ES8401980A1 - Procedimiento para preparar un compuesto de hidrurocarboniltris (triorganofosforo) rodio. - Google Patents

Procedimiento para preparar un compuesto de hidrurocarboniltris (triorganofosforo) rodio.

Info

Publication number
ES8401980A1
ES8401980A1 ES518851A ES518851A ES8401980A1 ES 8401980 A1 ES8401980 A1 ES 8401980A1 ES 518851 A ES518851 A ES 518851A ES 518851 A ES518851 A ES 518851A ES 8401980 A1 ES8401980 A1 ES 8401980A1
Authority
ES
Spain
Prior art keywords
preparation
complex compounds
rhodium complex
triorganophosphorus
rhodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES518851A
Other languages
English (en)
Other versions
ES518851A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ES8401980A1 publication Critical patent/ES8401980A1/es
Publication of ES518851A0 publication Critical patent/ES518851A0/es
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

PROCEDIMIENTO PARA PREPARAR UN COMPUESTO DE HIDRO-CARBONIL-TRIS (TRIORGANOFOSFORO)RODIO. CONSISTE EN HACER REACCIONAR, A UNA TEMPERATURA COMPRENDIDA ENTRE 20 Y 100º, UN COMPUESTO DE HALOCARBONILBIS (TRIORGANOFOSFORO)-RODIO, SIN AISLARLO DE SU MEZCLA PRODUCTO, CON UN AGENTE REDUCTOR DE HIDRURO METALICO Y LIGANDO DE TRIORGANOFOSFORO LIBRE, DURANTE AL MENOS UN PERIODO DE TIEMPO SUFICIENTE PARA FORMAR DICHO COMPUESTO DE HIDRUROCARBONILTRIS(TRIORGANOFOSFORO)-RODIO. EL HIDRURO METALICO UTILIZADO ES UN BOROHIDRURO Y EL LIGANDO DE TRIORGANO FOSFORO LIBRE ES TRIFENILFOSFINA.
ES518851A 1980-12-30 1983-01-07 Procedimiento para preparar un compuesto de hidrurocarboniltris (triorganofosforo) rodio. Granted ES518851A0 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/221,502 US4363764A (en) 1980-12-30 1980-12-30 Preparation of rhodium complex compounds

Publications (2)

Publication Number Publication Date
ES8401980A1 true ES8401980A1 (es) 1984-02-01
ES518851A0 ES518851A0 (es) 1984-02-01

Family

ID=22828092

Family Applications (2)

Application Number Title Priority Date Filing Date
ES508413A Granted ES508413A0 (es) 1980-12-30 1981-12-29 Procedimiento para preparar un compuesto de halocarbonilbis (triorganofosforo) rodio.
ES518851A Granted ES518851A0 (es) 1980-12-30 1983-01-07 Procedimiento para preparar un compuesto de hidrurocarboniltris (triorganofosforo) rodio.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES508413A Granted ES508413A0 (es) 1980-12-30 1981-12-29 Procedimiento para preparar un compuesto de halocarbonilbis (triorganofosforo) rodio.

Country Status (13)

Country Link
US (1) US4363764A (es)
EP (1) EP0055487B1 (es)
JP (2) JPS57167998A (es)
KR (1) KR860001612B1 (es)
AT (1) ATE9701T1 (es)
BR (1) BR8108413A (es)
CA (1) CA1174243A (es)
DE (1) DE3166529D1 (es)
ES (2) ES508413A0 (es)
MX (1) MX163334A (es)
PL (2) PL134893B1 (es)
YU (2) YU43059B (es)
ZA (1) ZA818634B (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4446074A (en) * 1981-12-24 1984-05-01 Union Carbide Corporation Preparation of rhodium complex compounds
US4668809A (en) * 1982-05-03 1987-05-26 Exxon Research And Engineering Transition metal complex catalysts
US4595753A (en) * 1982-05-03 1986-06-17 Exxon Research And Engineering Co. Heterocycle-substituted alkyl diaryl phosphine rhodium caronyl hydride complex hydroformylation catalyst compositions
JPS6127994A (ja) * 1984-07-16 1986-02-07 Agency Of Ind Science & Technol ロジウム化合物の製造法
US4673753A (en) * 1986-02-03 1987-06-16 Minnesota Mining And Manufacturing Company Rhodium oxymetallate catalysts
US4788308A (en) * 1986-02-03 1988-11-29 Minnesota Mining And Manufacturing Company Rhodium oxymetallate catalysts
KR0134494B1 (ko) * 1993-10-20 1998-04-20 성재갑 하이드리도카르보닐트리스(트리오가노포스포러스)로듐의 제조방법
UA27055C2 (uk) * 1993-12-14 2000-02-28 Центр Ембріональних Тканин "Емселл" Лікарський препарат імуhозаміhhої дії hа осhові клітиhhої суспеhзії та спосіб лікуваhhя сиhдрому hабутого імуhодефіциту (віл-іhфекції) з використаhhям цього препарату
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
DE102004028183B4 (de) * 2003-06-10 2008-04-30 Bayer Schering Pharma Aktiengesellschaft Verfahren zum Regenerieren der Katalysatorverbindungen Rh(PX3)3(Y)
CN102382143B (zh) * 2010-08-31 2014-05-28 中国石油化工股份有限公司 一种烯烃氢甲酰化均相络合催化剂的制备方法
CN106661069B (zh) 2014-07-11 2020-04-03 优美科股份公司及两合公司 用于制备三(三苯基膦)羰基氢化铑(i)的方法
US11416246B2 (en) 2018-09-03 2022-08-16 Nec Corporation Information processing apparatus, analysis system, analysis method, and non-transitory computer readable medium storing analysis program
JP7350674B2 (ja) 2020-02-26 2023-09-26 株式会社東芝 情報処理装置、情報処理方法、およびプログラム

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3560539A (en) * 1968-08-21 1971-02-02 Union Oil Co Selective catalyst recovery
US3857895A (en) * 1969-05-12 1974-12-31 Union Oil Co Recovery of catalyst complexes
US3644446A (en) * 1969-07-01 1972-02-22 Union Oil Co Preparation of rhodium and iridium hydride carbonyl complexes
US3859359A (en) * 1970-04-27 1975-01-07 Ethyl Corp Compound and method
US3641076A (en) * 1970-08-24 1972-02-08 Union Oil Co Catalyst recovery
JPS5136799B2 (es) * 1971-10-06 1976-10-12
IT1007026B (it) * 1974-01-23 1976-10-30 Montedison Spa Procedimento per il ricupero di sistemi catalitici da grezzi di idroformilazione
DE2448005C2 (de) * 1974-10-09 1983-10-20 Basf Ag, 6700 Ludwigshafen Verfahren zur Regenerierung von Rhodium oder Iridium enthaltenden Katalysatoren aus Destillationsrückständen von Hydroformylierungsgemischen
DE2614799C2 (de) * 1976-04-06 1986-02-27 Basf Ag, 6700 Ludwigshafen Verfahren zur Regenerierung von Rhodium enthaltenden Katalysatoren durch Behandeln von rhodiumhaltigen Destillationsrückständen von Hydroformylierungsgemischen
JPS5594390A (en) * 1979-01-08 1980-07-17 Toyo Soda Mfg Co Ltd Preparation of catalyst
US4196096A (en) * 1979-02-12 1980-04-01 Eastman Kodak Company Process for regeneration of rhodium hydroformylation catalysts
NO156742C (no) * 1979-03-28 1987-11-18 Union Carbide Corp Fremgangsmaate for fremstilling av et hydroformyleringsmedium, og fremgangsmaate for fremstilling av aldehyder.

Also Published As

Publication number Publication date
PL234494A1 (es) 1982-09-13
JPS6338036B2 (es) 1988-07-28
DE3166529D1 (en) 1984-11-08
BR8108413A (pt) 1982-10-13
ATE9701T1 (de) 1984-10-15
CA1174243A (en) 1984-09-11
KR830007711A (ko) 1983-11-04
JPH0120160B2 (es) 1989-04-14
US4363764A (en) 1982-12-14
MX163334A (es) 1992-04-22
JPS57167998A (en) 1982-10-16
EP0055487B1 (en) 1984-10-03
YU313381A (en) 1983-10-31
YU43059B (en) 1989-02-28
JPS62265294A (ja) 1987-11-18
PL135114B1 (en) 1985-09-30
ES8304583A1 (es) 1983-04-01
PL134893B1 (en) 1985-09-30
ES508413A0 (es) 1983-04-01
KR860001612B1 (ko) 1986-10-14
YU127483A (en) 1983-12-31
ZA818634B (en) 1982-10-27
EP0055487A1 (en) 1982-07-07
ES518851A0 (es) 1984-02-01

Similar Documents

Publication Publication Date Title
YU122783A (en) Process for preparation of sin-isomeres
GB2080808B (en) Process for the preparation of n-aryl-n-(mono- or disubstituted)-urea derivatives
ES8304583A1 (es) Procedimiento para preparar un compuesto de halocarbonilbis (triorganofosforo) rodio.
GB2086918B (en) Process for the preparation of polybutadiene
DE3162193D1 (en) Process for preparing homogeneous films of hg1-xcdxte
IL62669A (en) Process for the preparation of 9-carbamoyl-9(substituted)aminopropylfluorenes and novel 9-carbamoyl-9-(2-cyanoethyl)fluorenes therefor and their preparation
GB2083465B (en) Process for preparations of ethanol
DE3160090D1 (en) Process for the preparation of 2-mercaptobenzthiazoles
DE3160603D1 (en) Process for the preparation of fluorobenzonitriles
PT72946A (en) Process for the preparation of substituted succinimides
PT72565B (en) Process for the preparation of phenoxy-amino-propanol derivati-ves
DE3173547D1 (en) Process for the preparation of hydrazono-isoindolines
DE3167279D1 (en) Process for the preparation of 2-hydroxy-benzothiazoles
YU133581A (en) Process for preparing substituted derivatives of phenoxy-amino-propanol
DE3160245D1 (en) Process for preparing n-methyl-carbamate of methylthioacetal-doxime
IL60122A (en) Process for the preparation of 2-oxa-3-oxo-delta4-steroids
DE3160225D1 (en) Process for the preparation of 1-phenyl-3-carbamoyl-pyrazol-5-ones
DE3160063D1 (en) Process for the preparation of 2-amino-4-nitrophenol
GB2088357B (en) Concentration of alcohol by freeze-separation process
DE3171470D1 (en) Process for the preparation of dihalomethylene-lactones
DE3161197D1 (en) Process for the preparation of trimethyl benzoquinone
DE3160147D1 (en) Process for the preparation of 1-acetoxy-3-chloro-pentanone-4
DE3160108D1 (en) Process for the preparation of 2-amino-6-nitro-benzothiazole
PL238643A1 (en) Process for preparing novel n-oxide of 2-isopropylaminepyrimidine
GB2088360B (en) Process for the preparation of p-allyl-phenols