ES2959535T3 - Composiciones poliméricas estabilizadas con organopolisulfuros - Google Patents
Composiciones poliméricas estabilizadas con organopolisulfuros Download PDFInfo
- Publication number
- ES2959535T3 ES2959535T3 ES18823708T ES18823708T ES2959535T3 ES 2959535 T3 ES2959535 T3 ES 2959535T3 ES 18823708 T ES18823708 T ES 18823708T ES 18823708 T ES18823708 T ES 18823708T ES 2959535 T3 ES2959535 T3 ES 2959535T3
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- Prior art keywords
- group
- polymer
- stabilized
- organopolysulfide
- tert
- Prior art date
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- 229920000642 polymer Polymers 0.000 claims abstract description 121
- 239000003381 stabilizer Substances 0.000 claims abstract description 65
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- -1 tert-amyl Chemical group 0.000 claims description 128
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- 239000005077 polysulfide Substances 0.000 claims description 29
- 229920001021 polysulfide Polymers 0.000 claims description 29
- 125000003118 aryl group Chemical group 0.000 claims description 25
- 230000000996 additive effect Effects 0.000 claims description 24
- 230000000087 stabilizing effect Effects 0.000 claims description 23
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- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 4
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
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- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 2
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- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 2
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- 125000004521 1,3,4-thiadiazol-2-yl group Chemical group S1C(=NN=C1)* 0.000 description 1
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- MAZSRFDGMAAKBY-UHFFFAOYSA-N 10-oxo-10-(2,2,6,6-tetramethylpiperidin-1-yl)oxydecanoic acid Chemical compound CC1(C)CCCC(C)(C)N1OC(=O)CCCCCCCCC(O)=O MAZSRFDGMAAKBY-UHFFFAOYSA-N 0.000 description 1
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical class CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 1
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- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
- C08K5/40—Thiurams, i.e. compounds containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
- C08L59/02—Polyacetals containing polyoxymethylene sequences only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/04—Polysulfides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/16—Homopolymers or copolymers of vinylidene fluoride
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/02—Disposition of insulation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/206—Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762526536P | 2017-06-29 | 2017-06-29 | |
| PCT/US2018/039901 WO2019006060A1 (en) | 2017-06-29 | 2018-06-28 | POLYMERIC COMPOSITIONS STABILIZED WITH ORGANOPOLYSULFIDES |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2959535T3 true ES2959535T3 (es) | 2024-02-26 |
Family
ID=64741848
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES18823708T Active ES2959535T3 (es) | 2017-06-29 | 2018-06-28 | Composiciones poliméricas estabilizadas con organopolisulfuros |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US11161965B2 (enExample) |
| EP (1) | EP3645511B1 (enExample) |
| JP (1) | JP7181234B2 (enExample) |
| KR (1) | KR102584689B1 (enExample) |
| CN (1) | CN110831923B (enExample) |
| BR (1) | BR112019028028B1 (enExample) |
| CA (1) | CA3067853A1 (enExample) |
| ES (1) | ES2959535T3 (enExample) |
| HU (1) | HUE064223T2 (enExample) |
| SG (1) | SG11201911924PA (enExample) |
| WO (1) | WO2019006060A1 (enExample) |
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| CN117957278A (zh) * | 2021-07-06 | 2024-04-30 | 阿科玛股份有限公司 | 用有机二硫化物共混物稳定的聚合物组合物 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL104900C (enExample) * | 1959-06-10 | |||
| US3703454A (en) * | 1969-05-26 | 1972-11-21 | Japan Atomic Energy Res Inst | Polymerization of tetraoxane in the presence of sulfur and sulfur compounds |
| US3843600A (en) | 1972-05-08 | 1974-10-22 | Ashland Oil Inc | Stabilization of olefin polymers |
| FR2199757A5 (enExample) * | 1972-09-20 | 1974-04-12 | Ethylene Plastique Sa | |
| US3978022A (en) * | 1974-07-08 | 1976-08-31 | Rohm And Haas Company | Thermal stabilization of acrylic polymers |
| GB2043079B (en) | 1979-02-26 | 1982-12-08 | El Paso Polyolefins | High energy radiation treatment of stabilised propylene polymers |
| US4535127A (en) * | 1983-03-23 | 1985-08-13 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyacetal copolymers and process for production thereof |
| WO1992011322A2 (en) * | 1990-12-20 | 1992-07-09 | Exxon Chemical Patents Inc. | Uv/eb curable butyl copolymers for lithographic and corrosion-resistant coating applications |
| ES2118838T3 (es) * | 1991-10-17 | 1998-10-01 | Exxon Chemical Patents Inc | Copolimeros de isoolefina curables por radiacion. |
| US5258422A (en) * | 1992-05-05 | 1993-11-02 | Tredegar Industries, Inc. | Compostable thermoplastic compositions |
| KR100394565B1 (ko) | 1992-09-25 | 2003-11-20 | 시바 스페셜티 케미칼스 홀딩 인크. | 재생된플라스틱혼합물을안정화시키는방법및이를위한안정화제혼합물 |
| US5912212A (en) * | 1995-12-28 | 1999-06-15 | Nippon Oil Co., Ltd. | Lubricating oil composition |
| US6214915B1 (en) | 1998-12-10 | 2001-04-10 | General Electric Company | Stabilized thermoplastic compositions |
| DE19903390A1 (de) * | 1999-01-29 | 2000-08-03 | Bayer Ag | Stabilisierte, feindisperse niedrigviskose Polymerpolyole mit einem hohen Gehalt an Polystyrol oder Polystyrol-Copolymerisaten |
| WO2004033545A1 (en) * | 2002-10-08 | 2004-04-22 | Borealis Technology Oy | Stabilized polymer composition |
| US7579396B2 (en) * | 2007-01-31 | 2009-08-25 | Eastman Kodak Company | Polymer composite |
| US20080269085A1 (en) * | 2007-04-30 | 2008-10-30 | Chevron U.S.A. Inc. | Lubricating oil composition containing alkali metal borates with improved frictional properties |
| EP2207848B1 (en) | 2007-11-06 | 2011-10-19 | DSM IP Assets B.V. | Process for producing high molecular weight polyethylene |
| JP2009191199A (ja) * | 2008-02-15 | 2009-08-27 | Nof Corp | 架橋ゴムの製造方法 |
| EP2297239A1 (en) | 2008-07-02 | 2011-03-23 | Basf Se | Blends of stabilizers for aliphatic polyesters |
| TR201909357T4 (tr) * | 2012-02-20 | 2019-07-22 | Basf Se | Polifenol disülfitlerin üretimine yönelik yöntem. |
| US20160215082A1 (en) * | 2013-09-11 | 2016-07-28 | Sumitomo Chemical Company, Limited | Methacrylic resin composition |
| GB201320919D0 (en) | 2013-11-27 | 2014-01-08 | Addivant Switzerland Gmbh | Composition |
| JPWO2015136792A1 (ja) * | 2014-03-12 | 2017-04-06 | デンカ株式会社 | ゴム組成物及びその加硫物 |
| CN103937447A (zh) | 2014-04-25 | 2014-07-23 | 东莞泰和沥青产品有限公司 | 抗低温灌缝胶及加工工艺 |
| CN106459537A (zh) | 2014-05-15 | 2017-02-22 | Sabic环球技术有限责任公司 | 稳定的树脂组合物 |
| WO2016094381A1 (en) * | 2014-12-11 | 2016-06-16 | Ticona Llc | Stabilized flexible thermoplastic composition and products formed therefrom |
| EP3388481A4 (en) * | 2015-12-08 | 2019-08-21 | Sumitomo Seika Chemicals Co. Ltd. | ADDITIVE FOR RUBBER |
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- 2018-06-28 ES ES18823708T patent/ES2959535T3/es active Active
- 2018-06-28 BR BR112019028028-6A patent/BR112019028028B1/pt active IP Right Grant
- 2018-06-28 EP EP18823708.5A patent/EP3645511B1/en active Active
- 2018-06-28 KR KR1020207002670A patent/KR102584689B1/ko active Active
- 2018-06-28 CN CN201880043658.7A patent/CN110831923B/zh active Active
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- 2018-06-28 SG SG11201911924PA patent/SG11201911924PA/en unknown
- 2018-06-28 WO PCT/US2018/039901 patent/WO2019006060A1/en not_active Ceased
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Also Published As
| Publication number | Publication date |
|---|---|
| US11161965B2 (en) | 2021-11-02 |
| CN110831923A (zh) | 2020-02-21 |
| CN110831923B (zh) | 2022-08-09 |
| EP3645511A1 (en) | 2020-05-06 |
| BR112019028028A2 (pt) | 2020-07-07 |
| EP3645511B1 (en) | 2023-08-16 |
| EP3645511C0 (en) | 2023-08-16 |
| EP3645511A4 (en) | 2021-03-24 |
| CA3067853A1 (en) | 2019-01-03 |
| US20190194423A1 (en) | 2019-06-27 |
| KR102584689B1 (ko) | 2023-10-10 |
| BR112019028028B1 (pt) | 2023-03-21 |
| SG11201911924PA (en) | 2020-01-30 |
| JP2020526606A (ja) | 2020-08-31 |
| HUE064223T2 (hu) | 2024-02-28 |
| KR20200024865A (ko) | 2020-03-09 |
| WO2019006060A1 (en) | 2019-01-03 |
| JP7181234B2 (ja) | 2022-11-30 |
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