ES8706101A1 - Un procedimiento para preparar mono-olefinas alifaticas que tienen 4-24 atomos de carbono por molecula. - Google Patents

Un procedimiento para preparar mono-olefinas alifaticas que tienen 4-24 atomos de carbono por molecula.

Info

Publication number
ES8706101A1
ES8706101A1 ES550042A ES550042A ES8706101A1 ES 8706101 A1 ES8706101 A1 ES 8706101A1 ES 550042 A ES550042 A ES 550042A ES 550042 A ES550042 A ES 550042A ES 8706101 A1 ES8706101 A1 ES 8706101A1
Authority
ES
Spain
Prior art keywords
olefins
preparation
dimerization products
aliphatic mono
dimerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES550042A
Other languages
English (en)
Other versions
ES550042A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of ES550042A0 publication Critical patent/ES550042A0/es
Publication of ES8706101A1 publication Critical patent/ES8706101A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/12—Fluorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

METODO DE OBTENER MONO-OLEFINAS ALIFATICAS QUE TIENEN 4-24 ATOMOS DE CARBONO POR MOLECULA. COMPRENDE UNA REACCION DE DIMERIZACION, QUE SE LLEVA A CABO PONIENDO EN CONTACTO LAS MONO-OLEFINAS ALIFATICAS QUE TIENEN C 2 A 12 POR MOLECULA, A UNA TEMPERATURA ENTRE 20 Y 200JC, Y A UNA PRESION ENTRE 1 Y 100 BARES MANOMETRICOS, EN UN DISOLVENTE ORGANICO APROTICO, CON 10C6 A 10C1 MOLES DE UN COMPUESTO DE PALADIO Y/O RUTENIO POR CADA MOL DE MONO-OLEFINA ALIFATICA DE PARTIDA Y SIMULTANEAMENTE CON UN EQUIVALENTE DE UN ACIDO POR CADA MOL DE PALADIO Y/O RUTENIO, TENIENDO EL ACIDO UN PKA MENOR QUE 2 Y NO SIENDO UN HIDRACIDO HALOGENADO. TIENE APLICACIONES INDUSTRIALES PARA PREPARAR PRODUCTOS DE DIMERIZACION.
ES550042A 1984-12-19 1985-12-17 Un procedimiento para preparar mono-olefinas alifaticas que tienen 4-24 atomos de carbono por molecula. Expired ES8706101A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB848432042A GB8432042D0 (en) 1984-12-19 1984-12-19 Preparation of dimerization products

Publications (2)

Publication Number Publication Date
ES550042A0 ES550042A0 (es) 1987-06-01
ES8706101A1 true ES8706101A1 (es) 1987-06-01

Family

ID=10571419

Family Applications (1)

Application Number Title Priority Date Filing Date
ES550042A Expired ES8706101A1 (es) 1984-12-19 1985-12-17 Un procedimiento para preparar mono-olefinas alifaticas que tienen 4-24 atomos de carbono por molecula.

Country Status (17)

Country Link
US (1) US4599476A (es)
EP (1) EP0188830B1 (es)
JP (1) JPS61145126A (es)
CN (1) CN1003853B (es)
AR (1) AR241500A1 (es)
AT (1) ATE40878T1 (es)
AU (1) AU584956B2 (es)
BR (1) BR8506330A (es)
CA (1) CA1255334A (es)
DD (1) DD240197A5 (es)
DE (1) DE3568326D1 (es)
ES (1) ES8706101A1 (es)
FI (1) FI81777C (es)
GB (1) GB8432042D0 (es)
IN (1) IN169685B (es)
SU (1) SU1482520A3 (es)
ZA (1) ZA859603B (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IN166314B (es) * 1985-08-29 1990-04-07 Shell Int Research
IN168306B (es) * 1986-03-05 1991-03-09 Shell Int Research
IN168056B (es) * 1986-03-05 1991-01-26 Shell Int Research
EP0235866A3 (en) * 1986-03-05 1988-01-27 Shell Internationale Researchmaatschappij B.V. Catalyst compositions
CA1271877A (en) * 1986-03-24 1990-07-17 Johannes A.M. Van Broekhoven Polymer preparation
EP0253416A1 (en) * 1986-06-24 1988-01-20 Shell Internationale Researchmaatschappij B.V. Catalyst compositions
US4804739A (en) * 1986-07-01 1989-02-14 Shell Oil Company Process for preparing carbon monoxide polymer with quaternary phosphonium compound bidentate ligand
EP0254956A3 (de) * 1986-07-29 1988-08-03 Linde Aktiengesellschaft Verfahren zur Oligomerisierung von Olefinen
US4820802A (en) * 1987-02-03 1989-04-11 Shell Oil Company Improved process of preparing carbon monoxide/olefin copolymer with ortho substituted phosphine catalyst composition.
GB8704338D0 (en) * 1987-02-24 1987-04-01 Shell Int Research Dimerization of olefins
GB8711524D0 (en) * 1987-05-15 1987-06-17 Shell Int Research Carboxylic acids
GB8720379D0 (en) * 1987-08-28 1987-10-07 Shell Int Research Preparation of butenes
US4857147A (en) * 1988-03-18 1989-08-15 Shell Oil Company Method of composite part fabrication
DE69325757T2 (de) * 1992-09-21 1999-12-30 Montell Technology Company Bv Polymerisationsverfahren
US6331502B1 (en) * 1998-12-09 2001-12-18 Council Of Scientific And Industrial Research Catalyst system containing a semilabile anionic ligand and a use of such catalyst system to produce α, β, -unsaturated carboxylic acids and their esters
US6228797B1 (en) 1998-12-11 2001-05-08 Phillips Petroleum Company Oligomerization catalyst system and method of making and method of using such catalyst system in the oligomerization of olefins
EP1365004A1 (en) * 2002-05-23 2003-11-26 ATOFINA Research Production of olefins
JP2007022974A (ja) * 2005-07-19 2007-02-01 Nissei Kagaku Kogyosho:Kk ハロメチル芳香族炭化水素の製造方法
US8383869B2 (en) 2009-09-01 2013-02-26 Shell Oil Company Olefin oligomer composition
US20140163277A1 (en) * 2012-12-12 2014-06-12 Uop Llc Process for the generation of 2,5-dimethylhexene from isobutene
JP6178611B2 (ja) * 2013-05-08 2017-08-09 Ｊｘｔｇエネルギー株式会社 エステル化合物の製造方法
CN107497489B (zh) * 2016-06-14 2020-06-09 中国石油化工股份有限公司 乙烯合成丙酸甲酯用催化剂组合物及其合成方法
CN113024336B (zh) * 2021-03-19 2022-09-27 常州大学 催化异戊烯二聚制备异癸烯的方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL127268C (es) * 1957-12-03
FR1517704A (fr) * 1966-04-07 1968-03-22 Inst Francais Du Petrole Dimérisation d'oléfines
SU374930A1 (ru) * 1971-07-07 1978-09-25 Сибирское Отделение Ордена Трудового Красного Знамени Института Катализа Ан Ссср Гомогенный катализатор димеризации этилена
US4487847A (en) * 1983-07-25 1984-12-11 Phillips Petroleum Company Ethylene dimerization
EP0170311B1 (en) * 1984-07-30 1989-02-01 Shell Internationale Researchmaatschappij B.V. Process for the dimerization of olefins

Also Published As

Publication number Publication date
DD240197A5 (de) 1986-10-22
ES550042A0 (es) 1987-06-01
BR8506330A (pt) 1988-03-01
AU5132985A (en) 1986-06-26
DE3568326D1 (en) 1989-03-30
GB8432042D0 (en) 1985-01-30
AR241500A1 (es) 1992-07-31
FI81777C (fi) 1990-12-10
SU1482520A3 (ru) 1989-05-23
ZA859603B (en) 1986-08-27
JPS61145126A (ja) 1986-07-02
EP0188830A1 (en) 1986-07-30
FI855027A0 (fi) 1985-12-17
FI81777B (fi) 1990-08-31
CN85109193A (zh) 1986-06-10
AU584956B2 (en) 1989-06-08
CN1003853B (zh) 1989-04-12
ATE40878T1 (de) 1989-03-15
CA1255334A (en) 1989-06-06
FI855027A (fi) 1986-06-20
US4599476A (en) 1986-07-08
IN169685B (es) 1991-12-07
EP0188830B1 (en) 1989-02-22

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FD1A Patent lapsed

Effective date: 19970203