FI87796B - Limblandningar foer anvaendning pao vinylsubstrat och med dylika bestrukna substrat - Google Patents

Limblandningar foer anvaendning pao vinylsubstrat och med dylika bestrukna substrat Download PDF

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Publication number
FI87796B
FI87796B FI880438A FI880438A FI87796B FI 87796 B FI87796 B FI 87796B FI 880438 A FI880438 A FI 880438A FI 880438 A FI880438 A FI 880438A FI 87796 B FI87796 B FI 87796B
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FI
Finland
Prior art keywords
weight
acid
contact adhesive
vinyl
polymer
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Application number
FI880438A
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English (en)
Finnish (fi)
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FI880438A (fi
FI880438A0 (fi
FI87796C (sv
Inventor
Paul R Mudge
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Nat Starch Chem Corp
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Application filed by Nat Starch Chem Corp filed Critical Nat Starch Chem Corp
Publication of FI880438A0 publication Critical patent/FI880438A0/fi
Publication of FI880438A publication Critical patent/FI880438A/fi
Publication of FI87796B publication Critical patent/FI87796B/fi
Application granted granted Critical
Publication of FI87796C publication Critical patent/FI87796C/sv

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852—Adhesive compositions
    • Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852—Adhesive compositions
    • Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
    • Y10T428/2887—Adhesive compositions including addition polymer from unsaturated monomer including nitrogen containing polymer [e.g., polyacrylonitrile, polymethacrylonitrile, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852—Adhesive compositions
    • Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
    • Y10T428/2891—Adhesive compositions including addition polymer from unsaturated monomer including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer
    • Y10T428/3192—Next to vinyl or vinylidene chloride polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
  • Materials For Medical Uses (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Adhesive Tapes (AREA)

Claims (15)

1. Plasti ficerade polyvinylkloridsubstrat som är bestrukna med en kontaktlimblandning, kännetecknade av att blandningen innehaller en polymeremulsion gjord av 30... 70 vikt-% vinylester av en alkansyra; 10. . . 30 vikt-% etylen; 20... 40 vikt-% di-2-etylhexylmaleat eller motsvarande fumarat; och 1. . . 10 vikt-% omättad monokarboxylsyra.
2. Substrat enligt patentkravet 1, kännetecknatav att polyvinylkloridsubstratet är plastificerat med en migre-rande mj ukgörare.
3. Substrat enligt patentkravet 2, kännetecknatav att mjukgöraren är en ftalatester, en polyester eller en epoxi-derad soijaolja.
4. Substrat enligt patentkravet 1, kännetecknatav att polymeren ytterligare innehaller upp tili 5 % av en sam-polymeriserbar sammonomer som valts bland akrylamid, allyl-karbamat, N-metylol(met)akrylamid, N-vinylpyrrolidinon, di-allyladipat, triallylcyanurat, butandioldiakrylat, allylmetakrylat, hydroxietylakrylat, hydroxipropylakrylat och } ie 87796 motsvarande metakrylater, varvid mängden sammonomer är sadan, att limmets Tw bibehälls inom omradet mellan -45 och -25 *C.
5. Substrat enligt patentkravet 1, kännetecknat av att vinylestern i polymeren är vinylacetat.
5. Substrat enligt patentkravet 1, kännetecknatav att syran i polymeren är akrylsyra eller metakrylsyra eller en halvester av maleinsyra.
7. Substrat enligt patentkravet 1, kännetecknat av att mängden vinylester är 40. . . 60 vikt-% och att mängden maleat 25. . . 35 vikt-%.
8. Substrat enligt patentkravet 1, kännetecknat av att den sampolymeriserbara sammonomeren är hydroxietylakry-lat eller hydroxipropylakrylat.
9. Kontaktlimblandningar, kännetecknade av att deras T9 är mellan -45 och -25 ’ C och att de är lämpliga for bestrykning pa plastificerade polyvinylkloridfilmer och att de bestär väsentligen av en polymeremulsion gjord av 30... 70 vikt-% vinylester av en alkansyra; 10. . . 30 vikt-% etylen; 20. . . 40 vikt-% di-2-etylhexylmaleat eller motsvarande fumarat; och 1. .. 10 vikt-% omättad monokarboxylsyra samt 0. . . 10 vikt-% sampolymeriserbar sammonomer som valts bland akrylamid, allyl-karbamat, N-metylol(met)akrylamid, N-vinylpyrrolidinon, di-allyladipat, triallylcyanurat, butandioldiakrylat, allyl-metakrylat, hydroxietylkrylat, hydroxipropylakrylat och motsvarande metakrylater.
10. Kontaktlimblandning enligt patentkravet 9, k ä n n e -tecknad av att polymeren ytterligare innehäller upp tili 5 % av en sampolymeriserbar sammonomer som valts bland akrylamid, allylkarbamat, N-metylol(met)akrylamid, N-vinylpyrrolidinon, diallyladipat, triallylcyanurat, butandioldiakrylat, allylmetakrylat, hydroxietylakrylat, hydroxipropylakrylat och
17 H 7 796 motsvarande metakrylater, varvid mängden sammonomer är sadan, att limmets T* bibehälls inom omrädet mellan -45 och -25 ’ C.
11. Kontaktiimblandning enligt patentkravet 9, k ä n n e - tecknad av att vinylestern i polymeren är vinylacetat.
12. Kontaktlimblandning enligt patentkravet 9, k ä n n e - tecknad av att syran i polymeren är akrylsyra eller metakrylsyra eller en halvester av maleinsyra.
13. Kontaktlimblandning enligt patentkravet 9, k ä n n e - tecknad av att mängden vinylester är 40... 60 vikt-% och att mängden maleat 25...35 vikt-%.
14. Kontaktlimblandning enligt patentkravet 9, k ä n n e -tecknad av att den sampolymeriserbara sammonomeren är hydroxietylakrylat eller hydroxipropylakrylat.
FI880438A 1987-02-02 1988-02-01 Limblandningar för användning på vinylsubstrat och med dylika bestrukn a substrat FI87796C (sv)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US945087 1987-02-02
US07/009,450 US4753846A (en) 1987-02-02 1987-02-02 Adhesive compositions for use on vinyl substrates

Publications (4)

Publication Number Publication Date
FI880438A0 FI880438A0 (fi) 1988-02-01
FI880438A FI880438A (fi) 1988-08-03
FI87796B true FI87796B (fi) 1992-11-13
FI87796C FI87796C (sv) 1993-02-25

Family

ID=21737734

Family Applications (1)

Application Number Title Priority Date Filing Date
FI880438A FI87796C (sv) 1987-02-02 1988-02-01 Limblandningar för användning på vinylsubstrat och med dylika bestrukn a substrat

Country Status (11)

Country Link
US (1) US4753846A (sv)
EP (1) EP0277516B1 (sv)
JP (1) JPS63243188A (sv)
AT (1) ATE67771T1 (sv)
AU (1) AU588721B2 (sv)
CA (1) CA1323128C (sv)
DE (1) DE3865030D1 (sv)
ES (1) ES2025217B3 (sv)
FI (1) FI87796C (sv)
GR (1) GR3002789T3 (sv)
MY (1) MY103171A (sv)

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US4961993A (en) * 1988-03-17 1990-10-09 National Starch And Chemical Investment Holding Corporation Ethylene vinyl acetate-dioctyl maleate-2-ethylhexyl acrylate interpolymers
US4939220A (en) * 1988-03-17 1990-07-03 National Starch And Chemical Investment Holding Corporation Ethylene vinyl acetate-dioctyl maleate-2-ethylhexyl acrylate interpolymers
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US5120785A (en) * 1988-10-28 1992-06-09 National Starch And Chemical Investment Holding Corporation Ethylene vinyl acetate polymers for latex caulks
US4943461A (en) * 1989-02-01 1990-07-24 Minnesota Mining And Manufacturing Company Radiation-curable pressure-sensitive adhesive having improved adhesion to plasticized vinyl substrates
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US5079047A (en) * 1989-05-12 1992-01-07 Minnesota Mining And Manufacturing Company Radiation-curable pressure-sensitive adhesive having improved adhesion to plasticized vinyl substrates
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Also Published As

Publication number Publication date
JPS63243188A (ja) 1988-10-11
FI880438A (fi) 1988-08-03
ATE67771T1 (de) 1991-10-15
EP0277516A2 (en) 1988-08-10
AU1094888A (en) 1988-08-04
AU588721B2 (en) 1989-09-21
GR3002789T3 (en) 1993-01-25
EP0277516B1 (en) 1991-09-25
DE3865030D1 (de) 1991-10-31
CA1323128C (en) 1993-10-12
US4753846A (en) 1988-06-28
FI880438A0 (fi) 1988-02-01
EP0277516A3 (en) 1989-05-10
MY103171A (en) 1993-04-30
ES2025217B3 (es) 1992-03-16
FI87796C (sv) 1993-02-25

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