GB1123879A - Terpolymer pour point depressant and method of manufacture - Google Patents

Terpolymer pour point depressant and method of manufacture

Info

Publication number
GB1123879A
GB1123879A GB4659266A GB4659266A GB1123879A GB 1123879 A GB1123879 A GB 1123879A GB 4659266 A GB4659266 A GB 4659266A GB 4659266 A GB4659266 A GB 4659266A GB 1123879 A GB1123879 A GB 1123879A
Authority
GB
United Kingdom
Prior art keywords
terpolymer
weight
per cent
ethylene
weight per
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4659266A
Inventor
Stephan Ilnyckyj
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Priority to GB4659266A priority Critical patent/GB1123879A/en
Publication of GB1123879A publication Critical patent/GB1123879A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
    • C10L1/1966—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof poly-carboxylic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

A terpolymer comprises from 30 to 85 weight per cent of ethylene, from 10 to 40 weight per cent of an olefinically unsaturated C3-C5 alipathic ester of a monocarboxylic acid and from 5 to 30 weight per cent of an ester of an ethylene-dicarboxylic acid and a C1-C24 monohydric alcohol, said terpolymer having a molecular weight in the range of from 1000 to 4000. Hydrocarbon compositions may comprise a major proportion by weight of a petroleum distillate fuel boiling within the range between 250 DEG and 750 DEG F. and a minor proportion by weight of oil-soluble terpolymer. The terpolymer may be prepared by polymerizing the monomers in a hydrocarbon solvent at pressures of from 500 to 1500 p.s.i. and temperature of from 250 DEG to 350 DEG F., using a peroxide catalyst for 3 to 24 hours. Suitable esters of an ethylene-dicarboxylic acid are C4-C18 dialkyl fumarates and C13 oxo fumarates. In the example were used vinyl acetate, dilauryl fumarate, ditert butyl peroxide and benzene.ALSO:Hydrocarbon compositions comprise a major proportion by weight of a petroleum distillate fuel boiling within the range between 250 DEG and 750 DEG F. and a minor proportion by weight of an oil-soluble terpolymer pour point depressant comprising from 30 to 85 weight per cent of ethylene, from 10 to 40 weight per cent of an olefinically unsaturated C3-C5 aliphatic ester of a monocarboxylic acid and from 5 to 30 weight per cent of an ester of an ethylenedicarboxylic acid and a C1-C24 monohydric alcohol, said terpolymer having a molecular weight in the range of from 1000 to 4000. Preferably, the terpolymer is used in a concentration of from 0.001 to 0.09% by weight. In the example, an ethylene/vinyl acetate/dilauryl fumarate terpolymer is used in a middle distillate gas oil.
GB4659266A 1966-10-18 1966-10-18 Terpolymer pour point depressant and method of manufacture Expired GB1123879A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB4659266A GB1123879A (en) 1966-10-18 1966-10-18 Terpolymer pour point depressant and method of manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4659266A GB1123879A (en) 1966-10-18 1966-10-18 Terpolymer pour point depressant and method of manufacture

Publications (1)

Publication Number Publication Date
GB1123879A true GB1123879A (en) 1968-08-14

Family

ID=10441864

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4659266A Expired GB1123879A (en) 1966-10-18 1966-10-18 Terpolymer pour point depressant and method of manufacture

Country Status (1)

Country Link
GB (1) GB1123879A (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4692366A (en) * 1986-09-08 1987-09-08 National Starch And Chemical Corporation Flocking adhesives based on eva-maleate copolymers
US4740394A (en) * 1986-09-08 1988-04-26 National Starch And Chemical Corporation Textile coatings based on eva-maleate copolymers
US4753846A (en) * 1987-02-02 1988-06-28 National Starch And Chemical Corporation Adhesive compositions for use on vinyl substrates
US4812547A (en) * 1985-12-11 1989-03-14 National Starch & Chemical Corp. Pressure sensitive adhesives comprising ethylene vinyl acetate dioctyl maleate terpolymers
US4826938A (en) * 1988-04-21 1989-05-02 National Starch And Chemical Corporation Substrates coated with pressure sensitive adhesives comprising ethylene vinyl acetate dioctyl maleate polymers
US4829139A (en) * 1988-04-21 1989-05-09 National Starch And Chemical Corporation Pressure sensitive adhesives comprising ethylene vinyl acetate dioctyl maleate terpolymers
US4892917A (en) * 1987-02-02 1990-01-09 National Starch And Chemical Corporation Adhesive compositions for use on vinyl substrates
US4908268A (en) * 1988-03-17 1990-03-13 National Starch And Chemical Corporation Ethylene vinyl acetate-dioctyl maleate-2-ethylhexyl acrylate interpolymers
US4911960A (en) * 1988-01-19 1990-03-27 National Starch And Chemical Corporation Laminating adhesive for film/paper microwavable products
US4939220A (en) * 1988-03-17 1990-07-03 National Starch And Chemical Investment Holding Corporation Ethylene vinyl acetate-dioctyl maleate-2-ethylhexyl acrylate interpolymers
US4961993A (en) * 1988-03-17 1990-10-09 National Starch And Chemical Investment Holding Corporation Ethylene vinyl acetate-dioctyl maleate-2-ethylhexyl acrylate interpolymers
GB2622942A (en) * 2022-08-09 2024-04-03 Innospec Fuel Specialties Llc Improvements in fuels

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4812547A (en) * 1985-12-11 1989-03-14 National Starch & Chemical Corp. Pressure sensitive adhesives comprising ethylene vinyl acetate dioctyl maleate terpolymers
US4692366A (en) * 1986-09-08 1987-09-08 National Starch And Chemical Corporation Flocking adhesives based on eva-maleate copolymers
US4740394A (en) * 1986-09-08 1988-04-26 National Starch And Chemical Corporation Textile coatings based on eva-maleate copolymers
US4753846A (en) * 1987-02-02 1988-06-28 National Starch And Chemical Corporation Adhesive compositions for use on vinyl substrates
US4892917A (en) * 1987-02-02 1990-01-09 National Starch And Chemical Corporation Adhesive compositions for use on vinyl substrates
US4911960A (en) * 1988-01-19 1990-03-27 National Starch And Chemical Corporation Laminating adhesive for film/paper microwavable products
US4908268A (en) * 1988-03-17 1990-03-13 National Starch And Chemical Corporation Ethylene vinyl acetate-dioctyl maleate-2-ethylhexyl acrylate interpolymers
US4939220A (en) * 1988-03-17 1990-07-03 National Starch And Chemical Investment Holding Corporation Ethylene vinyl acetate-dioctyl maleate-2-ethylhexyl acrylate interpolymers
US4961993A (en) * 1988-03-17 1990-10-09 National Starch And Chemical Investment Holding Corporation Ethylene vinyl acetate-dioctyl maleate-2-ethylhexyl acrylate interpolymers
US4826938A (en) * 1988-04-21 1989-05-02 National Starch And Chemical Corporation Substrates coated with pressure sensitive adhesives comprising ethylene vinyl acetate dioctyl maleate polymers
US4829139A (en) * 1988-04-21 1989-05-09 National Starch And Chemical Corporation Pressure sensitive adhesives comprising ethylene vinyl acetate dioctyl maleate terpolymers
GB2622942A (en) * 2022-08-09 2024-04-03 Innospec Fuel Specialties Llc Improvements in fuels

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