FI69620C - Katalysator och foerfarande foer framstaellning av vaetgas ur kolmonoxid och vatten - Google Patents

Katalysator och foerfarande foer framstaellning av vaetgas ur kolmonoxid och vatten Download PDF

Info

Publication number
FI69620C
FI69620C FI842175A FI842175A FI69620C FI 69620 C FI69620 C FI 69620C FI 842175 A FI842175 A FI 842175A FI 842175 A FI842175 A FI 842175A FI 69620 C FI69620 C FI 69620C
Authority
FI
Finland
Prior art keywords
catalyst
bipyridine
water
reaction
carbon monoxide
Prior art date
Application number
FI842175A
Other languages
English (en)
Finnish (fi)
Swedish (sv)
Other versions
FI69620B (fi
FI842175A0 (fi
Inventor
Tapani Venaelaeinen
Tapani Pakkanen
Tuula Pakkanen
Eero Iiskola
Original Assignee
Neste Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Neste Oy filed Critical Neste Oy
Publication of FI842175A0 publication Critical patent/FI842175A0/fi
Priority to FI842175A priority Critical patent/FI69620C/fi
Priority to DK232285A priority patent/DK169124B1/da
Priority to NO852061A priority patent/NO160245C/no
Priority to US06/738,783 priority patent/US4699775A/en
Priority to CA000482696A priority patent/CA1248933A/en
Priority to JP60117622A priority patent/JPS60261545A/ja
Priority to DE8585303796T priority patent/DE3579192D1/de
Priority to EP85303796A priority patent/EP0163532B1/en
Application granted granted Critical
Publication of FI69620B publication Critical patent/FI69620B/fi
Publication of FI69620C publication Critical patent/FI69620C/fi

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/12—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
FI842175A 1984-05-30 1984-05-30 Katalysator och foerfarande foer framstaellning av vaetgas ur kolmonoxid och vatten FI69620C (fi)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FI842175A FI69620C (fi) 1984-05-30 1984-05-30 Katalysator och foerfarande foer framstaellning av vaetgas ur kolmonoxid och vatten
DK232285A DK169124B1 (da) 1984-05-30 1985-05-23 Katalysator til fremstilling af hydrogengas ud fra carbonmonoxid og vand og fremgangsmåde til fremstilling af hydrogengas ud fra carbonmonoxid og vand i nærværelse af en katalysator
NO852061A NO160245C (no) 1984-05-30 1985-05-23 Katalysator og fremgangsmaate for fremstilling av hydrogengass fra karbonmonoksyd og vann.
CA000482696A CA1248933A (en) 1984-05-30 1985-05-29 Catalyst and procedure for producing hydrogen gas from carbon monoxide and water
US06/738,783 US4699775A (en) 1984-05-30 1985-05-29 Catalyst and method for producing hydrogen gas from carbon monoxide and water
JP60117622A JPS60261545A (ja) 1984-05-30 1985-05-30 一酸化炭素と水から水素ガスの製造用触媒及び方法
DE8585303796T DE3579192D1 (de) 1984-05-30 1985-05-30 Katalysator und verfahren zum erzeugen von wasserstoff aus kohlenmonoxyd und wasser.
EP85303796A EP0163532B1 (en) 1984-05-30 1985-05-30 Catalyst and procedure for producing gas from carbon monoxide and water

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI842175A FI69620C (fi) 1984-05-30 1984-05-30 Katalysator och foerfarande foer framstaellning av vaetgas ur kolmonoxid och vatten
FI842175 1985-05-30

Publications (3)

Publication Number Publication Date
FI842175A0 FI842175A0 (fi) 1984-05-30
FI69620B FI69620B (fi) 1985-11-29
FI69620C true FI69620C (fi) 1986-03-10

Family

ID=8519166

Family Applications (1)

Application Number Title Priority Date Filing Date
FI842175A FI69620C (fi) 1984-05-30 1984-05-30 Katalysator och foerfarande foer framstaellning av vaetgas ur kolmonoxid och vatten

Country Status (8)

Country Link
US (1) US4699775A (mo)
EP (1) EP0163532B1 (mo)
JP (1) JPS60261545A (mo)
CA (1) CA1248933A (mo)
DE (1) DE3579192D1 (mo)
DK (1) DK169124B1 (mo)
FI (1) FI69620C (mo)
NO (1) NO160245C (mo)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI85849C (fi) * 1988-03-22 1992-06-10 Neste Oy Foerfarande foer framstaellning av alkoholer och aldehyder fraon alkener och syntesgas.
US4980145A (en) * 1988-07-19 1990-12-25 Air Products And Chemicals, Inc. Liquid phase carbon monoxide shift process
FI84142C (fi) * 1990-01-16 1991-10-25 Neste Oy Foerfarande foer framstaellning av vattengas- och hydroformuleringskatalyt, en med foerfarandet framstaelld katalyt och anvaendning av katalyten.
FI88116C (fi) * 1991-12-31 1993-04-13 Neste Oy Foerfarande foer framstaellning av heterogena katalysatorer
FI98603C (fi) 1995-11-09 1997-07-25 Neste Oy Menetelmä vesikaasun siirtoreaktiokatalyyttien valmistamiseksi ja katalyytin käyttö
DE19834568A1 (de) * 1998-07-31 2000-02-03 Aventis Res & Tech Gmbh & Co Bimetallische Kupfer-Ruthenium-Trägerkatalysatoren mit hoher Sinterstabilität und Verfahren zu deren Herstellung
AU2003297313A1 (en) * 2002-12-20 2004-07-22 Honda Giken Kogyo Kabushiki Kaisha Platinum-free ruthenium-cobalt catalyst formulations for hydrogen generation
US7700071B2 (en) * 2004-01-23 2010-04-20 Ovonic Battery Company, Inc. Production of hydrogen via a base-facilitated reaction of carbon monoxide

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855307A (en) * 1967-02-20 1974-12-17 Monsanto Co Catalysis
US3804914A (en) * 1972-05-25 1974-04-16 Phillips Petroleum Co Ruthenium(ii)complexes as catalysts for selective hydrogenation of cyclic polyenes to cyclic monoenes
US4169853A (en) * 1978-02-06 1979-10-02 Texaco Development Corporation Homogeneous ruthenium catalysts useful in the reduction of ortho-substituted nitroaromatics to amines
US4292242A (en) * 1978-12-06 1981-09-29 Sri International Production of amines
US4344866A (en) * 1979-10-31 1982-08-17 Standard Oil Company Carbonylation of olefinically unsaturated compounds
US4324695A (en) * 1980-11-17 1982-04-13 National Distillers & Chemical Corp. Catalyst compositions of transition metal carbonyl complexes intercalcated with lamellar materials

Also Published As

Publication number Publication date
EP0163532A2 (en) 1985-12-04
DK232285A (da) 1985-12-01
NO160245C (no) 1991-05-22
DE3579192D1 (de) 1990-09-20
DK169124B1 (da) 1994-08-22
NO160245B (no) 1988-12-19
EP0163532B1 (en) 1990-08-16
JPS60261545A (ja) 1985-12-24
FI69620B (fi) 1985-11-29
CA1248933A (en) 1989-01-17
EP0163532A3 (en) 1987-05-27
US4699775A (en) 1987-10-13
JPH0530502B2 (mo) 1993-05-10
FI842175A0 (fi) 1984-05-30
DK232285D0 (da) 1985-05-23
NO852061L (no) 1985-12-02

Similar Documents

Publication Publication Date Title
EP2294075B1 (en) Novel ruthenium complexes having hybrid amine ligands, their preparation and use
Coetzee et al. Homogeneous catalytic hydrogenation of amides to amines
KR102026538B1 (ko) 수소화 촉매 및 이를 이용한 이산화탄소의 수소화 방법
Doetz et al. Reactions of complex ligands. 29. Metal-assisted cyclization of alkynols at a d6 metal template. One-pot synthesis of 2-oxacycloalkylidene complexes of chromium, tungsten, and manganese
FI69620C (fi) Katalysator och foerfarande foer framstaellning av vaetgas ur kolmonoxid och vatten
Sanchez-Delgado et al. Kinetics and mechanism of the regioselective homogeneous hydrogenation of quinoline using [Rh (COD)(PPh3) 2] PF6 as the catalyst precursor
Krafft et al. Dodecacarbonyltetracobalt Catalysis in the Thermal Pauson–Khand Reaction
EP3256250B1 (en) Phenanthroline based pincer complexes useful as catalysts for the preparation of methanol from carbondioxide
Werner et al. Basic Metals: XXXIII. Synthesis and reactivity of pentamethylcyclopentadienylrhodium (I) complexes: metal basicity versus phosphorus basicity in C5Me5Rh (CO) P2Me4
JPH04139192A (ja) イリジウム―光学活性ホスフィン錯体及びこれを用いた光学活性アルコールの製造方法
US6508753B2 (en) Chiral ligands for asymmetric catalysis
Dupau et al. Optically active amine derivatives: Ruthenium-catalyzed enantioselective hydrogenation of enamides
Inagaki et al. Synthesis of (R)-2-diphenylphosphino-2′-diphenylphosphinomethyl-1, 1′-binaphthyl and its use for asymmetric hydrogenation of α-alkylstyrenes
EP2297042A2 (en) Catalytic asymetric hydrogenation
WO2019166578A1 (en) Hydrogenation of imines with ru complexes
US20030130112A1 (en) Solid support dirhodium catalyst compositions and methods for making and using same
EP0371095B1 (en) Procedure for producing alcohols and aldehydes from alkenes and synthesis gases
Alcón et al. Synthesis of Rh (I) and Ir (I) complexes with chiral C2-multitopic ligands: Structural and catalytic properties
Goswami et al. Reductive functionalization of CO2 under mild reaction conditions for the catalytic synthesis of N-formamides by Mannich base based Cobalt (III) complex
CN110551036A (zh) 一种铱/手性亚磷酸酯-吡啶催化亚胺不对称氢化方法
JPS5951244A (ja) ３−アミノメチル−１−（３−アミノプロピル−１−メチル）−４−メチルシクロヘキサン、その製造方法及び使用
Forniés-Cámer et al. Mononuclear Pt (II) and Pd (II) 1, 4-dithiolato complexes. Crystal structures of [Pt ((−) DIOS)(PPh3) 2] and [Pd (S (CH2) 4S)(Ph2P (CH2) 3PPh2)]. Application in styrene hydroformylation
Garlaschelli et al. Hydrocarboxylation of isoprene catalyzed by iodo-carbonylrhodium derivatives. Spectroscopic evidence for participation of H+··· Rh (CO) 2I2− tight ion pairs and cis-Rh (CO) 2 (H2O) I in catalysis
US4510096A (en) Magnesium group VIII transition metal carbonyl complex
EP3931176B1 (en) Hydrogenation of imines with ru complexes

Legal Events

Date Code Title Description
MM Patent lapsed
MM Patent lapsed

Owner name: NESTE OY