FR2076726A5 - Aminosilane treated glass fibres coated with elastomers - free from zinc oxide and fatty acids - Google Patents
Aminosilane treated glass fibres coated with elastomers - free from zinc oxide and fatty acidsInfo
- Publication number
- FR2076726A5 FR2076726A5 FR7002655A FR7002655A FR2076726A5 FR 2076726 A5 FR2076726 A5 FR 2076726A5 FR 7002655 A FR7002655 A FR 7002655A FR 7002655 A FR7002655 A FR 7002655A FR 2076726 A5 FR2076726 A5 FR 2076726A5
- Authority
- FR
- France
- Prior art keywords
- fatty acids
- glass fibres
- elastomers
- free
- fibres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
- C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/27—Rubber latex
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Reinforced Plastic Materials (AREA)
- Laminated Bodies (AREA)
Abstract
Glass fibre-reinforced rubber is made by (1) depositing on glass fibres an organo-Si compound in which the organic group contains an NH2 group, (2) coating the treated fibres with a S-curable elastomer containing 0.05% of ZnO and 0.5% of free fatty acid, up to 5% of S and up to 5% of a vulcanisation accelerator, and (3) applying a curable rubber to the fibres and curing the resulting composite. The S-curable elastomer can be a natural, SBR, nitrile, butyl or halogenated butyl rubber, neoprene, a polydiene or a C2H4/C3H6 terpolymer. The use of elastomers containing no more than small amounts of ZnO and fatty acids improves the bonding of the elastomer to the glass fibres through the aminosilane.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19702002895 DE2002895A1 (en) | 1970-01-23 | 1970-01-23 | Glass fiber reinforced elastomers |
FR7002655A FR2076726A5 (en) | 1970-01-23 | 1970-01-26 | Aminosilane treated glass fibres coated with elastomers - free from zinc oxide and fatty acids |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19702002895 DE2002895A1 (en) | 1970-01-23 | 1970-01-23 | Glass fiber reinforced elastomers |
FR7002655A FR2076726A5 (en) | 1970-01-23 | 1970-01-26 | Aminosilane treated glass fibres coated with elastomers - free from zinc oxide and fatty acids |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2076726A5 true FR2076726A5 (en) | 1971-10-15 |
Family
ID=25758527
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7002655A Expired FR2076726A5 (en) | 1970-01-23 | 1970-01-26 | Aminosilane treated glass fibres coated with elastomers - free from zinc oxide and fatty acids |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE2002895A1 (en) |
FR (1) | FR2076726A5 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2479802A1 (en) * | 1980-04-03 | 1981-10-09 | Ppg Industries Inc | Reducing chemical degradation in fibre reinforced polymers - using pref. phenolic or di:arylamine antioxidants used as stable aq. emulsions in glass fibre finishing compsns. |
US4483948A (en) * | 1980-09-24 | 1984-11-20 | Ppg Industries, Inc. | Antioxidants and reinforced polymers and oil-in-water emulsions of antioxidants |
-
1970
- 1970-01-23 DE DE19702002895 patent/DE2002895A1/en active Pending
- 1970-01-26 FR FR7002655A patent/FR2076726A5/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2479802A1 (en) * | 1980-04-03 | 1981-10-09 | Ppg Industries Inc | Reducing chemical degradation in fibre reinforced polymers - using pref. phenolic or di:arylamine antioxidants used as stable aq. emulsions in glass fibre finishing compsns. |
US4483948A (en) * | 1980-09-24 | 1984-11-20 | Ppg Industries, Inc. | Antioxidants and reinforced polymers and oil-in-water emulsions of antioxidants |
Also Published As
Publication number | Publication date |
---|---|
DE2002895A1 (en) | 1971-07-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |