ES8205874A1 - Un procedimiento para eliminar li+ de una disolucion acuosa - Google Patents

Un procedimiento para eliminar li+ de una disolucion acuosa

Info

Publication number
ES8205874A1
ES8205874A1 ES498153A ES498153A ES8205874A1 ES 8205874 A1 ES8205874 A1 ES 8205874A1 ES 498153 A ES498153 A ES 498153A ES 498153 A ES498153 A ES 498153A ES 8205874 A1 ES8205874 A1 ES 8205874A1
Authority
ES
Spain
Prior art keywords
lithium
increasing
solutions
aluminates
content obtained
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES498153A
Other languages
English (en)
Other versions
ES498153A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of ES498153A0 publication Critical patent/ES498153A0/es
Publication of ES8205874A1 publication Critical patent/ES8205874A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/04—Processes using organic exchangers
    • B01J41/07—Processes using organic exchangers in the weakly basic form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J47/00—Ion-exchange processes in general; Apparatus therefor
    • B01J47/016—Modification or after-treatment of ion-exchangers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/14—Purification
    • C01D3/145—Purification by solid ion-exchangers or solid chelating agents
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Removal Of Specific Substances (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

UN PROCEDIMIENTO PARA ELIMINAR LI+ DE UNA DISOLUCION ACUOSA. PRIMERO, CARGAR LA SOLUCION ACUOSA DEL COMPUESTO DE LI+ CON UNA SAL METALICA NO COMPETITIVA; SEGUNDO, ALIMENTAR LA DISOLUCION CARGADA A TRAVES DE UNA COLUMNA QUE CONTIENE UN COMPUESTO DE RESINA ALUMINATO; TERCERO, PASAR UN LIQUIDO DE LAVADO ACUOSO A TRAVES DEL COMPUESTO PARA ELUDIR EL LI+ DEL COMPUESTO; CUARTO, DIRIGIR EL ELUATO OBTENIDO HACIA LOS MEDIOS DE FLUJO ADECUADOS; QUINTO, REPETIR EL PROCESO A TRAVES DE OTRAS COLUMNAS COLUMNAS CONECTADAS HASTA QUE EL ELUATO OBTENIDO TENGA UNA CONCENTRACION DE LI+ SUFICIENTE. EL COMPUESTO DE RESINA ALUMINATO SE MANTIENE A UNA TEMPERATURA COMPRENDIDA ENTRE 60 C Y LA DE REFLUJO.
ES498153A 1979-12-26 1980-12-24 Un procedimiento para eliminar li+ de una disolucion acuosa Expired ES8205874A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/106,961 US4291001A (en) 1979-12-26 1979-12-26 Recovery of lithium from brine

Publications (2)

Publication Number Publication Date
ES498153A0 ES498153A0 (es) 1982-06-16
ES8205874A1 true ES8205874A1 (es) 1982-06-16

Family

ID=22314142

Family Applications (1)

Application Number Title Priority Date Filing Date
ES498153A Expired ES8205874A1 (es) 1979-12-26 1980-12-24 Un procedimiento para eliminar li+ de una disolucion acuosa

Country Status (12)

Country Link
US (1) US4291001A (es)
EP (1) EP0032563A1 (es)
JP (1) JPS5696723A (es)
AU (1) AU6548580A (es)
BR (1) BR8008591A (es)
CA (1) CA1126481A (es)
ES (1) ES8205874A1 (es)
FI (1) FI803930L (es)
IL (1) IL61723A0 (es)
NO (1) NO803943L (es)
NZ (1) NZ195860A (es)
PT (1) PT72282B (es)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4540509A (en) * 1980-12-18 1985-09-10 The Dow Chemical Company Crystalline 3-layer lithium aluminates
US4477367A (en) * 1980-12-18 1984-10-16 The Dow Chemical Company Crystalline 2-layer lithium-hydroxy aluminates
US4376100A (en) * 1981-11-23 1983-03-08 The Dow Chemical Company Lithium halide brine purification
EP0117316B1 (en) * 1983-03-01 1986-08-13 The Dow Chemical Company A method of leaching lithium values from a brine-contaminated resin/aluminate composite
US4495160A (en) * 1983-03-28 1985-01-22 The Standard Oil Company Removal and recovery of magnesium, strontium and barium from brines
JPS6393355A (ja) * 1986-10-09 1988-04-23 Res Dev Corp Of Japan 金属イオン選択的イオン交換体
US4732441A (en) * 1987-05-14 1988-03-22 Cheng Teh Yao Oriented-reflection reflective mirror screen
US5599516A (en) 1993-05-24 1997-02-04 Fmc Corporation Recovery of lithium values from brines
US5389349A (en) * 1993-05-24 1995-02-14 Bauman; William C. Recovery of lithium values from brines
US5681477A (en) * 1995-10-25 1997-10-28 Praxair Technology, Inc. Thermally-driven ion-exchange process for lithium recovery
US6555078B1 (en) * 1996-09-26 2003-04-29 Fmc Corporation Method of preparing lithium salts
US8741256B1 (en) 2009-04-24 2014-06-03 Simbol Inc. Preparation of lithium carbonate from lithium chloride containing brines
US8753594B1 (en) 2009-11-13 2014-06-17 Simbol, Inc. Sorbent for lithium extraction
US8454816B1 (en) 2009-09-11 2013-06-04 Simbol Inc. Selective recovery of manganese and zinc from geothermal brines
US10190030B2 (en) 2009-04-24 2019-01-29 Alger Alternative Energy, Llc Treated geothermal brine compositions with reduced concentrations of silica, iron and lithium
US9051827B1 (en) 2009-09-02 2015-06-09 Simbol Mining Corporation Selective removal of silica from silica containing brines
US8637428B1 (en) 2009-12-18 2014-01-28 Simbol Inc. Lithium extraction composition and method of preparation thereof
US8597521B1 (en) 2009-06-24 2013-12-03 Simbol Inc. Selective removal of silica from silica containing brines
US9034294B1 (en) 2009-04-24 2015-05-19 Simbol, Inc. Preparation of lithium carbonate from lithium chloride containing brines
US9527753B1 (en) 2009-04-24 2016-12-27 Geothermal Energy Project, Llc Production of zinc chloride and zinc sulfate from geothermal brines
US10935006B2 (en) 2009-06-24 2021-03-02 Terralithium Llc Process for producing geothermal power, selective removal of silica and iron from brines, and improved injectivity of treated brines
US9644126B2 (en) 2009-06-24 2017-05-09 Simbol, Inc. Treated geothermal brine compositions with reduced concentrations of silica, iron, and zinc
US9534276B1 (en) 2011-06-29 2017-01-03 Geothermal Energy Project, Llc Separation of manganese from brine
US8518232B1 (en) 2011-06-29 2013-08-27 Simbol Inc. Selective recovery of manganese, lead and zinc
US10683563B2 (en) 2009-06-24 2020-06-16 Terralithium Llc Treated geothermal brine compositions with reduced concentrations of silica, iron and manganese
US9644866B2 (en) 2009-06-24 2017-05-09 Simbol, Inc. Treated brine compositions with reduced concentrations of potassium, rubidium, and cesium
US9650555B2 (en) 2009-06-24 2017-05-16 Simbol, Inc. Treated geothermal brine compositions with reduced concentrations of iron and silica
US9249478B2 (en) 2009-09-11 2016-02-02 Simbol, Inc. Selective recovery of manganese, lead and zinc
CN102947225A (zh) 2010-02-17 2013-02-27 辛博尔股份有限公司 高纯碳酸锂和其它高纯含锂化合物的制备方法
KR101047986B1 (ko) 2010-11-26 2011-07-13 한국지질자원연구원 Ｃｃｄ 공정을 이용한 리튬 이온의 흡착/탈착 장치 및 그 방법
US8309043B2 (en) 2010-12-06 2012-11-13 Fmc Corporation Recovery of Li values from sodium saturate brine
US10329160B2 (en) 2016-10-25 2019-06-25 Malvi Technologies, Llc Methods and equipment to make lithium hydroxide monohydrate from lithium salts
EP3538266B1 (en) 2016-11-14 2024-08-21 Lilac Solutions, Inc. Lithium extraction with coated ion exchange particles
US10604414B2 (en) 2017-06-15 2020-03-31 Energysource Minerals Llc System and process for recovery of lithium from a geothermal brine
US11365128B2 (en) 2017-06-15 2022-06-21 Energysource Minerals Llc Process for selective adsorption and recovery of lithium from natural and synthetic brines
AR112663A1 (es) 2017-08-02 2019-11-27 Lilac Solutions Inc Extracción de litio con perlas porosas de intercambio iónico
WO2019028174A2 (en) * 2017-08-02 2019-02-07 Lilac Solutions, Inc. ION EXCHANGE SYSTEM FOR LITHIUM EXTRACTION
AR114412A1 (es) 2018-02-28 2020-09-02 Lilac Solutions Inc Reactor de intercambio iónico con trampas de partículas para la extracción de litio
US11174532B1 (en) 2018-03-09 2021-11-16 Terralithium Llc Processes for producing lithium compounds using reverse osmosis
US11235282B2 (en) 2018-03-09 2022-02-01 Terralithium Llc Processes for producing lithium compounds using forward osmosis
RU2688593C1 (ru) * 2018-08-16 2019-05-21 Публичное акционерное общество "Татнефть" имени В.Д. Шашина Способ сорбционного извлечения лития из литийсодержащих хлоридных рассолов
CA3178825A1 (en) 2020-06-09 2021-12-16 David Henry SNYDACKER Lithium extraction in the presence of scalants
AR125722A1 (es) 2021-04-23 2023-08-09 Lilac Solutions Inc Dispositivos de intercambio iónico para la extracción de litio
WO2023192192A1 (en) 2022-03-28 2023-10-05 Lilac Solutions, Inc. Lithium extraction enhanced by an alternate phase
CN115011816B (zh) * 2022-06-02 2023-05-26 紫金矿业集团股份有限公司 从盐田氯化钙结晶中回收锂的方法
US11904297B1 (en) 2023-01-11 2024-02-20 Iliad Ip Company, Llc Process for manufacturing lithium selective adsorption/separation media

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4116858A (en) * 1977-07-05 1978-09-26 The Dow Chemical Company Recovery of lithium from brines
US4116856A (en) * 1977-07-05 1978-09-26 The Dow Chemical Company Recovery of lithium from brines

Also Published As

Publication number Publication date
NO803943L (no) 1981-06-29
AU6548580A (en) 1981-07-02
JPS5696723A (en) 1981-08-05
EP0032563A1 (en) 1981-07-29
ES498153A0 (es) 1982-06-16
CA1126481A (en) 1982-06-29
NZ195860A (en) 1983-07-15
PT72282B (en) 1982-07-13
PT72282A (en) 1981-01-01
US4291001A (en) 1981-09-22
IL61723A0 (en) 1981-01-30
BR8008591A (pt) 1981-07-21
FI803930L (fi) 1981-06-27

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