FI64383B - Polyester-aminoalkylalkoxisilan foerfarande foer dess framstaellning och dess anvaendning som oeverdrag och adhesionsfoerbaettrande medel foer glas - Google Patents

Polyester-aminoalkylalkoxisilan foerfarande foer dess framstaellning och dess anvaendning som oeverdrag och adhesionsfoerbaettrande medel foer glas Download PDF

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Publication number
FI64383B
FI64383B FI782062A FI782062A FI64383B FI 64383 B FI64383 B FI 64383B FI 782062 A FI782062 A FI 782062A FI 782062 A FI782062 A FI 782062A FI 64383 B FI64383 B FI 64383B
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Finland
Prior art keywords
polyester
silane
formula
molecular weight
och
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FI782062A
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English (en)
Finnish (fi)
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FI64383C (fi
FI782062A (fi
Inventor
Enrico James Pepe
James Glenn Marsden
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Union Carbide Corp
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Publication of FI782062A publication Critical patent/FI782062A/fi
Application granted granted Critical
Publication of FI64383B publication Critical patent/FI64383B/fi
Publication of FI64383C publication Critical patent/FI64383C/fi

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10—Coating or impregnating
    • C04B20/1051—Organo-metallic compounds; Organo-silicon compounds, e.g. bentone
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/40—Organo-silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
    • C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
    • C04B41/4988—Organosilicium-organic copolymers, e.g. olefins with terminal silane groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/68—Unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
    • C08G18/837—Chemically modified polymers by silicon containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
    • C08G63/6854—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6858—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/695—Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon
    • C08G63/6954—Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon derived from polxycarboxylic acids and polyhydroxy compounds
    • C08G63/6958—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/918—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Structural Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paints Or Removers (AREA)

Claims (12)

1. Polyester-aminoalkylalkoxisilan-polymer som är användbar som överdrag och adhesionsförbättrande medel för glas och som har en molekylvikt större än 1000, kännetecknat därav, att don inneh.il ler enheter med formcln 27 6438 3
0 S-- 0 0 0 0 K /"=V I» M «I» "'c\ 0 - - CCH*CHC----0R0 -- --CCH2CaiC -- (X) _a_ -b~ -d- NHCCHgC^HH) y(^H2)ySiX^_z ) _ e R’z i vilken formel R är en tvävärd kolväteradikai, R' är en envärd alkyl-, aryl- eller aralkylgrupp, X är en envärd alkoxigrupp, y är O eller 1, v är ett helt tai 1...6, z är O, 1 eller 2, a är O eller en molfraktion mellan 0,004...0,6, och b, d och e är molfraktioner mellan ca 0,004...0,6 under förutsättning av att d är större än, lika med eller litet mindre än a + b + e.
2. Förfarande för framställning av en polyester-aminoalkylalkoxi-silan genom Michael-additionsreaktionen, kä nnetecknat därav, att man bringar att reagera med varandra A. en omättad konjugerad polyester med en molekylvikt om minst 1000 och omfattande enheter med formeln (II), 'o 21 Γ° «Π f C - CCH»CHC -· -- 0R0 -* UI) JaL. -11> L —d i vilken formel R betecknar en tvävärd kolväteradikal, a är 0 eller en molfraktion mellan 0,004 och 0,6 och b och d är molfraktioner frän ca 0,004...0,6, vilken polyester om sä önskats bringats att reagera med ett organiskt di-isocyanat, för att bilda en omättad konjugerad polyester med förlängd kedja med en molekylvikt om minst 5000, och B. en aminoalkylalkoxisilan med formeln R' I 2 H2N(CH2CH2NH)y(CH2)vSiX{3_z) (III) i vilken formel R' är en envärd alkyl-, aryl- eller aralkyigruDpt χ är en envärd alkoxigrupp, y är 0 eller 1, v är ett helt tai 1...6 och z är 0, 1 eller 2, vid en temperatur om ca 0...235 °c, för att framställä polyester-aminoalkylalkoxisilan. 28 64383
3. Förfarande enligt patentkravet 2 , kännetecknat därav, att man bringar polyester-aminoalkylalkoxisilanen att reagera med vatten, för att bildaett hydrolysat av denna aminoalkylalkoxi-silan.
4. Förfarande enligt patentkravet 2 , kännetecknat därav, att molekylvikten för den omattade konjugerade polyestern är minst 2000.
5. Förfarande enligt patentkravet 2 , kännetecknat därav, att molekylvikten för den omattade konjugerade polyestern är minst 4000.
6. Förfarande enligt patentkravet 2, kännetecknat därav, att aminoalkylalkoxisilanen är gamma-aminopropyltrietoxisilan.
7. Förfarande enligt patentkravet 2 , kännetecknat därav, att aminoalkylalkoxisilanen är N-beta-(aminoetyl)-gamma-aminopr opyltr imetoxisiian.
8. Förfarande enligt patentkravet 2 , kännetecknat därav, att det organiska di-isocyanatet är toluen-di-isocyanat.
9. Användning av en polyester-arcinoalkylalkoxisi lan för att göra oorganiska kiselhaltiga material kompatibla med och vidhäftande vid organiska hartser, kännetecknad därav, att man över-drager ytan av detta oorganiska kiselhaltiga material innan det kombineras med nämnda organiska harts ellet under tiden för kombi-nerandet med en polyester-aminoalkylalkoxisilan-polymer med en mole-kylvikt större an 1000, som innehäller enheter med formeln (I), °1 r Ί Γ 1 Γ Ί o c- 0 0 0 0 "’vT ~~ OCH·OTC j-ORO -- .-COIgCHC -- (I) JaL JbL JdL ^(CH2CH2NH)3r(CH2)vSiX(3.z)Je R'z i vilken formel R är en tvävärd kolväteradikal, R' är en envärd alkyl-, aryl- eller aralkylgrupp, X är en envärd alkoxigrupp, y är 0 eller 1, v är ett belt tai 1...6, z är 0, 1 eller 2, a är 0 eller II
FI782062A 1977-07-05 1978-06-28 Polyester-aminoalkylalkoxisilan foerfarande foer dess framstaellning och dess anvaendning som oeverdrag och adhesionsfoerbaettrande medel foer glas FI64383C (fi)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/813,074 US4122074A (en) 1977-07-05 1977-07-05 Polyester aminoalkylalkoxysilanes
US81307477 1977-07-05

Publications (3)

Publication Number Publication Date
FI782062A FI782062A (fi) 1979-01-06
FI64383B true FI64383B (fi) 1983-07-29
FI64383C FI64383C (fi) 1983-11-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
FI782062A FI64383C (fi) 1977-07-05 1978-06-28 Polyester-aminoalkylalkoxisilan foerfarande foer dess framstaellning och dess anvaendning som oeverdrag och adhesionsfoerbaettrande medel foer glas

Country Status (11)

Country Link
US (1) US4122074A (sv)
BE (1) BE868721A (sv)
CA (1) CA1110386A (sv)
DE (1) DE2829394C2 (sv)
FI (1) FI64383C (sv)
FR (1) FR2396778B1 (sv)
GB (1) GB2000792B (sv)
IT (1) IT1096967B (sv)
NL (1) NL185934C (sv)
NO (1) NO151624C (sv)
SE (1) SE428696B (sv)

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US4370439A (en) * 1979-03-22 1983-01-25 Ppg Industries, Inc. Method of preparing a sizing composition for treating glass fibers
US4273694A (en) * 1980-04-01 1981-06-16 Union Carbide Corporation Certain acid salts of polyester aminoorganosilanes
JPS5742556A (en) * 1980-06-27 1982-03-10 Union Carbide Corp Improved polyester aminoorganosilane salt/ polyalkylene oxide composition for glass fiber treatment
US4340520A (en) * 1980-06-27 1982-07-20 Union Carbide Corporation Polyester aminoorganosilane salt/polyalkylene oxide compositions for improved glass fiber treatment
US4340524A (en) * 1980-06-30 1982-07-20 Union Carbide Corporation Water-resistant latex sealants
US4370157A (en) * 1981-03-09 1983-01-25 Ppg Industries, Inc. Stable sizing compositions used during forming of glass fibers and resulting fiber
US4396681A (en) * 1981-06-10 1983-08-02 Essex Chemical Corporation Process for coating one pot moisture curable coating composition onto non-porous substrate and article
US4429082A (en) 1982-05-10 1984-01-31 Ppg Industries, Inc. Film-forming resins containing alkoxy silane groups
US4430486A (en) 1982-11-29 1984-02-07 Ppg Industries, Inc. Film-forming urethane resins containing alkoxy silane groups and acrylyl groups
GB8301374D0 (en) * 1983-01-19 1983-02-23 Dow Corning Ltd Siloxane-polyester compositions
US4468492A (en) * 1983-07-15 1984-08-28 Ppg Industries, Inc. Polymeric organo functional silanes as reactive modifying materials
US4596737A (en) * 1985-07-23 1986-06-24 Manville Corporation Method for the treatment and production of glass fiber mats
DE3626057A1 (de) * 1986-08-01 1988-02-04 Quarzwerke Gmbh Als waessrige kunstharzdispersionen vorliegende lacke oder grundierungen mit einem mineralischen fuellstoff
US4876039A (en) * 1986-11-04 1989-10-24 Dow Corning Corporation Process for preparing silicone microparticles cured by a Michael addition reaction
US4698406A (en) * 1986-11-04 1987-10-06 Dow Corning Corporation Curable organopolysiloxane composition
US4962177A (en) * 1988-04-04 1990-10-09 Dow Corning Corporation Aminofunctional organosilicon optical brighteners
US5230959A (en) 1989-03-20 1993-07-27 Weyerhaeuser Company Coated fiber product with adhered super absorbent particles
US5091465A (en) * 1989-12-13 1992-02-25 Union Carbide Chemicals And Plastics Company, Inc. Glass fiber size
US5354829A (en) * 1992-06-30 1994-10-11 Ppg Industries, Inc. Silylated polyamine polymers and a method of treating fibers
US5616757A (en) * 1993-04-08 1997-04-01 Bausch & Lomb Incorporated Organosilicon-containing materials useful for biomedical devices
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US5891942A (en) * 1997-05-01 1999-04-06 Fibre Glass-Evercoat Company, Inc. Coating composition with improved water and mar resistance
US5948927A (en) * 1998-04-01 1999-09-07 Witco Corporation Bis-silyl tertiary amines
WO2000047588A1 (de) * 1999-02-09 2000-08-17 Cognis Deutschland Gmbh Aminosilanester
US6579616B1 (en) * 1999-03-30 2003-06-17 Owens Corning Fiberglas Technology, Inc. String binders
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DE10242265A1 (de) * 2002-09-12 2004-03-25 Degussa Ag Haftungsverbessernder Zusatz aus einem ungesättigten, amorphen Polyester
DE102005023107A1 (de) * 2005-05-13 2006-11-16 Basf Ag Modifizierte Polyamine
US7781493B2 (en) 2005-06-20 2010-08-24 Dow Global Technologies Inc. Protective coating for window glass
EP2122638B1 (en) * 2006-12-19 2012-11-07 Dow Global Technologies LLC Improved composites and methods for conductive transparent substrates
CN101553351B (zh) * 2006-12-19 2012-09-05 陶氏环球技术公司 包封的嵌板组件及其制造方法
US9193880B2 (en) * 2006-12-19 2015-11-24 Dow Global Technologies Llc Adhesion promotion additives and methods for improving coating compositions
EP3080183B1 (en) * 2013-12-12 2023-04-19 Dow Global Technologies Llc Aminosilane adhesion promoter for urethane system
CN116987264B (zh) * 2023-07-13 2024-02-27 山东星顺新材料有限公司 一种聚氨基酰胺硅烷偶联剂及其制备方法和应用、粘接剂

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Also Published As

Publication number Publication date
DE2829394A1 (de) 1979-01-11
CA1110386A (en) 1981-10-06
NO151624B (no) 1985-01-28
US4122074A (en) 1978-10-24
GB2000792B (en) 1982-06-16
NO151624C (no) 1985-05-08
BE868721A (fr) 1979-01-04
IT1096967B (it) 1985-08-26
FR2396778B1 (fr) 1985-05-31
FI64383C (fi) 1983-11-10
NL185934C (nl) 1990-08-16
SE7807543L (sv) 1979-01-06
IT7825312A0 (it) 1978-07-04
NL7807260A (nl) 1979-01-09
FI782062A (fi) 1979-01-06
FR2396778A1 (fr) 1979-02-02
DE2829394C2 (de) 1982-08-26
SE428696B (sv) 1983-07-18
GB2000792A (en) 1979-01-17
NO782335L (no) 1979-01-08

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