 (en) 2017-08-02 2020-01-28 Eastman Chemical Company Process for making formic acid utilizing higher-boiling formate esters
US10570081B2 (en) 2017-08-02 2020-02-25 Eastman Chemical Company Process for making formic acid utilizing lower-boiling formate esters
US10266466B2 (en) 2017-08-02 2019-04-23 Eastman Chemical Company Iron-catalyzed transfer hydrogenation of esters to alcohols

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE622053A (fr) * 1961-09-02 1900-01-01
DE662731C (de) * 1930-07-26 1938-07-20 Boehme Fettchemie Ges M B H Verfahren zur Herstellung hoeherer aliphatischer Alkohole
US2607807A (en) * 1950-02-24 1952-08-19 Du Pont Preparation of alcohols from carboxylic acids
US2607805A (en) * 1949-06-10 1952-08-19 Du Pont Hydrogenation of glycolic acid to ethylene glycol
FR1293723A (fr) * 1960-05-18 1962-05-18 Basf Ag Procédé pour la transformation d'acides carboxyliques en alcools, par hydrogénation
FR1303231A (fr) * 1961-09-01 1962-09-07 Hydrierwerk Rodleben Veb Procédé de préparation d'alcools
FR1426720A (fr) * 1964-03-17 1966-01-28 Basf Ag Procédé de préparation d'alcools par hydrogénation catalytique d'acides carboxyliques
FR2040257A1 (fr) * 1969-04-26 1971-01-22 Basf Ag
FR2310331A1 (fr) * 1975-05-03 1976-12-03 Hoechst Ag Procede de preparation du butanediol-1,4
FR2340922A1 (fr) * 1976-02-10 1977-09-09 Veba Chemie Ag Procede de fabrication d'alcools par hydrogenation directe d'acides

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2094611A (en) * 1934-12-11 1937-10-05 Du Pont Process for producing alcohols from hydroxy carboxylic compounds
US2285448A (en) * 1937-10-30 1942-06-09 Du Pont Preparation of polyhydric alcohols
DE1188572B (de) * 1960-05-18 1965-03-11 Basf Ag Verfahren zur Herstellung von Alkoholen durch Hydrieren von Carbonsaeuren
DE2434991A1 (de) * 1974-07-20 1976-02-05 Hoechst Ag Verfahren zur herstellung von butandiol-(1,4)
DE2501499A1 (de) * 1975-01-16 1976-07-22 Hoechst Ag Verfahren zur herstellung von butandiol-(1.4)
US4088682A (en) * 1975-07-03 1978-05-09 Jordan Robert Kenneth Oxalate hydrogenation process

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE662731C (de) * 1930-07-26 1938-07-20 Boehme Fettchemie Ges M B H Verfahren zur Herstellung hoeherer aliphatischer Alkohole
US2607805A (en) * 1949-06-10 1952-08-19 Du Pont Hydrogenation of glycolic acid to ethylene glycol
US2607807A (en) * 1950-02-24 1952-08-19 Du Pont Preparation of alcohols from carboxylic acids
FR1293723A (fr) * 1960-05-18 1962-05-18 Basf Ag Procédé pour la transformation d'acides carboxyliques en alcools, par hydrogénation
FR1303231A (fr) * 1961-09-01 1962-09-07 Hydrierwerk Rodleben Veb Procédé de préparation d'alcools
BE622053A (fr) * 1961-09-02 1900-01-01
FR1426720A (fr) * 1964-03-17 1966-01-28 Basf Ag Procédé de préparation d'alcools par hydrogénation catalytique d'acides carboxyliques
FR2040257A1 (fr) * 1969-04-26 1971-01-22 Basf Ag
FR2310331A1 (fr) * 1975-05-03 1976-12-03 Hoechst Ag Procede de preparation du butanediol-1,4
FR2340922A1 (fr) * 1976-02-10 1977-09-09 Veba Chemie Ag Procede de fabrication d'alcools par hydrogenation directe d'acides

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0373938A2 (fr) * 1988-12-15 1990-06-20 Hoechst Celanese Corporation Catalyseur résistant au formaldéhyde pour l'hydrogénation et l'hydrogénolyse d'aldéhydes, acétals ou esters
EP0373938A3 (fr) * 1988-12-15 1991-05-15 Hoechst Celanese Corporation Catalyseur résistant au formaldéhyde pour l'hydrogénation et l'hydrogénolyse d'aldéhydes, acétals ou esters

Also Published As

Publication number Publication date
GB1599598A (en) 1981-10-07
JPS53124206A (en) 1978-10-30
IT1094292B (it) 1985-07-26
NL7803695A (nl) 1978-10-10
IT7821989A0 (it) 1978-04-05
US4214106A (en) 1980-07-22
CA1098544A (fr) 1981-03-31
BE865808A (fr) 1978-10-09
DE2715666A1 (de) 1978-10-12

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