FR2364450A1 - Methode et appareil de protection des electrodes detectrices d'une cellule electrochimique a electrolyte solide - Google Patents

Methode et appareil de protection des electrodes detectrices d'une cellule electrochimique a electrolyte solide

Info

Publication number
FR2364450A1
FR2364450A1 FR7727355A FR7727355A FR2364450A1 FR 2364450 A1 FR2364450 A1 FR 2364450A1 FR 7727355 A FR7727355 A FR 7727355A FR 7727355 A FR7727355 A FR 7727355A FR 2364450 A1 FR2364450 A1 FR 2364450A1
Authority
FR
France
Prior art keywords
oxygen
cell
electrode
solid electrolyte
detector
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7727355A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CBS Corp
Original Assignee
Westinghouse Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Westinghouse Electric Corp filed Critical Westinghouse Electric Corp
Publication of FR2364450A1 publication Critical patent/FR2364450A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403—Cells and electrode assemblies
    • G01N27/406—Cells and probes with solid electrolytes
    • G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
    • G01N27/4077—Means for protecting the electrolyte or the electrodes
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Pathology (AREA)
  • Immunology (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • Medicinal Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Measuring Oxygen Concentration In Cells (AREA)

Abstract

L'invention est du domaine des cellules électrochimiques à électrolyte solide conducteur d'ions oxygène. Elle vise plus précisément une cellule de ce type comportant une électrode de transport d'oxygène 27 exposée à une source d'oxygène, un circuit de mesure de tension 46 surveillant la f.é.m. produite par la cellule et indicatrice de la teneur en oxygène de l'environnement surveillé ME, tandis que, si le taux d'oxygène surveillé tombe au-dessous d'un niveau où l'atmosphère est susceptible de sulfurer l'électrode détectrice 24 de la cellule, cette dernière se transforme en << pompe >> pour transporter l'oxygène de la source au moyen de l'électrode de transfert et de l'électrolyte 22 afin de maintenir une atmosphère oxydante protectrice au contact de l'électrode détectrice. Application à la protection des électrodes détectrices contre les dommages dus à un environnement sulfureux.
FR7727355A 1976-09-10 1977-09-09 Methode et appareil de protection des electrodes detectrices d'une cellule electrochimique a electrolyte solide Withdrawn FR2364450A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/722,259 US4088543A (en) 1976-09-10 1976-09-10 Technique for protecting sensing electrodes in sulfiding environments

Publications (1)

Publication Number Publication Date
FR2364450A1 true FR2364450A1 (fr) 1978-04-07

Family

ID=24901100

Family Applications (2)

Application Number Title Priority Date Filing Date
FR7727355A Withdrawn FR2364450A1 (fr) 1976-09-10 1977-09-09 Methode et appareil de protection des electrodes detectrices d'une cellule electrochimique a electrolyte solide
FR8214184A Granted FR2509050A1 (fr) 1976-09-10 1982-08-16 Procede de protection des electrodes detectrices d'une cellule electrochimique a electrolyte solide

Family Applications After (1)

Application Number Title Priority Date Filing Date
FR8214184A Granted FR2509050A1 (fr) 1976-09-10 1982-08-16 Procede de protection des electrodes detectrices d'une cellule electrochimique a electrolyte solide

Country Status (9)

Country Link
US (1) US4088543A (fr)
JP (1) JPS5335595A (fr)
AU (1) AU508840B2 (fr)
BE (1) BE858572A (fr)
CA (1) CA1078020A (fr)
DE (1) DE2736451C2 (fr)
FR (2) FR2364450A1 (fr)
GB (1) GB1589308A (fr)
IT (1) IT1086473B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2416469A1 (fr) * 1978-02-01 1979-08-31 Westinghouse Electric Corp Appareil perfectionne de dosage de l'oxygene muni d'un dispositif filtrant

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4088543A (en) * 1976-09-10 1978-05-09 Westinghouse Electric Corp. Technique for protecting sensing electrodes in sulfiding environments
FR2392382A1 (fr) * 1977-05-27 1978-12-22 Anvar Jauge electrochimique a oxygene a reference interne et electrolyte solide
GB1604445A (en) * 1977-09-30 1981-12-09 Sybron Corp Device for monitoring a component in a fluid mixture
GB2052751B (en) * 1979-06-21 1983-03-16 Taylor Instr Analytics Ltd Device for monitoring a component in a fluid mixture
NL7906833A (nl) * 1979-09-13 1981-03-17 Philips Nv Gasanalyseapparaat.
JPS57131046A (en) * 1981-02-06 1982-08-13 Hitachi Ltd Air-fuel ratio controller for internal combustion engine
JPS57187647A (en) * 1981-05-15 1982-11-18 Hitachi Ltd Combustion detector
DE3131103A1 (de) * 1981-08-06 1983-02-24 Bbc Brown Boveri & Cie "elektrochemische messvorrichtung"
US4377460A (en) * 1981-10-19 1983-03-22 Westinghouse Electric Corp. Solid electrolyte gas sensing apparatus
DE3209438C1 (de) * 1982-03-16 1983-07-28 Joachim Dr-Ing Wuenning Verfahren und Messeinrichtung zur Bestimmung der Aktivitaet des Kohlenstoffes in Ofenatmosphaeren
US4579643A (en) * 1983-11-18 1986-04-01 Ngk Insulators, Ltd. Electrochemical device
DE3405162A1 (de) * 1984-02-14 1985-08-22 Bosch Gmbh Robert Polarographischer sauerstoffmessfuehler
JPS60219547A (ja) * 1984-04-16 1985-11-02 Nissan Motor Co Ltd 酸素濃度検出装置
US4568443A (en) * 1984-09-06 1986-02-04 Mitsubishi Denki Kabushiki Kaisha Air-to-fuel ratio sensor
US4812329A (en) * 1986-05-28 1989-03-14 Westinghouse Electric Corp. Method of making sulfur tolerant composite cermet electrodes for solid oxide electrochemical cells
DE3627799A1 (de) * 1986-08-16 1988-02-25 Programmelectronic Eng Ag Verfahren zur regeneration von potentiometrischen festelektrolyt-messzellen und anordnung zum aufschalten auf eine messzelle
US4875990A (en) * 1986-08-28 1989-10-24 Ngk Insulators, Ltd. Oxygen concentration measuring device
JPH07104319B2 (ja) * 1986-09-10 1995-11-13 株式会社日立製作所 空燃比センサ
JP2512548B2 (ja) * 1988-03-29 1996-07-03 日本碍子株式会社 酸素センサの多孔質保護層の検査方法
US4882032A (en) * 1988-06-27 1989-11-21 General Motors Corporation Hydrogen probe
DE4225775C2 (de) * 1992-08-04 2002-09-19 Heraeus Electro Nite Int Anordnung zum kontinuierlichen Überwachen der Konzentration von NO in Gasgemischen
DE4311985C2 (de) * 1993-04-07 1996-02-08 Mannesmann Ag Festelektrolyt-Sensor
US5851369A (en) * 1996-09-20 1998-12-22 Marathon Monitors, Inc. Electrolytic sensor providing controlled burn-off of deposits on the electrodes
US5980728A (en) * 1996-09-24 1999-11-09 Rosemont Analytical Inc. Diagnostic method and apparatus for solid electrolyte gas analyzer
US6110861A (en) * 1997-06-02 2000-08-29 The University Of Chicago Partial oxidation catalyst

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3514377A (en) * 1967-11-27 1970-05-26 Gen Electric Measurement of oxygen-containing gas compositions and apparatus therefor
US3650934A (en) * 1969-11-14 1972-03-21 Westinghouse Electric Corp Oxygen control and measuring apparatus
US3699032A (en) * 1969-06-20 1972-10-17 Univ Ohio Devices for the control of agents in fluids
FR2237194A1 (fr) * 1973-07-09 1975-02-07 Philips Nv
US3909384A (en) * 1973-06-18 1975-09-30 Texas Instruments Inc Electro-chemical sensors for trace gases
US3923624A (en) * 1973-03-28 1975-12-02 Philips Corp Apparatus for the measuring and supplying a controlled quantity of a gas

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL6710038A (fr) * 1967-07-20 1969-01-22
NL7105976A (fr) * 1971-04-30 1972-11-01
US3928161A (en) * 1972-04-25 1975-12-23 Westinghouse Electric Corp Gas measuring probe for industrial applications
US3835012A (en) * 1972-08-28 1974-09-10 Bendix Corp Protective shield for oxygen sensor
FR2231288A5 (fr) * 1973-05-23 1974-12-20 Bosch Gmbh Robert
US3844920A (en) * 1973-11-21 1974-10-29 Gen Motors Corp Air fuel ratio sensor
US3960500A (en) * 1975-01-09 1976-06-01 Bailey Meter Company Gas sampling analyzing system
JPS5273085A (en) * 1975-12-15 1977-06-18 Nippon Soken Oxygen concentration detector
US4088543A (en) * 1976-09-10 1978-05-09 Westinghouse Electric Corp. Technique for protecting sensing electrodes in sulfiding environments

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3514377A (en) * 1967-11-27 1970-05-26 Gen Electric Measurement of oxygen-containing gas compositions and apparatus therefor
US3699032A (en) * 1969-06-20 1972-10-17 Univ Ohio Devices for the control of agents in fluids
US3650934A (en) * 1969-11-14 1972-03-21 Westinghouse Electric Corp Oxygen control and measuring apparatus
US3923624A (en) * 1973-03-28 1975-12-02 Philips Corp Apparatus for the measuring and supplying a controlled quantity of a gas
US3909384A (en) * 1973-06-18 1975-09-30 Texas Instruments Inc Electro-chemical sensors for trace gases
FR2237194A1 (fr) * 1973-07-09 1975-02-07 Philips Nv

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2416469A1 (fr) * 1978-02-01 1979-08-31 Westinghouse Electric Corp Appareil perfectionne de dosage de l'oxygene muni d'un dispositif filtrant

Also Published As

Publication number Publication date
AU2813277A (en) 1979-03-01
GB1589308A (en) 1981-05-13
AU508840B2 (en) 1980-04-03
JPS5335595A (en) 1978-04-03
DE2736451A1 (de) 1978-03-16
JPS6126021B2 (fr) 1986-06-18
US4088543A (en) 1978-05-09
BE858572A (fr) 1978-03-09
FR2509050A1 (fr) 1983-01-07
IT1086473B (it) 1985-05-28
CA1078020A (fr) 1980-05-20
DE2736451C2 (de) 1986-11-20
FR2509050B1 (fr) 1985-01-04

Similar Documents

Publication Publication Date Title
FR2364450A1 (fr) Methode et appareil de protection des electrodes detectrices d&#39;une cellule electrochimique a electrolyte solide
FR2416469A1 (fr) Appareil perfectionne de dosage de l&#39;oxygene muni d&#39;un dispositif filtrant
US3764269A (en) Sensor for fluid components
US9726633B2 (en) Electrochemical gas sensor system
GB1264441A (fr)
GB2013895A (en) Electroanalytical cell and amperometric measurement method
SE8304489D0 (sv) Electrochemical apparatus for monitoring and/or measuring a component of a gas
Zambonin et al. Voltammetry of Peroxide and Superoxide in Fused Salts
US3546079A (en) Method for determining continuously small concentrations of gaseous halogenated compounds and of hydrogen halides in air and in other gases
JPS57161546A (en) Electrochemical measuring apparatus having measuring cell containing integrated detection element and several reference electrodes
ES468549A2 (es) Aparato electroquimico para medir la concentracion de oxige-no en un metal alcalino liquido
US4149948A (en) Electrochemical cell for detecting hydrogen sulphide in a gaseous mixture
US3681228A (en) Electrochemical concentration cell for gas analysis
JP4217077B2 (ja) 隔膜型電極の安定化方法
US4065313A (en) Bleach-fix regeneration monitoring method
Mizusaki et al. The application of an improved dc polarization technique to the electronic conductivity measurements of. ALPHA.-AgI and AgBr.
EP0096117B1 (fr) Analyseur d&#39;espèces chimiques oxydantes ou réductrices
GB1499651A (en) Electrochemical cells
CN205049513U (zh) 过程分析仪器
Jasinski et al. Computer simulation of current voltage response of electrocatalytic sensor
US4539092A (en) Plasma oxygen permeability meter
SU136590A1 (ru) Способ кулонометрического анализа металлов по осаждению
KR820000085B1 (ko) 고온 기준 전극
JPH0625746B2 (ja) 電気化学式酸性ガス検出装置
SU493719A1 (ru) Гальваническа чейка на твердом электролите

Legal Events

Date Code Title Description
ST Notification of lapse