ES8207189A1 - Procedimiento para convertir selectivamente fosfinas alquil-sustituidas presentes en un medio de reaccion de hidroformi-lacion a sus componentes oxidos de fosfina. esta patente ha sido despositada en los paises que se citan en la list - Google Patents

Procedimiento para convertir selectivamente fosfinas alquil-sustituidas presentes en un medio de reaccion de hidroformi-lacion a sus componentes oxidos de fosfina. esta patente ha sido despositada en los paises que se citan en la list

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Publication number
ES8207189A1
ES8207189A1 ES505725A ES505725A ES8207189A1 ES 8207189 A1 ES8207189 A1 ES 8207189A1 ES 505725 A ES505725 A ES 505725A ES 505725 A ES505725 A ES 505725A ES 8207189 A1 ES8207189 A1 ES 8207189A1
Authority
ES
Spain
Prior art keywords
reactivation
rhodium complex
hydroformylation catalysts
complex hydroformylation
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES505725A
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English (en)
Other versions
ES505725A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ES505725A0 publication Critical patent/ES505725A0/es
Publication of ES8207189A1 publication Critical patent/ES8207189A1/es
Expired legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

PROCEDIMIENTO PARA CONVERTIR FOSFINAS ALCUIL-SUSTITUIDAS PROCEDENTES DE REACCION DE HIDROFORMILACION EN LOS CORRESPONDIENTES OXIDOS DE FOSFINA,ASI COMO PARA MEJORAR LA ACTIVIDAD DEL CATALIZADOR DE HIDROFORMILACION A BASE DE COMPLEJO DE RODIO. CONSISTE EN DETENER LA REACCION DE HIDROFORMILACION Y TRATAR, BAJO CONDICIONES NO HIDROFORMILANTES, CON AIRE O UNA MEZCLA DE AIRE Y NITROGENO A UNA TEMPERATURA ENTRE 20 Y 80, LA TOTALIDAD O UNA PARTE DEL MEDIO DE REACCION DE HIDROFORMILACION, QUE CONTIENE 5 A 60 POR 100 DE ALDEHIDOS, 10 A70 POR 100 DE SUBPRODUCTOS DE CONDESANCION DE ALDEHIDOS, UN CATALIZADOR DE HIDROFORMILACION DE COMPLEJO DE RODIO, SOLUBLE, PARCIALMENTE DESACTIVADO, 0,1 A 5 POR 100 DE FOSFINA ALQUIL-SUSTICION SE MANTIENE HASTA QUE SE HA CONVERTIDO AL MENOS EL 25 POR 100 DE FOSFINA ALQUIL-SUSTITUIDA EN EL CORRESPONDIENTE OXIDO.
ES505725A 1980-09-24 1981-09-23 Procedimiento para convertir selectivamente fosfinas alquil-sustituidas presentes en un medio de reaccion de hidroformi-lacion a sus componentes oxidos de fosfina. esta patente ha sido despositada en los paises que se citan en la list Expired ES8207189A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/190,280 US4605780A (en) 1980-09-24 1980-09-24 Reactivation of rhodium complex hydroformylation catalysts

Publications (2)

Publication Number Publication Date
ES505725A0 ES505725A0 (es) 1982-08-16
ES8207189A1 true ES8207189A1 (es) 1982-08-16

Family

ID=22700690

Family Applications (1)

Application Number Title Priority Date Filing Date
ES505725A Expired ES8207189A1 (es) 1980-09-24 1981-09-23 Procedimiento para convertir selectivamente fosfinas alquil-sustituidas presentes en un medio de reaccion de hidroformi-lacion a sus componentes oxidos de fosfina. esta patente ha sido despositada en los paises que se citan en la list

Country Status (13)

Country Link
US (1) US4605780A (es)
EP (1) EP0049781B1 (es)
JP (1) JPS607941B2 (es)
KR (1) KR880000058B1 (es)
AT (1) ATE6992T1 (es)
BR (1) BR8105868A (es)
CA (1) CA1187100A (es)
DE (1) DE3163094D1 (es)
ES (1) ES8207189A1 (es)
MX (1) MX158918A (es)
PL (1) PL131753B1 (es)
SU (1) SU1757458A3 (es)
YU (1) YU43040B (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5976034A (ja) * 1982-10-21 1984-04-28 Mitsubishi Chem Ind Ltd ヒドロホルミル化法
US4929767A (en) * 1988-08-12 1990-05-29 Union Carbide Chemicals And Plastics Company Inc. Treatment of rhodium catalysts
US4861918A (en) * 1988-08-12 1989-08-29 Union Carbide Corporation Reactivation of hydroformylation catalysts
US5099047A (en) * 1989-11-17 1992-03-24 Mitsubishi Kasei Corporation Method for recovering a group viii metal solid complex and hydroformylation method
DE4135050A1 (de) * 1991-10-24 1993-04-29 Hoechst Ag Verfahren zur reaktivierung wasserloeslicher hydroformylierungskatalysatoren
US5237106A (en) * 1992-01-24 1993-08-17 Union Carbide Chemicals & Plastics Technology Corporation Reactivation of hydroformylation catalysts
US5290743A (en) * 1993-03-22 1994-03-01 Arco Chemical Technology L.P. Process for regenerating a deactivated rhodium hydroformylation catalyst system
CZ283697A3 (cs) * 1996-09-11 1998-04-15 Mitsubishi Chemical Corporation Způsob přípravy roztoku komplexu rhodia a jeho použití
CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
CN104248994B (zh) * 2013-06-25 2018-03-20 中国石油化工股份有限公司 羰基化铑膦催化剂的活性恢复方法
CN103570514B (zh) * 2013-10-07 2015-11-18 青岛科技大学 一种均相催化-两相分离烯烃氢甲酰化的方法
EP3374340B1 (en) 2015-11-10 2021-12-29 Dow Technology Investments LLC Process for producing aldehydes
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
JP7268602B2 (ja) 2017-11-15 2023-05-08 三菱ケミカル株式会社 アルデヒドの製造方法及びアルコールの製造方法
TW202126385A (zh) 2019-11-05 2021-07-16 美商陶氏科技投資有限公司 自氫甲醯化製程回收銠之方法
CN113351249B (zh) * 2021-04-29 2023-02-03 四川大学 一种催化内烯烃氢甲酰化制醛的催化体系
WO2023095907A1 (ja) * 2021-11-29 2023-06-01 三菱ケミカル株式会社 アルデヒドの製造方法
WO2024129290A1 (en) 2022-12-13 2024-06-20 Dow Technology Investments Llc Process to minimize polyphosphine usage by making use of degradation products

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Publication number Priority date Publication date Assignee Title
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US3555098A (en) * 1967-12-13 1971-01-12 Union Oil Co Hydroformylation
US3547964A (en) * 1968-07-24 1970-12-15 Union Oil Co Group viii noble metal catalyst recovery
JPS5123212A (en) * 1974-08-17 1976-02-24 Mitsubishi Chem Ind Arudehidono seizohoho
US4148830A (en) * 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
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US4221743A (en) * 1976-07-07 1980-09-09 Union Carbide Corporation Hydroformylation process
AT356639B (de) * 1977-01-20 1980-05-12 Stamicarbon Verfahren zur katalytischen umsetzung ole- finisch ungesaettigter verbindungen mit wasser- stoff und kohlenmonoxid
US4135911A (en) * 1977-07-28 1979-01-23 E. I. Du Pont De Nemours And Company Rhodium recovery from hydroformylation still heel with triaryl phosphite ligand
FR2428021A1 (fr) * 1978-06-05 1980-01-04 Kuraray Co Hydroformylation de composes olefiniques
EP0007768A3 (en) * 1978-07-27 1980-02-20 DAVY McKEE (LONDON) LIMITED Hydroformylation of alpha-olefinic compounds
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US4260828A (en) * 1980-04-16 1981-04-07 Union Carbide Corporation Hydroformylation process

Also Published As

Publication number Publication date
PL131753B1 (en) 1984-12-31
YU43040B (en) 1989-02-28
KR880000058B1 (ko) 1988-02-22
PL233146A1 (es) 1982-05-24
JPS607941B2 (ja) 1985-02-28
DE3163094D1 (en) 1984-05-17
KR830007136A (ko) 1983-10-14
SU1757458A3 (ru) 1992-08-23
JPS5787845A (en) 1982-06-01
MX158918A (es) 1989-03-30
BR8105868A (pt) 1982-06-08
YU228081A (en) 1984-08-31
EP0049781B1 (en) 1984-04-11
ES505725A0 (es) 1982-08-16
EP0049781A1 (en) 1982-04-21
US4605780A (en) 1986-08-12
ATE6992T1 (de) 1984-04-15
CA1187100A (en) 1985-05-14

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FD1A Patent lapsed

Effective date: 19971001