FR2012552A1 - Tertiary olefins prodn and purification - using an ion-exchange catalyst - Google Patents
Tertiary olefins prodn and purification - using an ion-exchange catalystInfo
- Publication number
- FR2012552A1 FR2012552A1 FR6922961A FR6922961A FR2012552A1 FR 2012552 A1 FR2012552 A1 FR 2012552A1 FR 6922961 A FR6922961 A FR 6922961A FR 6922961 A FR6922961 A FR 6922961A FR 2012552 A1 FR2012552 A1 FR 2012552A1
- Authority
- FR
- France
- Prior art keywords
- tert
- ether
- primary
- alcohol
- prodn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 150000001336 alkenes Chemical group 0.000 title abstract 2
- 238000005342 ion exchange Methods 0.000 title abstract 2
- 238000000746 purification Methods 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 8
- 150000003138 primary alcohols Chemical class 0.000 abstract 3
- 229910006069 SO3H Inorganic materials 0.000 abstract 2
- 150000005673 monoalkenes Chemical class 0.000 abstract 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 abstract 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003729 cation exchange resin Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
- C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/14875—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with organic compounds
- C07C7/14891—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with organic compounds alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
- C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3261268A GB1176620A (en) | 1968-07-09 | 1968-07-09 | Recovery of Tertiary Olefins |
GB3261368A GB1165479A (en) | 1968-07-09 | 1968-07-09 | Process for the Preparation of Tertiary Monoolefins |
GB3261568A GB1272585A (en) | 1968-07-09 | 1968-07-09 | Process for carrying ot exothermic catalytic reactions and an apparatus therefor |
GB4474968A GB1173128A (en) | 1968-09-20 | 1968-09-20 | Process for the preparation of Olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2012552A1 true FR2012552A1 (en) | 1970-03-20 |
Family
ID=27448825
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR6922961A Withdrawn FR2012552A1 (en) | 1968-07-09 | 1969-07-07 | Tertiary olefins prodn and purification - using an ion-exchange catalyst |
Country Status (6)
Country | Link |
---|---|
BE (1) | BE735740A (enrdf_load_stackoverflow) |
CA (1) | CA929537A (enrdf_load_stackoverflow) |
DE (1) | DE1934422C3 (enrdf_load_stackoverflow) |
FR (1) | FR2012552A1 (enrdf_load_stackoverflow) |
NL (1) | NL160234C (enrdf_load_stackoverflow) |
SE (1) | SE349559B (enrdf_load_stackoverflow) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0008860A1 (en) * | 1978-07-27 | 1980-03-19 | CHEMICAL RESEARCH & LICENSING COMPANY | Catalyst system |
FR2440931A1 (fr) * | 1978-11-08 | 1980-06-06 | Inst Francais Du Petrole | Procede de production d'ethers par reaction d'olefines avec des alcools |
FR2520356A1 (fr) * | 1982-01-26 | 1983-07-29 | Inst Francais Du Petrole | Procede de valorisation des coupes c4 olefiniques |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5168512A (enrdf_load_stackoverflow) * | 1974-12-02 | 1976-06-14 | Texaco Development Corp | |
DE2802199C3 (de) * | 1978-01-19 | 1987-12-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Gewinnung von Isobuten aus Isobuten enthaltenden C↓4↓-Kohlenwasserstoffgemischen |
FR2449074A1 (fr) * | 1979-02-14 | 1980-09-12 | Inst Francais Du Petrole | Procede de production et d'isolement de methyl tertiobutyl ether |
DE2928509A1 (de) * | 1979-07-14 | 1981-01-29 | Basf Ag | Verfahren zur gemeinsamen herstellung von methyl-tert.-butylaether und gewinnung von isobuten |
DE2928510A1 (de) * | 1979-07-14 | 1981-01-29 | Basf Ag | Verfahren zur gewinnung von isobuten aus isobuten enthaltenden c tief 4 -kohlenwasserstoffgemischen |
FR2481269A1 (fr) * | 1980-04-28 | 1981-10-30 | Inst Francais Du Petrole | Procede de production d'ethers par reaction d'olefines avec des alcools |
JPS57209233A (en) * | 1981-06-19 | 1982-12-22 | Sumitomo Chem Co Ltd | Decomposing method of methyl-tert-butyl ether |
US4950803A (en) * | 1982-11-17 | 1990-08-21 | Chemical Research & Licensing Company | Etherification process |
DE3509292A1 (de) * | 1985-03-15 | 1985-12-05 | Ulrich 3300 Braunschweig Haupt | Verfahren zur herstellung von reinen tertiaeren olefinen |
US5118873A (en) * | 1990-11-19 | 1992-06-02 | Chemical Research & Licensing Company | Process for the preparation of mtbe |
US7320745B2 (en) | 2005-01-19 | 2008-01-22 | Catalytic Distillation Technologies | Energy efficient method for exothermic reactions |
DE102009027404A1 (de) | 2009-07-01 | 2011-01-05 | Evonik Oxeno Gmbh | Herstellung von Isobuten durch Spaltung von MTBE |
CN108409517B (zh) * | 2018-02-24 | 2020-10-20 | 安徽海德化工科技有限公司 | 一种利用甲基叔丁基醚催化裂解制备异丁烯的方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE733750C (de) * | 1940-08-30 | 1943-04-01 | Wacker Chemie Gmbh | Verfahren zur Herstellung von Tetrachloraethan |
DE908247C (de) * | 1942-08-11 | 1954-04-05 | Gaeneral Electric Company | Verfahren zur Entfernung von Kationen aus fluessigen Medien |
US2480940A (en) * | 1946-09-20 | 1949-09-06 | Atlantic Refining Co | Production of aliphatic ethers |
DE1113570B (de) * | 1957-04-20 | 1961-09-07 | Bayer Ag | Verfahren zur Herstellung von Kationenaustauschern auf Basis von nicht sprosspolymerisierten vernetzten Polymerisaten |
BE590370A (enrdf_load_stackoverflow) * | 1959-04-29 | 1900-01-01 | ||
DE1168081B (de) * | 1960-01-21 | 1964-04-16 | Bayer Ag | Verfahren zur Erhoehung der Kapazitaet von maximal eine Sulfonsaeuregruppe pro Arylkern enthaltenden Kationenaustauschern |
FR1256388A (fr) * | 1960-05-04 | 1961-03-17 | Sinclair Refining Co | Procédé de préparation d'oléfines tertiaires |
DE1224294B (de) * | 1961-01-09 | 1966-09-08 | Bayer Ag | Verfahren zur Herstellung von tertiaeren Butylalkylaethern |
-
1969
- 1969-07-07 SE SE956669A patent/SE349559B/xx unknown
- 1969-07-07 NL NL6910382A patent/NL160234C/xx not_active IP Right Cessation
- 1969-07-07 FR FR6922961A patent/FR2012552A1/fr not_active Withdrawn
- 1969-07-07 CA CA056379A patent/CA929537A/en not_active Expired
- 1969-07-07 DE DE19691934422 patent/DE1934422C3/de not_active Expired
- 1969-07-07 BE BE735740D patent/BE735740A/xx not_active IP Right Cessation
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0008860A1 (en) * | 1978-07-27 | 1980-03-19 | CHEMICAL RESEARCH & LICENSING COMPANY | Catalyst system |
FR2440931A1 (fr) * | 1978-11-08 | 1980-06-06 | Inst Francais Du Petrole | Procede de production d'ethers par reaction d'olefines avec des alcools |
FR2520356A1 (fr) * | 1982-01-26 | 1983-07-29 | Inst Francais Du Petrole | Procede de valorisation des coupes c4 olefiniques |
Also Published As
Publication number | Publication date |
---|---|
DE1934422A1 (de) | 1970-01-15 |
DE1934422B2 (de) | 1978-08-31 |
CA929537A (en) | 1973-07-03 |
NL160234B (nl) | 1979-05-15 |
SE349559B (enrdf_load_stackoverflow) | 1972-10-02 |
NL6910382A (enrdf_load_stackoverflow) | 1970-01-13 |
DE1934422C3 (de) | 1984-04-26 |
BE735740A (enrdf_load_stackoverflow) | 1970-01-07 |
NL160234C (nl) | 1979-10-15 |
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FR2012552A1 (en) | Tertiary olefins prodn and purification - using an ion-exchange catalyst | |
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BE879801A (fr) | Procede de production d'ethers par reaction d'olefines avec des alcools | |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |