FI80473C - Stabil, haellbar, flytande tvaettmedelskomposition. - Google Patents
Stabil, haellbar, flytande tvaettmedelskomposition. Download PDFInfo
- Publication number
- FI80473C FI80473C FI845098A FI845098A FI80473C FI 80473 C FI80473 C FI 80473C FI 845098 A FI845098 A FI 845098A FI 845098 A FI845098 A FI 845098A FI 80473 C FI80473 C FI 80473C
- Authority
- FI
- Finland
- Prior art keywords
- composition
- surfactant
- salt
- electrolyte
- stable
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 343
- 239000003599 detergent Substances 0.000 title claims description 60
- 239000007788 liquid Substances 0.000 title claims description 44
- 239000003792 electrolyte Substances 0.000 claims description 111
- 239000004094 surface-active agent Substances 0.000 claims description 93
- 239000003623 enhancer Substances 0.000 claims description 61
- 239000007787 solid Substances 0.000 claims description 56
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 53
- 150000003839 salts Chemical class 0.000 claims description 38
- 239000002245 particle Substances 0.000 claims description 13
- 230000007423 decrease Effects 0.000 claims description 11
- 239000000693 micelle Substances 0.000 claims description 11
- 230000000694 effects Effects 0.000 claims description 10
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 8
- 239000012071 phase Substances 0.000 description 102
- 239000004480 active ingredient Substances 0.000 description 94
- -1 by chelating Chemical compound 0.000 description 45
- 238000009472 formulation Methods 0.000 description 27
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 26
- 238000005406 washing Methods 0.000 description 26
- 238000005119 centrifugation Methods 0.000 description 23
- 239000004615 ingredient Substances 0.000 description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 20
- 239000000243 solution Substances 0.000 description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 18
- 125000000217 alkyl group Chemical group 0.000 description 18
- 235000019832 sodium triphosphate Nutrition 0.000 description 18
- 239000011734 sodium Substances 0.000 description 17
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 16
- 239000003945 anionic surfactant Substances 0.000 description 15
- 229910052708 sodium Inorganic materials 0.000 description 15
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 14
- 150000001412 amines Chemical class 0.000 description 13
- 229910000029 sodium carbonate Inorganic materials 0.000 description 13
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 12
- 239000008346 aqueous phase Substances 0.000 description 12
- 239000003752 hydrotrope Substances 0.000 description 12
- 239000002736 nonionic surfactant Substances 0.000 description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 11
- 239000004115 Sodium Silicate Substances 0.000 description 11
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- 239000003795 chemical substances by application Substances 0.000 description 11
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- 125000003342 alkenyl group Chemical group 0.000 description 10
- 125000000129 anionic group Chemical group 0.000 description 10
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- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 10
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- 239000002904 solvent Substances 0.000 description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
- 238000011049 filling Methods 0.000 description 8
- 230000001965 increasing effect Effects 0.000 description 8
- 229910052700 potassium Inorganic materials 0.000 description 8
- 239000011591 potassium Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000004062 sedimentation Methods 0.000 description 8
- 150000004760 silicates Chemical class 0.000 description 8
- 239000004317 sodium nitrate Substances 0.000 description 8
- 235000010344 sodium nitrate Nutrition 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 7
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 7
- 150000004996 alkyl benzenes Chemical class 0.000 description 7
- 229940077388 benzenesulfonate Drugs 0.000 description 7
- 230000003287 optical effect Effects 0.000 description 7
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 7
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 6
- 239000000872 buffer Substances 0.000 description 6
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- 238000000034 method Methods 0.000 description 6
- 238000001683 neutron diffraction Methods 0.000 description 6
- 239000013049 sediment Substances 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 6
- 230000035882 stress Effects 0.000 description 6
- 229910021653 sulphate ion Inorganic materials 0.000 description 6
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- 239000013543 active substance Substances 0.000 description 5
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- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 150000001340 alkali metals Chemical class 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 5
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 239000007983 Tris buffer Substances 0.000 description 4
- 229910021536 Zeolite Inorganic materials 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000008051 alkyl sulfates Chemical class 0.000 description 4
- 239000002518 antifoaming agent Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 0 CC1=*CCCC1 Chemical compound CC1=*CCCC1 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
- 239000002671 adjuvant Substances 0.000 description 3
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- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000004665 cationic fabric softener Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
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- 238000001000 micrograph Methods 0.000 description 3
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- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
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- 230000009467 reduction Effects 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
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- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 description 2
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- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
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- LRMHFDNWKCSEQU-UHFFFAOYSA-N ethoxyethane;phenol Chemical compound CCOCC.OC1=CC=CC=C1 LRMHFDNWKCSEQU-UHFFFAOYSA-N 0.000 description 2
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- 230000005484 gravity Effects 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
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- 150000002823 nitrates Chemical class 0.000 description 2
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000005185 salting out Methods 0.000 description 2
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical group [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 2
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- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 2
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- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
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- BCFOOQRXUXKJCL-UHFFFAOYSA-N 4-amino-4-oxo-2-sulfobutanoic acid Chemical class NC(=O)CC(C(O)=O)S(O)(=O)=O BCFOOQRXUXKJCL-UHFFFAOYSA-N 0.000 description 1
- VKRZNAWSCAUDRQ-BQYQJAHWSA-N 5-methyl-2-[(e)-2-(5-methyl-1,3-benzoxazol-2-yl)ethenyl]-1,3-benzoxazole Chemical group CC1=CC=C2OC(/C=C/C=3OC4=CC=C(C=C4N=3)C)=NC2=C1 VKRZNAWSCAUDRQ-BQYQJAHWSA-N 0.000 description 1
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- 238000005481 NMR spectroscopy Methods 0.000 description 1
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- 102100034492 Serine/threonine-protein phosphatase 4 catalytic subunit Human genes 0.000 description 1
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- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
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- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
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- HJMZMZRCABDKKV-UHFFFAOYSA-N carbonocyanidic acid Chemical class OC(=O)C#N HJMZMZRCABDKKV-UHFFFAOYSA-N 0.000 description 1
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- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
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- 230000008570 general process Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 125000005908 glyceryl ester group Chemical group 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- DZVYKHCNKURSHC-UHFFFAOYSA-N hexadecylbenzene;potassium Chemical compound [K].CCCCCCCCCCCCCCCCC1=CC=CC=C1 DZVYKHCNKURSHC-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000003893 lactate salts Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007937 lozenge Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
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- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000005528 methosulfate group Chemical group 0.000 description 1
- 229920000609 methyl cellulose Chemical class 0.000 description 1
- 239000001923 methylcellulose Chemical class 0.000 description 1
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- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
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- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
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- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 150000002942 palmitic acid derivatives Chemical class 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
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- 238000000053 physical method Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000002797 proteolythic effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 1
- TZGWRTOSBWDHPO-UHFFFAOYSA-M sodium;4-dodecyl-2,3-dimethylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C(C)=C1C TZGWRTOSBWDHPO-UHFFFAOYSA-M 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-M toluenesulfonate group Chemical group C=1(C(=CC=CC1)S(=O)(=O)[O-])C LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical class [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0026—Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB838334250A GB8334250D0 (en) | 1983-12-22 | 1983-12-22 | Liquid detergent compositions |
| GB8334250 | 1983-12-22 | ||
| US57663284A | 1984-02-03 | 1984-02-03 | |
| US57663284 | 1984-02-03 | ||
| GB8415783 | 1984-06-20 | ||
| GB848415783A GB8415783D0 (en) | 1984-06-20 | 1984-06-20 | Liquid detergent compositions |
| GB848421759A GB8421759D0 (en) | 1984-08-28 | 1984-08-28 | Liquid detergent compositions |
| GB8421759 | 1984-08-28 |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI845098A0 FI845098A0 (fi) | 1984-12-21 |
| FI845098L FI845098L (fi) | 1985-06-23 |
| FI80473B FI80473B (fi) | 1990-02-28 |
| FI80473C true FI80473C (fi) | 1990-06-11 |
Family
ID=27449526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI845098A FI80473C (fi) | 1983-12-22 | 1984-12-21 | Stabil, haellbar, flytande tvaettmedelskomposition. |
Country Status (26)
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EG18543A (en) * | 1986-02-20 | 1993-07-30 | Albright & Wilson | Protected enzyme systems |
| GB8713574D0 (en) * | 1987-06-10 | 1987-07-15 | Albright & Wilson | Liquid detergent compositions |
| GB8803037D0 (en) * | 1988-02-10 | 1988-03-09 | Unilever Plc | Aqueous detergent compositions & methods of forming them |
| GB8804590D0 (en) * | 1988-02-26 | 1988-03-30 | Unilever Plc | Detergent compositions |
| JPH0234700A (ja) * | 1988-06-13 | 1990-02-05 | Unilever Nv | 液体洗剤組成物 |
| CA1335646C (en) * | 1988-06-13 | 1995-05-23 | Guido Clemens Van Den Brom | Liquid detergent compositions |
| GB8818704D0 (en) * | 1988-08-05 | 1988-09-07 | Albright & Wilson | Liquid cleaning compositions |
| GB8904007D0 (en) * | 1989-02-22 | 1989-04-05 | Procter & Gamble | Stabilized,bleach containing,liquid detergent compositions |
| EP0385522B1 (en) * | 1989-02-27 | 2001-08-29 | Unilever N.V. | Liquid detergent composition |
| GB8906234D0 (en) | 1989-03-17 | 1989-05-04 | Albright & Wilson | Agrochemical suspensions |
| FI921570A7 (fi) * | 1989-10-12 | 1992-04-09 | Unilever Nv | Nestemäiset pesuaineet |
| GB8924478D0 (en) * | 1989-10-31 | 1989-12-20 | Unilever Plc | Detergent compositions |
| GB2245262A (en) * | 1990-06-22 | 1992-01-02 | Unilever Plc | Aluminosilicate slurries l |
| GB2247028B (en) * | 1990-08-15 | 1994-06-08 | Albright & Wilson | Dye suspensions |
| FR2666344B1 (fr) * | 1990-09-03 | 1992-12-18 | Total France | Procede d'adoucissement en lit fixe de distillats petroliers acides de temperatures de coupe comprises entre environ 125 et environ 350 degre c. |
| GB9102757D0 (en) * | 1991-02-08 | 1991-03-27 | Albright & Wilson | Biocidal and agrochemical suspensions |
| IN185580B (enrdf_load_stackoverflow) * | 1991-08-30 | 2001-03-03 | Albright & Wilson Uk Ltd | |
| GB2259519B (en) * | 1991-08-30 | 1996-03-06 | Albright & Wilson | Concentrated aqueous surfactant compositions |
| SK53294A3 (en) | 1993-05-07 | 1995-04-12 | Albright & Wilson | Concentrated aqueous mixture containing surface active matter and its use |
| US6166095A (en) * | 1993-12-15 | 2000-12-26 | Albright & Wilson Uk Limited | Method of preparing a drilling fluid comprising structured surfactants |
| DZ1837A1 (fr) * | 1993-12-15 | 2002-02-17 | Albright & Wilson | Surfactants structures. |
| EP0759062B1 (en) * | 1994-05-13 | 1999-01-20 | Unilever N.V. | Detergent composition |
| US5529724A (en) * | 1995-02-06 | 1996-06-25 | Lever Brothers Company, Division Of Conopco, Inc. | Structured liquid compositions comprising selected secondary alcohol sulfates and a deflocculating polymer |
| EP0776965A3 (en) | 1995-11-30 | 1999-02-03 | Unilever N.V. | Polymer compositions |
| US5759290A (en) * | 1996-06-13 | 1998-06-02 | Colgate Palmolive Company | Liquid crystal compositions |
| US6133217A (en) * | 1998-08-28 | 2000-10-17 | Huntsman Petrochemical Corporation | Solubilization of low 2-phenyl alkylbenzene sulfonates |
| US6083897A (en) * | 1998-08-28 | 2000-07-04 | Huntsman Petrochemical Corporation | Solubilization of low 2-phenyl alkylbenzene sulfonates |
| ATE250121T1 (de) * | 1998-12-16 | 2003-10-15 | Unilever Nv | Strukturierte flüssige waschmittelzusammensetzung |
| AU2495400A (en) | 1999-01-11 | 2000-08-01 | Huntsman Petrochemical Corporation | Surfactant compositions containing alkoxylated amines |
| US6897188B2 (en) | 2001-07-17 | 2005-05-24 | Ecolab, Inc. | Liquid conditioner and method for washing textiles |
| IL162227A0 (en) | 2001-12-21 | 2005-11-20 | Rhodia | Stable surfactant compositions for suspending components |
| GB0229502D0 (en) * | 2002-12-19 | 2003-01-22 | Unilever Plc | Detergent composition |
| GB0229503D0 (en) * | 2002-12-19 | 2003-01-22 | Unilever Plc | Detergent composition |
| US8110537B2 (en) | 2003-01-14 | 2012-02-07 | Ecolab Usa Inc. | Liquid detergent composition and methods for using |
| US7682403B2 (en) | 2004-01-09 | 2010-03-23 | Ecolab Inc. | Method for treating laundry |
| WO2007001341A2 (en) | 2005-06-24 | 2007-01-04 | Rhodia, Inc. | Structured surfactant compositions |
| GB2434586A (en) * | 2006-01-24 | 2007-08-01 | Henkel Uk | Structured liquid abrasive composition |
| WO2008047148A1 (en) * | 2006-10-20 | 2008-04-24 | Innovation Deli Limited | Skin cleansing compositions |
| DK2308957T3 (da) | 2006-12-15 | 2013-05-13 | Colgate Palmolive Co | Flydende vaskemiddel-sammensætning |
| US8809245B2 (en) * | 2010-12-14 | 2014-08-19 | Robert E. Hill | Remedial composition and treatment method |
| US20130029895A1 (en) | 2011-07-27 | 2013-01-31 | Jean-Luc Phillippe Bettiol | Multiphase liquid detergent composition |
| WO2013064356A1 (de) * | 2011-11-02 | 2013-05-10 | Henkel Ag & Co. Kgaa | STRUKTURIERTES WASCH- ODER REINIGUNGSMITTEL MIT FLIEßGRENZE |
| GB201202333D0 (en) | 2012-02-10 | 2012-03-28 | Stepan Co | Structured surfactant suspending systems |
| DE102012219218A1 (de) * | 2012-10-22 | 2014-04-24 | Henkel Ag & Co. Kgaa | Tensid-haltige Schäume |
| US10494591B2 (en) | 2017-06-22 | 2019-12-03 | Ecolab Usa Inc. | Bleaching using peroxyformic acid and an oxygen catalyst |
| CN112900081B (zh) * | 2021-02-02 | 2022-05-24 | 天津大学 | 一种疏水球晶、疏水材料、疏水复合材料、Janus复合材料及其制备方法和应用 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB948617A (en) * | 1959-10-30 | 1964-02-05 | Unilever Ltd | Stabilised liquid detergent compositions |
| US3623990A (en) * | 1967-06-26 | 1971-11-30 | Procter & Gamble | Liquid detergent composition |
| GB1468181A (en) * | 1973-10-11 | 1977-03-23 | Unilever Ltd | Liquid detergent composition |
| GB1506427A (en) * | 1975-04-29 | 1978-04-05 | Unilever Ltd | Liquid detergent |
| NZ191283A (en) * | 1978-08-21 | 1982-03-09 | Colgate Palmolive Co | Stable pourable heavy-duty built liquid detergent comprising optical brightening agent or water soluble dye |
| US4452717A (en) * | 1980-04-09 | 1984-06-05 | Lever Brothers Company | Built liquid detergent compositions and method of preparation |
| AU547579B2 (en) * | 1981-11-13 | 1985-10-24 | Unilever Plc | Low foaming liquid detergent composition |
| EP0080221B1 (en) * | 1981-11-13 | 1985-07-24 | Unilever N.V. | Stable liquid detergent suspensions |
| IS1740B (is) * | 1982-02-05 | 1999-12-31 | Albright & Wilson Uk Limited | Samsetning á hreinsivökva |
| DE3240088A1 (de) * | 1982-10-29 | 1984-05-03 | Henkel KGaA, 4000 Düsseldorf | Stabile waessrige reinigungsmittel und verfahren zu ihrer herstellung |
-
1984
- 1984-12-19 MX MX20380584A patent/MX167884B/es unknown
- 1984-12-20 AR AR84299043A patent/AR244329A1/es active
- 1984-12-21 CA CA000470874A patent/CA1325946C/en not_active Expired - Fee Related
- 1984-12-21 PL PL1984251139A patent/PL146679B1/pl unknown
- 1984-12-21 YU YU217784A patent/YU46364B/sh unknown
- 1984-12-21 DK DK626284A patent/DK166030C/da not_active IP Right Cessation
- 1984-12-21 AT AT84309004T patent/ATE52106T1/de not_active IP Right Cessation
- 1984-12-21 DE DE8484309004T patent/DE3481996D1/de not_active Expired - Lifetime
- 1984-12-21 GB GB848432487A patent/GB8432487D0/en active Pending
- 1984-12-21 BG BG68023A patent/BG60382B1/bg unknown
- 1984-12-21 BR BR8406827A patent/BR8406827A/pt not_active IP Right Cessation
- 1984-12-21 GR GR82576A patent/GR82576B/el unknown
- 1984-12-21 FI FI845098A patent/FI80473C/fi not_active IP Right Cessation
- 1984-12-21 GB GB08432387A patent/GB2153380B/en not_active Expired
- 1984-12-21 EP EP84309004A patent/EP0151884B1/en not_active Expired
- 1984-12-21 PT PT79744A patent/PT79744B/pt not_active IP Right Cessation
- 1984-12-21 NO NO845211A patent/NO166724C/no unknown
- 1984-12-21 NZ NZ210707A patent/NZ210707A/xx unknown
- 1984-12-21 ES ES84539001A patent/ES8605570A1/es not_active Expired
- 1984-12-21 IL IL73903A patent/IL73903A0/xx unknown
- 1984-12-22 KR KR1019840008280A patent/KR900000897B1/ko not_active Expired
- 1984-12-22 HU HU844827A patent/HU214669B/hu not_active IP Right Cessation
- 1984-12-22 IN IN957/DEL/84A patent/IN163276B/en unknown
- 1984-12-23 IL IL73917A patent/IL73917A/xx not_active IP Right Cessation
- 1984-12-24 FR FR848419788A patent/FR2587355B1/fr not_active Expired - Lifetime
- 1984-12-24 IT IT68278/84A patent/IT1179891B/it active
- 1984-12-28 IE IE334684A patent/IE58044B1/en not_active IP Right Cessation
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1994
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| TC | Name/ company changed in patent |
Owner name: ALBRIGHT & WILSON UK LIMITED |
|
| MM | Patent lapsed |
Owner name: HUNTSMAN INTERNATIONAL LLC |