ES2886525T3 - Procedimiento para preparar una membrana de fibra hueca de tamiz molecular de carbono modificada asimétrica y uso del mismo - Google Patents
Procedimiento para preparar una membrana de fibra hueca de tamiz molecular de carbono modificada asimétrica y uso del mismo Download PDFInfo
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- ES2886525T3 ES2886525T3 ES14848035T ES14848035T ES2886525T3 ES 2886525 T3 ES2886525 T3 ES 2886525T3 ES 14848035 T ES14848035 T ES 14848035T ES 14848035 T ES14848035 T ES 14848035T ES 2886525 T3 ES2886525 T3 ES 2886525T3
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- modifying agent
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- hollow fiber
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- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- ZEIWWVGGEOHESL-UHFFFAOYSA-N methanol;titanium Chemical compound [Ti].OC.OC.OC.OC ZEIWWVGGEOHESL-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
- 238000004452 microanalysis Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920002627 poly(phosphazenes) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920002577 polybenzoxazole Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
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- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- HKJYVRJHDIPMQB-UHFFFAOYSA-N propan-1-olate;titanium(4+) Chemical compound CCCO[Ti](OCCC)(OCCC)OCCC HKJYVRJHDIPMQB-UHFFFAOYSA-N 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 230000017105 transposition Effects 0.000 description 1
- SGCFZHOZKKQIBU-UHFFFAOYSA-N tributoxy(ethenyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C=C SGCFZHOZKKQIBU-UHFFFAOYSA-N 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/021—Carbon
- B01D71/0211—Graphene or derivates thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0067—Inorganic membrane manufacture by carbonisation or pyrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/021—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/021—Carbon
- B01D71/0212—Carbon nanotubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/12—Specific ratios of components used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
- B01D2325/0231—Dense layers being placed on the outer side of the cross-section
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
- B01D2325/0232—Dense layer on both outer sides of the membrane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
- B01D2325/0233—Asymmetric membranes with clearly distinguishable layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/20—Specific permeability or cut-off range
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/22—Thermal or heat-resistance properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/20—Capture or disposal of greenhouse gases of methane
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Inorganic Fibers (AREA)
- Carbon And Carbon Compounds (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
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US201361884548P | 2013-09-30 | 2013-09-30 | |
PCT/US2014/058329 WO2015048754A1 (en) | 2013-09-30 | 2014-09-30 | Asymmetric modified carbon molecular sieve hollow fiber membranes having improved permeance |
Publications (1)
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ES2886525T3 true ES2886525T3 (es) | 2021-12-20 |
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Family Applications (1)
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ES14848035T Active ES2886525T3 (es) | 2013-09-30 | 2014-09-30 | Procedimiento para preparar una membrana de fibra hueca de tamiz molecular de carbono modificada asimétrica y uso del mismo |
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US (3) | US9815030B2 (zh) |
EP (2) | EP3052222B1 (zh) |
JP (1) | JP6487910B2 (zh) |
KR (1) | KR102130876B1 (zh) |
CN (2) | CN105792917B (zh) |
AU (2) | AU2014324439B2 (zh) |
BR (1) | BR112016007089A2 (zh) |
EA (1) | EA034734B1 (zh) |
ES (1) | ES2886525T3 (zh) |
MY (1) | MY177312A (zh) |
SA (1) | SA516370840B1 (zh) |
WO (1) | WO2015048754A1 (zh) |
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US10352833B2 (en) * | 2015-07-22 | 2019-07-16 | The Florida International University Board Of Trustees | Microextraction capsules and method of making |
MY192760A (en) | 2015-07-28 | 2022-09-07 | Shell Int Research | Process for preparing a paraffin product |
BR112018011094B1 (pt) | 2015-12-17 | 2023-03-07 | Dow Global Technologies Llc | Método para fazer uma membrana de peneira molecular de carbono, e, processo para separar uma molécula de gás de uma alimentação de gás |
US10968105B2 (en) | 2016-03-28 | 2021-04-06 | Board Of Regents, The University Of Texas System | Low-temperature pyrolysis of organic acid salts providing graphene rich carbons |
JP7078544B2 (ja) * | 2016-04-29 | 2022-05-31 | ダウ グローバル テクノロジーズ エルエルシー | 改善された遷移金属含有炭素分子篩膜及びそれらを作製する方法 |
CA3043164A1 (en) * | 2016-11-10 | 2018-05-17 | Dow Global Technologies Llc | Improved method to make carbon molecular sieve hollow fiber membranes |
IDP201907952A (zh) * | 2017-02-10 | 2019-11-08 | ||
JP2020518446A (ja) | 2017-05-04 | 2020-06-25 | サウジ アラビアン オイル カンパニー | 架橋ポリマー膜およびその製造方法 |
US20190030491A1 (en) * | 2017-07-25 | 2019-01-31 | Georgia Tech Research Corporation | Methods for preparing carbon molecular sieve hollow fiber membranes for gas separation |
BR112020002664B1 (pt) | 2017-08-14 | 2024-03-12 | Dow Global Technologies Llc | Método para produzir uma membrana de peneira molecular de carbono de fibra oca, processo para separar uma molécula de gás de uma alimentação de gás compreendida da molécula de gás e pelo menos uma outra molécula de gás e módulo de separação de gás |
US20190054427A1 (en) * | 2017-08-15 | 2019-02-21 | Georgia Tech Research Corporation | Methods for regenerating aged carbon molecular sieve membranes |
KR101950107B1 (ko) * | 2017-09-05 | 2019-02-19 | 한양대학교 에리카산학협력단 | 중공 섬유 복합체의 제조 방법 |
CN115888411A (zh) * | 2017-10-30 | 2023-04-04 | 陶氏环球技术有限责任公司 | 含第13族金属的碳分子筛膜和其制造方法 |
CN108993400A (zh) * | 2018-09-14 | 2018-12-14 | 河南环宇石化装备科技股份有限公司 | 一种分离氮气-甲烷的高效吸附剂的制备方法 |
CN114340764B (zh) * | 2019-05-01 | 2024-03-05 | 阿卜杜拉国王科技大学 | 杂化无机氧化物-碳分子筛膜 |
CN110508165A (zh) * | 2019-08-09 | 2019-11-29 | 大连理工大学 | 天然气提浓氦气多孔碳纳米球混合基质复合膜及其制备方法 |
KR102104426B1 (ko) | 2019-12-03 | 2020-04-24 | 주식회사 이피엠 | 고분자 수지의 함침성이 우수한 복합 중공사막 제조방법과 이에 의해 제조된 복합 중공사막 |
EP4164983A1 (en) | 2020-06-10 | 2023-04-19 | Shell Internationale Research Maatschappij B.V. | Method for the production of hydrogen |
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---|---|---|---|---|
US20020102674A1 (en) * | 1987-05-20 | 2002-08-01 | David M Anderson | Stabilized microporous materials |
US5234471A (en) | 1992-02-04 | 1993-08-10 | E. I. Du Pont De Nemours And Company | Polyimide gas separation membranes for carbon dioxide enrichment |
CN1099310C (zh) * | 1998-04-16 | 2003-01-22 | 中国科学院大连化学物理研究所 | 一种聚酰亚胺不对称中空纤维膜的制备方法 |
JP4081956B2 (ja) * | 1999-03-05 | 2008-04-30 | 宇部興産株式会社 | 部分炭素化された非対称性中空糸分離膜とその製法およびガス分離方法 |
US6299669B1 (en) | 1999-11-10 | 2001-10-09 | The University Of Texas System | Process for CO2/natural gas separation |
EP1118371B1 (en) * | 2000-01-19 | 2007-04-11 | Ube Industries, Ltd. | Gas separation membrane and its use |
JP4711544B2 (ja) | 2001-05-29 | 2011-06-29 | 京セラ株式会社 | 流体分離セル及び流体分離装置 |
JP2002355538A (ja) * | 2001-05-30 | 2002-12-10 | Asahi Medical Co Ltd | 炭素繊維中空糸膜用セルロース中空糸膜およびその製造方法 |
US7404844B2 (en) * | 2004-02-26 | 2008-07-29 | National University Of Singapore | Method for making carbon membranes for fluid separation |
US20090126570A1 (en) * | 2007-11-15 | 2009-05-21 | Chunqing Liu | Polymer Functionalized Molecular Sieve/Polymer Mixed Matrix Membranes |
EP2281926B1 (en) * | 2008-05-19 | 2018-09-05 | IUCF-HYU (Industry-University Cooperation Foundation Hanyang University) | Hollow fiber and method for manufacturing a hollow fiber |
CA2640545A1 (en) * | 2008-05-19 | 2009-11-19 | Industry-University Cooperation Foundation, Hanyang University | Polyimides dope composition, preparation method of hollow fiber using the same and hollow fiber prepared therefrom |
CN102448593A (zh) * | 2009-03-27 | 2012-05-09 | 环球油品公司 | 高性能的交联的聚苯并噁唑和聚苯并噻唑聚合物膜 |
US8561812B2 (en) * | 2009-03-27 | 2013-10-22 | Uop Llc | Blend polymer membranes comprising thermally rearranged polymers derived from aromatic polyimides containing ortho-positioned functional groups |
US7810652B2 (en) * | 2009-09-25 | 2010-10-12 | Uop Llc | Method to improve the selectivity of polybenzoxazole membranes |
US8486179B2 (en) | 2009-10-29 | 2013-07-16 | Georgia Tech Research Corporation | Method for producing carbon molecular sieve membranes in controlled atmospheres |
US8366804B2 (en) * | 2010-05-28 | 2013-02-05 | Uop Llc | High permeance polyimide membranes for air separation |
US20110316181A1 (en) | 2010-06-25 | 2011-12-29 | Uop Llc | Process of making asymmetric polybenzoxazole membranes |
EP2683473A1 (en) * | 2011-03-07 | 2014-01-15 | Georgia Tech Research Corporation | Polyimide-based carbon molecular sieve membrane for ethylene/ethane separations |
EP2794067B1 (en) * | 2011-12-20 | 2020-03-25 | Georgia Tech Research Corporation | Stabilization of porous morphologies for high performance carbon molecular sieve hollow fiber membranes |
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US20210379538A1 (en) | 2021-12-09 |
BR112016007089A2 (pt) | 2020-05-12 |
US11123693B2 (en) | 2021-09-21 |
CN110694495A (zh) | 2020-01-17 |
MY177312A (en) | 2020-09-11 |
KR20160070087A (ko) | 2016-06-17 |
WO2015048754A1 (en) | 2015-04-02 |
US20180071691A1 (en) | 2018-03-15 |
SA516370840B1 (ar) | 2018-09-26 |
AU2014324439A1 (en) | 2016-04-21 |
AU2018200567B2 (en) | 2020-04-02 |
CN105792917A (zh) | 2016-07-20 |
AU2018200567A1 (en) | 2018-02-15 |
US9815030B2 (en) | 2017-11-14 |
KR102130876B1 (ko) | 2020-07-09 |
US11992814B2 (en) | 2024-05-28 |
EA201690609A1 (ru) | 2017-01-30 |
AU2014324439B2 (en) | 2017-10-26 |
CN105792917B (zh) | 2019-10-11 |
EP3052222B1 (en) | 2021-05-12 |
US20150094445A1 (en) | 2015-04-02 |
JP2016539782A (ja) | 2016-12-22 |
EA034734B1 (ru) | 2020-03-13 |
EP3052222A4 (en) | 2017-06-07 |
EP3052222A1 (en) | 2016-08-10 |
JP6487910B2 (ja) | 2019-03-20 |
EP3862073A1 (en) | 2021-08-11 |
CN110694495B (zh) | 2022-09-16 |
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