ES478657A1 - Procedimiento para la produccion de cristales mixtos (upu) o2 - Google Patents
Procedimiento para la produccion de cristales mixtos (upu) o2Info
- Publication number
- ES478657A1 ES478657A1 ES478657A ES478657A ES478657A1 ES 478657 A1 ES478657 A1 ES 478657A1 ES 478657 A ES478657 A ES 478657A ES 478657 A ES478657 A ES 478657A ES 478657 A1 ES478657 A1 ES 478657A1
- Authority
- ES
- Spain
- Prior art keywords
- plutonium
- manufacture
- uranium
- mixed crystals
- oxalate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052778 Plutonium Inorganic materials 0.000 title abstract 2
- 239000013078 crystal Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 abstract 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 2
- 229910052770 Uranium Inorganic materials 0.000 abstract 2
- SHZGCJCMOBCMKK-KGJVWPDLSA-N beta-L-fucose Chemical compound C[C@@H]1O[C@H](O)[C@@H](O)[C@H](O)[C@@H]1O SHZGCJCMOBCMKK-KGJVWPDLSA-N 0.000 abstract 2
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 abstract 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 235000012501 ammonium carbonate Nutrition 0.000 abstract 1
- 239000001099 ammonium carbonate Substances 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- ZQPKENGPMDNVKK-UHFFFAOYSA-N nitric acid;plutonium Chemical compound [Pu].O[N+]([O-])=O ZQPKENGPMDNVKK-UHFFFAOYSA-N 0.000 abstract 1
- OYEHPCDNVJXUIW-UHFFFAOYSA-N plutonium atom Chemical compound [Pu] OYEHPCDNVJXUIW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- KUKDDTFBSTXDTC-UHFFFAOYSA-N uranium;hexanitrate Chemical compound [U].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O KUKDDTFBSTXDTC-UHFFFAOYSA-N 0.000 abstract 1
- 229910002007 uranyl nitrate Inorganic materials 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
- G21C3/42—Selection of substances for use as reactor fuel
- G21C3/58—Solid reactor fuel Pellets made of fissile material
- G21C3/62—Ceramic fuel
- G21C3/623—Oxide fuels
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G56/00—Compounds of transuranic elements
- C01G56/003—Compounds comprising, besides transuranic elements, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G56/00—Compounds of transuranic elements
- C01G56/004—Compounds of plutonium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/20—Powder free flowing behaviour
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S376/00—Induced nuclear reactions: processes, systems, and elements
- Y10S376/90—Particular material or material shapes for fission reactors
- Y10S376/901—Fuel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Ceramic Engineering (AREA)
- Plasma & Fusion (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Procedimiento para la construcción de cristales mixtos (u/pu)02, solubles en ácido nítrico 10 M, como etapa previa para la fabricación de cuerpos de combustible nuclear sinterizados, con sustancias de partida con contenido en uranio y plutonio, caracterizado porque se mezclan y oxidan una solución de nitrato de uranio y una solución de nitrato de plutonio, hasta que también el plutonio alcanza la etapa de valencia VI; se añade esta mezcla a continuación a una solución al 20% aproximadamente de (NH4)2 CO3, mientras que al mismo tiempo se agrega dosificado NH3 para ajustar el valor pH a 8, 1-8, 5, así como CO2 en exceso; se mantiene la temperatura a 45-60ºC mientras se precipita el producto (NH4)n+ (u/pu)02 (CO3)3; y el producto obtenido se calcina en atmósfera reductora a 300 hasta 700º C y acontinuación se granula a (U/Pu)02 pulviforme con el deseado contenido de oxígeno estequiométrico.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2811959A DE2811959C3 (de) | 1978-03-18 | 1978-03-18 | Verfahren zur Herstellung von (U/Pu)02 -Mischkristallen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES478657A1 true ES478657A1 (es) | 1979-11-01 |
Family
ID=6034870
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES478657A Expired ES478657A1 (es) | 1978-03-18 | 1979-03-15 | Procedimiento para la produccion de cristales mixtos (upu) o2 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4235740A (es) |
| JP (1) | JPS54135699A (es) |
| AT (1) | AT362477B (es) |
| BE (1) | BE874887A (es) |
| BR (1) | BR7901662A (es) |
| CA (1) | CA1121146A (es) |
| CH (1) | CH645323A5 (es) |
| DE (1) | DE2811959C3 (es) |
| ES (1) | ES478657A1 (es) |
| FR (1) | FR2419924A1 (es) |
| GB (1) | GB2016431B (es) |
| IT (1) | IT1110507B (es) |
| PT (1) | PT69365A (es) |
| SE (1) | SE444429B (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2929122A1 (de) * | 1979-07-18 | 1981-02-05 | Alkem Gmbh | Verfahren zur elektrochemischen einstellung der pu (vi)-oxidationsstufe |
| DE3030647C2 (de) * | 1980-08-13 | 1983-09-29 | Alkem Gmbh, 6450 Hanau | Verfahren zur Gewinnung von (NH↓4↓)↓4↓(U/Pu)O↓2↓(CO↓3↓)↓3↓ mittels Oxidation von Plutonium (IV)-Nitrat |
| DE3101505C2 (de) * | 1980-08-13 | 1994-07-07 | Siemens Ag | Verfahren zum Behandeln von Plutoniumnitrat, gegebenenfalls zusammen mit Uranylnitrat |
| DE3038807A1 (de) * | 1980-10-14 | 1982-06-03 | Alkem Gmbh, 6450 Hanau | Verfahren zum aufloesen schwerloeslicher thorium- und/oder plutoiumoxide |
| DE3038880C2 (de) * | 1980-10-15 | 1985-05-02 | Martin Stoll GmbH, 7890 Waldshut-Tiengen | Vorrichtung zur stufenweisen Abstandsverstellung von zwei Stuhlteilen |
| US4923639A (en) * | 1981-01-19 | 1990-05-08 | Alkem Gmbh | Method of processing plutonium and/or uranyl nitrate |
| DE3147435C2 (de) * | 1981-11-30 | 1986-11-06 | Alkem Gmbh, 6450 Hanau | Verfahren zum Ausfällen von Ammonium-Uranyl-Plutonyl-Carbonat |
| DE3245051C2 (de) * | 1982-12-06 | 1986-09-25 | Alkem Gmbh, 6450 Hanau | Verfahren zum Herstellen von PuO↓2↓-haltigen Kristallen |
| US4637900A (en) * | 1984-01-13 | 1987-01-20 | The United States Of America As Represented By The United States Department Of Energy | Fabrication of high exposure nuclear fuel pellets |
| DE3408029A1 (de) * | 1984-03-05 | 1985-09-12 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur chargenweisen feinreinigung von in einem wiederaufarbeitungsprozess fuer bestrahlte kernbrenn- und/oder brutstoffe rueckzugewinnendem uran oder plutonium |
| JPH0729774B2 (ja) * | 1986-06-18 | 1995-04-05 | 三菱マテリアル株式会社 | Ｕｏ▲下２▼ペレツトの結晶粒径をコントロ−ルする方法 |
| FR2619371B1 (fr) * | 1987-08-14 | 1990-11-16 | Commissariat Energie Atomique | Uranate plutonate d'ammonium, son procede de preparation et son utilisation pour l'elaboration d'oxyde mixte (u, pu)o2 |
| DE4014584C2 (de) * | 1990-05-07 | 1994-06-30 | Kernforschungsz Karlsruhe | Verfahren zur Herstellung von Mischoxiden des Typs (A/B)0¶2¶ |
| EP0589076B1 (de) * | 1992-09-22 | 1996-01-03 | Siemens Aktiengesellschaft | Verfahren zum Herstellen von UO2-oder U/PuO2-Pulver |
| DE19627806A1 (de) * | 1996-07-11 | 1998-01-15 | Siemens Ag | Kernbrennstoffsinterkörper und Verfahren zum Herstellen eines Kernbrennstoffsinterkörpers |
| FR2870841B1 (fr) * | 2004-05-28 | 2007-02-09 | Commissariat Energie Atomique | Procede de coprecipitation d'actinides a des etats d'oxydation distincts et procede de preparation de composes mixtes d'actinides |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2843453A (en) * | 1947-04-18 | 1958-07-15 | Robert E Connick | Separation of plutonyl ions |
| BE567113A (es) * | 1957-06-04 | |||
| FR1329961A (fr) * | 1961-08-18 | 1963-06-14 | Atomic Energy Authority Uk | Procédé de production de combustibles pour réacteurs nucléaires |
| FR1489438A (fr) * | 1965-08-11 | 1967-07-21 | Atomic Energy Commission | Procédé pour la préparation d'un coprécipité filtrable de plutonium et d'uranium |
| US3287279A (en) * | 1965-08-11 | 1966-11-22 | Ward L Lyon | Preparation of a filterable co-precipitate of plutonium and uranium |
| FR1524785A (fr) * | 1967-05-29 | 1968-05-10 | Nukem Gmbh | Procédé pour la fabrication de dioxo-tricarbonate-uranate de tétrammonium, ainsi que les produits conformes à ceux obtenus par le présent procédé ou procédé similaire |
| GB1349982A (en) * | 1971-01-18 | 1974-04-10 | Atomic Energy Authority Uk | Preparation of solutions of mixed uranium and plutonium nitrates |
| US3976775A (en) * | 1975-05-06 | 1976-08-24 | The United States Of America As Represented By The United States Energy Research And Development Administration | Method for dissolving plutonium dioxide |
-
1978
- 1978-03-18 DE DE2811959A patent/DE2811959C3/de not_active Expired
-
1979
- 1979-01-22 CH CH61779A patent/CH645323A5/de not_active IP Right Cessation
- 1979-02-20 SE SE7901484A patent/SE444429B/sv not_active IP Right Cessation
- 1979-02-21 GB GB7906338A patent/GB2016431B/en not_active Expired
- 1979-02-26 FR FR7904906A patent/FR2419924A1/fr active Granted
- 1979-03-09 IT IT20858/79A patent/IT1110507B/it active
- 1979-03-13 US US06/020,012 patent/US4235740A/en not_active Expired - Lifetime
- 1979-03-15 ES ES478657A patent/ES478657A1/es not_active Expired
- 1979-03-16 CA CA000323537A patent/CA1121146A/en not_active Expired
- 1979-03-16 AT AT199079A patent/AT362477B/de active
- 1979-03-16 PT PT69365A patent/PT69365A/pt unknown
- 1979-03-16 BE BE0/194050A patent/BE874887A/xx not_active IP Right Cessation
- 1979-03-16 JP JP3098979A patent/JPS54135699A/ja active Granted
- 1979-03-16 BR BR7901662A patent/BR7901662A/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA1121146A (en) | 1982-04-06 |
| FR2419924B1 (es) | 1983-09-09 |
| JPS6228089B2 (es) | 1987-06-18 |
| BR7901662A (pt) | 1979-10-16 |
| SE7901484L (sv) | 1979-09-19 |
| JPS54135699A (en) | 1979-10-22 |
| AT362477B (de) | 1981-05-25 |
| PT69365A (de) | 1979-04-01 |
| ATA199079A (de) | 1980-10-15 |
| US4235740A (en) | 1980-11-25 |
| FR2419924A1 (fr) | 1979-10-12 |
| IT7920858A0 (it) | 1979-03-09 |
| IT1110507B (it) | 1985-12-23 |
| DE2811959C3 (de) | 1980-09-25 |
| GB2016431B (en) | 1982-07-28 |
| BE874887A (fr) | 1979-07-16 |
| CH645323A5 (de) | 1984-09-28 |
| DE2811959B2 (de) | 1980-01-31 |
| DE2811959A1 (de) | 1979-09-27 |
| SE444429B (sv) | 1986-04-14 |
| GB2016431A (en) | 1979-09-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19971001 |