ES2869983T3 - Polímeros a base de etileno con bajo contenido de extraíbles con hexano - Google Patents

Polímeros a base de etileno con bajo contenido de extraíbles con hexano Download PDF

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Publication number
ES2869983T3
ES2869983T3 ES16742074T ES16742074T ES2869983T3 ES 2869983 T3 ES2869983 T3 ES 2869983T3 ES 16742074 T ES16742074 T ES 16742074T ES 16742074 T ES16742074 T ES 16742074T ES 2869983 T3 ES2869983 T3 ES 2869983T3
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Spain
Prior art keywords
ethylene
reactor
cta
zone
reaction zone
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ES16742074T
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English (en)
Spanish (es)
Inventor
Stefan Hinrichs
Doelder Cornelis F J Den
Nhi T Y Dang
Otto J Berbee
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2415Tubular reactors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/28Oxygen or compounds releasing free oxygen
    • C08F4/32Organic compounds
    • C08F4/38Mixtures of peroxy-compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00Characteristics for processes of polymerization
    • C08F2400/02Control or adjustment of polymerization parameters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/08Low density, i.e. < 0.91 g/cm3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17Viscosity
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
ES16742074T 2015-06-25 2016-06-23 Polímeros a base de etileno con bajo contenido de extraíbles con hexano Active ES2869983T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562184344P 2015-06-25 2015-06-25
PCT/US2016/038900 WO2016210055A1 (en) 2015-06-25 2016-06-23 Ethylene-based polymers with low hexane extractables

Publications (1)

Publication Number Publication Date
ES2869983T3 true ES2869983T3 (es) 2021-10-26

Family

ID=56409164

Family Applications (2)

Application Number Title Priority Date Filing Date
ES16742074T Active ES2869983T3 (es) 2015-06-25 2016-06-23 Polímeros a base de etileno con bajo contenido de extraíbles con hexano
ES16738267T Active ES2775506T3 (es) 2015-06-25 2016-06-23 Polímeros basados en etileno con bajo contenido de extraíbles con hexano

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES16738267T Active ES2775506T3 (es) 2015-06-25 2016-06-23 Polímeros basados en etileno con bajo contenido de extraíbles con hexano

Country Status (8)

Country Link
US (2) US10358512B2 (enExample)
EP (2) EP3313904B1 (enExample)
JP (5) JP7510740B2 (enExample)
KR (2) KR102612773B1 (enExample)
CN (2) CN107810208B (enExample)
BR (2) BR112017027564B1 (enExample)
ES (2) ES2869983T3 (enExample)
WO (2) WO2016210055A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3087112B1 (en) 2013-12-26 2019-01-30 Dow Global Technologies LLC Processes to improve reactor stability for the preparation of ethylene-based polymers using asymmetrical polyenes
EP3626752B1 (en) 2013-12-26 2021-04-21 Dow Global Technologies LLC Ethylene-based polymers formed using asymmetrical polyenes
WO2016210055A1 (en) * 2015-06-25 2016-12-29 Dow Global Technologies Llc Ethylene-based polymers with low hexane extractables
US10730973B2 (en) * 2015-06-25 2020-08-04 Dow Global Technologies Llc Ethylene-based polymers with low hexane extractables and low densities
EP3168238A1 (en) 2015-11-10 2017-05-17 Dow Global Technologies LLC Ethylene-based polymers formed by high pressure free radical polymerizations
JP6946331B2 (ja) * 2016-04-22 2021-10-06 ダウ グローバル テクノロジーズ エルエルシー 清浄な押出コーティング処理のための低揮発性管状低密度エチレン系ポリマーを製造する方法
EP3260473A1 (en) 2016-06-24 2017-12-27 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
EP3260472A1 (en) * 2016-06-24 2017-12-27 Dow Global Technologies LLC Ethylene-based polymers formed by high pressure free radical polymerizations
WO2018223045A1 (en) 2017-06-02 2018-12-06 Dow Global Technologies Llc Ethylene-based polymers and processes for the same
CN110240654A (zh) 2018-03-07 2019-09-17 复旦大学 结合cd73的抗体-药物偶联物
WO2025064134A1 (en) * 2023-09-20 2025-03-27 Dow Global Technologies Llc Ethylene-based polymer and process for producing the same

Family Cites Families (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE607527A (enExample) 1960-08-29 1900-01-01
US3917577A (en) 1968-09-20 1975-11-04 Basf Ag Continuous production of ethylene homopolymers
DE1807493C3 (de) 1968-11-07 1980-05-22 Basf Ag, 6700 Ludwigshafen Verfahren zum kontinuierlichen Herstellen von Äthylenhomopolymerisaten
EP0292215B2 (en) 1987-05-19 1997-10-08 Hitachi Chemical Co., Ltd. Method for production of methacrylate ester
DD276598A3 (de) 1988-04-12 1990-03-07 Leuna Werke Veb Verfahren zur einstellung und regelung der einsatzgasstroeme fuer mehrzonenrohrreaktoren
US5102955A (en) * 1989-12-29 1992-04-07 Mobil Oil Corporation Broad distribution, high molecular weight low density polyethylene and method of making thereof
US5126391A (en) * 1990-04-27 1992-06-30 Mitsubishi Petrochemical Co., Ltd. Filler-containing stretched film
SE9103077D0 (sv) 1991-10-22 1991-10-22 Neste Oy Omaettad etensampolymer och saett foer framstaellning daerav
SE507045C2 (sv) 1996-05-31 1998-03-23 Borealis As Etensampolymer med förhöjd omättnadsgrad och sätt för framställning därav
DE69826103T3 (de) * 1998-01-12 2012-07-12 Dow Global Technologies Inc. Äthylenpolymere mittlerer Dichte, Verfahren zur Herstellung dieser Polymere und Verwendung von Carbonyl-haltigen Kettenübertragungsmitteln in diesem Verfahren
JP3678907B2 (ja) * 1998-03-10 2005-08-03 三菱製紙株式会社 感光材料用支持体
DE19829399A1 (de) 1998-07-01 2000-02-03 Buna Sow Leuna Olefinverb Gmbh Verfahren zur Herstellung von Ethylenhomo- und Ethylencopolymerisaten niederer Dichte
CN1186358C (zh) 2000-03-16 2005-01-26 巴塞尔聚烯烃股份有限公司 聚乙烯的制备方法
BR0113218B1 (pt) 2000-08-15 2010-12-28 uso de trioxepanos em processos para a fabricação de resinas acrìlicas, estirênicas e do tipo ldpe, de alto teor de sólidos.
KR100833763B1 (ko) 2000-08-15 2008-05-29 아크조 노벨 엔.브이. 하이솔리드 아크릴, 스티렌 및 ldpe-형 수지를 제조하는데 사용되는 트리옥세판의 용도
US6596241B2 (en) 2001-12-19 2003-07-22 Exxonmobil Chemical Patents Inc Tubular polymerization reactors and polymers made therein
WO2004090206A1 (en) * 2003-04-03 2004-10-21 E.I. Dupont De Nemours And Company Rotary process for forming uniform material
PL1861434T3 (pl) 2005-03-09 2013-09-30 Saudi Basic Ind Corp Sposób otrzymywania kopolimeru etylenu w reaktorze rurowym
US7078467B1 (en) * 2005-06-14 2006-07-18 Univation Technologies, Llc Single catalyst low, medium and high density polyethylenes
PL1999170T3 (pl) 2006-03-24 2011-12-30 Saudi Basic Ind Corp Kompozycja do powlekania przez wytłaczanie
US7449287B1 (en) * 2008-01-30 2008-11-11 Eastman Kodak Company Pearlescent textured imaging supports
CN101970005A (zh) 2008-02-08 2011-02-09 斯克利普斯研究院 用遗传编码的非天然氨基酸打破免疫耐受
EA019226B9 (ru) * 2008-07-10 2014-05-30 Бореалис Аг Способ получения полиолефина, применение смеси по меньшей мере двух агентов переноса цепи для получения полиолефина, полиэтилен низкой плотности, способ получения кабеля и кабель
JP2010068637A (ja) 2008-09-11 2010-03-25 Mitsumi Electric Co Ltd 充電制御用半導体集積回路
US8535377B2 (en) 2009-03-31 2013-09-17 Imds Corporation Double bundle ACL repair system
KR101668146B1 (ko) * 2010-02-22 2016-10-20 다우 글로벌 테크놀로지스 엘엘씨 도장된 폴리올레핀 물품
KR101911673B1 (ko) * 2010-09-30 2018-10-24 다우 글로벌 테크놀로지스 엘엘씨 저밀도 폴리에틸렌을 제조하는 중합 방법
CN103282391B (zh) * 2010-10-29 2016-12-07 陶氏环球技术有限责任公司 基于乙烯的聚合物及其制备方法
EP2655444B2 (en) 2010-12-22 2018-11-21 Basell Polyolefine GmbH Process for the preparation of ethylene copolymers in the presence of free-radical polymerization initiator by copolymerizing ethylene, a bi- or multifunctional comonomer and optionally further comonomers
CN103403040B (zh) 2011-03-03 2015-11-25 巴塞尔聚烯烃股份有限公司 在具有至少两个具有不同链转移剂浓度的反应区的管式反应器中制备乙烯均聚物或共聚物的方法
EP2751146B1 (en) 2011-10-19 2016-01-20 Dow Global Technologies LLC Polymerization processes with fresh ethylene distributions for preparation of low density ethylene-based polymers
IN2014CN03782A (enExample) * 2011-11-23 2015-09-25 Dow Global Technologies Llc
KR101945575B1 (ko) 2011-11-23 2019-02-07 다우 글로벌 테크놀로지스 엘엘씨 더 낮은 분자량의 추출물을 갖는 저밀도 에틸렌-계 중합체
BR112014009337A2 (pt) 2011-12-09 2017-04-18 Borealis Ag polietileno de baixa densidade, composição, processo para produção de polietileno de baixa densidade, método de polimerização contínua, método para um processo de revestimento por extrusão, artigo e uso
KR101989335B1 (ko) 2011-12-22 2019-06-17 다우 글로벌 테크놀로지스 엘엘씨 개선된 용융 강도를 가진 에틸렌-기재 중합체 및 그의 제조 방법
EP2636691A1 (en) 2012-03-07 2013-09-11 Borealis AG Process and plant for manufacturing polyethylene-diene-copolymers
MX374238B (es) 2012-04-02 2025-03-05 Borealis Ag Proceso de polimerizacion de etileno usando un inhibidor.
EP2647650B1 (en) 2012-04-02 2015-06-17 Borealis AG High-pressure radical ethylene co-polymerization process with a reduced temperature of the reaction mixture prior to introduction into the reaction zone
EP2834279B1 (en) 2012-04-02 2018-02-21 Borealis AG High-pressure radical ethylene polymerization process in which ethylene is polymerized with a specific polyunsaturated olefin grade
JP6007319B2 (ja) 2012-05-31 2016-10-12 ボレアリス・アクチェンゲゼルシャフトBorealis Ag 押出コーティング用の低密度ポリエチレン
EP2855537B2 (en) 2012-05-31 2024-01-10 Borealis AG Ethylene polymers for extrusion coating
US10442878B2 (en) 2012-06-27 2019-10-15 Dow Global Technologies Llc Ethylene-based polymers and processes for the same
BR112015010787B1 (pt) * 2012-11-20 2022-01-18 Dow Global Technologies Llc Composição a base de etileno de baixa densidade, artigo e método de polimerização para formar uma composição a base de etileno de baixa densidade
CN105189638B (zh) 2013-05-22 2018-02-06 陶氏环球技术有限责任公司 在高熔体强度和中‑高密度控制下的基于低密度乙烯的聚合物组合物
ES2975010T3 (es) * 2013-05-22 2024-07-02 Dow Global Technologies Llc Composiciones que contienen polímeros a base de etileno de baja densidad con alta resistencia en estado fundido y películas formadas a partir de las mismas
WO2015166297A1 (en) 2014-04-30 2015-11-05 Exxonmobil Chemical Patents Inc. Process for manufacturing ethylene polymers and copolymers
CN106715486B (zh) 2014-07-24 2020-07-31 Sabic环球技术有限责任公司 用于制备乙烯共聚物的方法
WO2016210055A1 (en) * 2015-06-25 2016-12-29 Dow Global Technologies Llc Ethylene-based polymers with low hexane extractables

Also Published As

Publication number Publication date
KR20180021070A (ko) 2018-02-28
WO2016210055A1 (en) 2016-12-29
CN107810208B (zh) 2020-07-24
CN107810208A (zh) 2018-03-16
EP3313903A1 (en) 2018-05-02
US20180127523A1 (en) 2018-05-10
WO2016210075A1 (en) 2016-12-29
EP3313904A1 (en) 2018-05-02
JP2018522972A (ja) 2018-08-16
KR102612773B1 (ko) 2023-12-12
JP7510740B2 (ja) 2024-07-04
JP2018518577A (ja) 2018-07-12
EP3313903B1 (en) 2020-01-01
KR102577959B1 (ko) 2023-09-14
BR112017027866A2 (pt) 2018-08-28
CN107787334B (zh) 2020-07-24
JP2024037861A (ja) 2024-03-19
US20180112017A1 (en) 2018-04-26
BR112017027564A2 (pt) 2018-09-04
JP2022008573A (ja) 2022-01-13
BR112017027866B1 (pt) 2022-05-24
US10494460B2 (en) 2019-12-03
CN107787334A (zh) 2018-03-09
JP2024056727A (ja) 2024-04-23
JP7436135B2 (ja) 2024-02-21
KR20180021067A (ko) 2018-02-28
US10358512B2 (en) 2019-07-23
ES2775506T3 (es) 2020-07-27
BR112017027564B1 (pt) 2022-02-01
EP3313904B1 (en) 2021-04-21

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