FR2302996A1 - Procede pour preparer des isomeres stereospecifiques de l'acide farnesylacetique, de ses esters et de leurs derives - Google Patents
Procede pour preparer des isomeres stereospecifiques de l'acide farnesylacetique, de ses esters et de leurs derivesInfo
- Publication number
- FR2302996A1 FR2302996A1 FR7526705A FR7526705A FR2302996A1 FR 2302996 A1 FR2302996 A1 FR 2302996A1 FR 7526705 A FR7526705 A FR 7526705A FR 7526705 A FR7526705 A FR 7526705A FR 2302996 A1 FR2302996 A1 FR 2302996A1
- Authority
- FR
- France
- Prior art keywords
- esters
- derivatives
- farnesylacetic acid
- stereospecific isomers
- preparing stereospecific
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
- C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
- C07C29/42—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones with compounds containing triple carbon-to-carbon bonds, e.g. with metal-alkynes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
- C07C45/676—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton by elimination of carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
- C07C51/38—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by decarboxylation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/27—Preparation of carboxylic acid esters from ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C11/00—Fermentation processes for beer
- C12C11/02—Pitching yeast
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/09—Geometrical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Food Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- Mycology (AREA)
- Genetics & Genomics (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10063574A JPS5820948B2 (ja) | 1974-09-02 | 1974-09-02 | デルタ 4 ,デルタ 8− トランスフアルネシルサクサン マタハ ソノエステルルイ ノ セイゾウホウ |
JP10063474A JPS5822457B2 (ja) | 1974-09-02 | 1974-09-02 | デルタ 4 ,デルタ 8− トランスフアルネシルサクサン マタハ ソノエステルルイ ノ セイゾウホウホウ |
JP49100632A JPS5826328B2 (ja) | 1974-09-02 | 1974-09-02 | リツタイキセイサレタ フアルネシルサクサン マタハ ソノエステル ノ セイゾウホウホウ |
JP49100631A JPS5826330B2 (ja) | 1974-09-02 | 1974-09-02 | 立体規制されたファルネシル酢酸エステルの製造方法 |
JP49100633A JPS5826331B2 (ja) | 1974-09-02 | 1974-09-02 | 立体規制されたファルネシル酢酸エステルの製造方法 |
JP49104062A JPS5132511A (en) | 1974-09-10 | 1974-09-10 | Ritsutaikiseisareta geraniruaseton no seizohoho |
JP49119797A JPS5148604A (en) | 1974-10-17 | 1974-10-17 | Ritsutaikisei sareta neroridooruno seizoho |
JP49119798A JPS593452B2 (ja) | 1974-10-17 | 1974-10-17 | 立体規制されたネロリド−ルの製造法 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2302996A1 true FR2302996A1 (fr) | 1976-10-01 |
FR2302996B1 FR2302996B1 (fr) | 1983-03-25 |
Family
ID=27572946
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7526705A Granted FR2302996A1 (fr) | 1974-09-02 | 1975-08-29 | Procede pour preparer des isomeres stereospecifiques de l'acide farnesylacetique, de ses esters et de leurs derives |
Country Status (5)
Country | Link |
---|---|
US (1) | US4028385A (fr) |
DE (1) | DE2538532C2 (fr) |
FR (1) | FR2302996A1 (fr) |
GB (1) | GB1514292A (fr) |
IT (1) | IT1044026B (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014096107A1 (fr) * | 2012-12-18 | 2014-06-26 | Dsm Ip Assets B.V. | Utilisation de mélanges d'isomères e/z en vue d'obtenir des produits spécifiques de manière quantitative par combinaison d'hydrogénation asymétrique et d'isomérisation |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS601283B2 (ja) * | 1976-06-08 | 1985-01-14 | 帝人株式会社 | 包接化合物並びにその製造法 |
US4259253A (en) * | 1980-01-28 | 1981-03-31 | Istituto De Angeli S.P.A. | Process for the preparation of stereospecific trans, trans-farnesylacetic acid |
DE3735211A1 (de) * | 1987-10-17 | 1989-04-27 | Huels Chemische Werke Ag | Verfahren zur herstellung von beta-isophoron aus alpha-isophoron |
MY173272A (en) * | 2012-12-18 | 2020-01-09 | Dsm Ip Assets Bv | (6r,10r)-6,10,14-trimetylpentadecan-2-one prepared from 6,10,14-trimetylpentadeca-5,9,13-trien-2-one or 6,10,14-trimetylpentadeca-5,9-dien-2-one |
EP2935175B1 (fr) | 2012-12-18 | 2018-09-19 | DSM IP Assets B.V. | (6r, 10r) -6,10,14-trimétylpentadecan-2-one préparé à partir de (r)-6,10,14-trimetylpentadec-5-en-2-one |
CN104854072A (zh) | 2012-12-18 | 2015-08-19 | 帝斯曼知识产权资产管理有限公司 | 由6,10-二甲基十一碳-3,5,9-三烯-2-酮制备的(6r,10r)-6,10,14-三甲基十五烷-2-酮 |
BR112015014335B1 (pt) * | 2012-12-18 | 2020-12-08 | Dsm Ip Assets B.V. | (6r,10r)-6,10,14-trimetilpentadecan-2-ona preparada a partir de 6,10-dimetilundec-5-en-2-ona ou 6,10 dimetilundeca-5,9-dien-2-ona |
BR112015014106B1 (pt) * | 2012-12-18 | 2020-11-17 | Dsm Ip Assets B.V. | processo de uma isomerização cis/trans de um composto insaturado, processos de produção de isômeros cis e trans, composição, cetal ou acetal e uso de um politiol |
CN103012140B (zh) * | 2013-01-08 | 2016-02-17 | 湖南方盛制药股份有限公司 | 吉法酯的制备方法 |
ES2925229T3 (es) | 2017-09-04 | 2022-10-14 | Dsm Ip Assets Bv | Derivados de 6-cromanol y su síntesis |
EP3567091A1 (fr) | 2018-05-07 | 2019-11-13 | Oleon N.V. | Acides gras ramifiés et leurs esters |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2848502A (en) * | 1958-08-19 | Karl h | ||
US3082260A (en) * | 1959-05-20 | 1963-03-19 | Air Reduction | Preparation of acetylenic alcohols |
GB938712A (en) * | 1961-05-24 | 1963-10-02 | Angeli Inst Spa | Farnesyl acetic esters |
US3928403A (en) * | 1974-07-10 | 1975-12-23 | Kuraray Co | Process for preparing farnesyl acetic acid esters and 2-substituted-products thereof |
-
1975
- 1975-08-18 US US05/605,455 patent/US4028385A/en not_active Expired - Lifetime
- 1975-08-20 GB GB34559/75A patent/GB1514292A/en not_active Expired
- 1975-08-29 FR FR7526705A patent/FR2302996A1/fr active Granted
- 1975-08-29 DE DE2538532A patent/DE2538532C2/de not_active Expired
- 1975-09-01 IT IT26780/75A patent/IT1044026B/it active
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014096107A1 (fr) * | 2012-12-18 | 2014-06-26 | Dsm Ip Assets B.V. | Utilisation de mélanges d'isomères e/z en vue d'obtenir des produits spécifiques de manière quantitative par combinaison d'hydrogénation asymétrique et d'isomérisation |
US9573872B2 (en) | 2012-12-18 | 2017-02-21 | Dsm Ip Assets B.V. | Using mixtures of E/Z isomers to obtain quantitatively specific products by combining asymmetric hydrogenation and isomerization |
EA033435B1 (ru) * | 2012-12-18 | 2019-10-31 | Dsm Ip Assets Bv | Применение смесей e/z-изомеров для количественного получения определенных продуктов сочетанием асимметрической гидрогенизации и изомеризации |
Also Published As
Publication number | Publication date |
---|---|
US4028385A (en) | 1977-06-07 |
IT1044026B (it) | 1980-02-29 |
FR2302996B1 (fr) | 1983-03-25 |
DE2538532A1 (de) | 1976-03-18 |
DE2538532C2 (de) | 1982-10-14 |
GB1514292A (en) | 1978-06-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |