ES2795021T3 - Espumas y composiciones espumables que contienen agentes espumantes de olefina halogenada - Google Patents

Espumas y composiciones espumables que contienen agentes espumantes de olefina halogenada Download PDF

Info

Publication number
ES2795021T3
ES2795021T3 ES10808524T ES10808524T ES2795021T3 ES 2795021 T3 ES2795021 T3 ES 2795021T3 ES 10808524 T ES10808524 T ES 10808524T ES 10808524 T ES10808524 T ES 10808524T ES 2795021 T3 ES2795021 T3 ES 2795021T3
Authority
ES
Spain
Prior art keywords
weight
foaming agent
amount
amine
polyol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES10808524T
Other languages
English (en)
Spanish (es)
Inventor
David J Williams
Clifford P Gittere
Der Puy Michael Van
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell International Inc
Original Assignee
Honeywell International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honeywell International Inc filed Critical Honeywell International Inc
Application granted granted Critical
Publication of ES2795021T3 publication Critical patent/ES2795021T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/18Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1808Catalysts containing secondary or tertiary amines or salts thereof having alkylene polyamine groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/18Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1816Catalysts containing secondary or tertiary amines or salts thereof having carbocyclic groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143Halogen containing compounds
    • C08J9/144Halogen containing compounds containing carbon, halogen and hydrogen only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143Halogen containing compounds
    • C08J9/144Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00Manufacture of cellular products
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0041Foam properties having specified density
    • C08G2110/005< 50kg/m3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00Oligomerisation
    • C08G2115/02Oligomerisation to isocyanurate groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/14Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
ES10808524T 2009-08-11 2010-08-02 Espumas y composiciones espumables que contienen agentes espumantes de olefina halogenada Active ES2795021T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US23283609P 2009-08-11 2009-08-11
US12/847,381 US9695267B2 (en) 2009-08-11 2010-07-30 Foams and foamable compositions containing halogenated olefin blowing agents
PCT/US2010/044064 WO2011019528A2 (en) 2009-08-11 2010-08-02 Foams and foamable compositions containing halogenated olefin blowing agents

Publications (1)

Publication Number Publication Date
ES2795021T3 true ES2795021T3 (es) 2020-11-20

Family

ID=43586743

Family Applications (1)

Application Number Title Priority Date Filing Date
ES10808524T Active ES2795021T3 (es) 2009-08-11 2010-08-02 Espumas y composiciones espumables que contienen agentes espumantes de olefina halogenada

Country Status (11)

Country Link
US (2) US9695267B2 (cg-RX-API-DMAC7.html)
EP (1) EP2464684B1 (cg-RX-API-DMAC7.html)
JP (4) JP6004939B2 (cg-RX-API-DMAC7.html)
CN (2) CN102575045B (cg-RX-API-DMAC7.html)
BR (1) BR112012003038A2 (cg-RX-API-DMAC7.html)
CA (1) CA2770673A1 (cg-RX-API-DMAC7.html)
ES (1) ES2795021T3 (cg-RX-API-DMAC7.html)
IN (1) IN2012DN01280A (cg-RX-API-DMAC7.html)
MX (1) MX2012001820A (cg-RX-API-DMAC7.html)
PL (1) PL2464684T3 (cg-RX-API-DMAC7.html)
WO (1) WO2011019528A2 (cg-RX-API-DMAC7.html)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2773366C (en) * 2009-09-09 2018-03-06 Arkema Inc. Improved polyurethane foaming processes and foam properties using halogenated olefin blowing agent
US20120046372A1 (en) * 2010-08-18 2012-02-23 Honeywell International Inc. Blowing agents, foamable compositions and foams
US20140171527A1 (en) * 2011-02-21 2014-06-19 Honeywell International Inc. Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same
US20120313035A1 (en) * 2011-06-08 2012-12-13 Honeywell International Inc. Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same
US9556303B2 (en) * 2011-02-21 2017-01-31 Honeywell International Inc. Catalysts for polyurethane foam polyol premixes containing halogenated olefin blowing agents
CN103619955A (zh) * 2011-02-21 2014-03-05 霍尼韦尔国际公司 含有卤代烯烃发泡剂的聚氨酯泡沫预混料和由其制得的泡沫
CN103415548B (zh) * 2011-04-15 2017-05-17 阿科玛股份有限公司 包含卤代烯烃发泡剂的聚氨酯多元醇共混物的改善的稳定性
US10335623B2 (en) 2011-05-19 2019-07-02 Arkema Inc. Non-flammable compositions of chloro-trifluoropropene
KR20140053212A (ko) * 2011-07-28 2014-05-07 허니웰 인터내셔널 인코포레이티드 1-클로로-3,3,3-트리플루오로프로펜(1233zd)을 함유하는 폼 및 이로부터 제조된 난연성 물품
PL2739676T5 (pl) * 2011-08-01 2024-11-04 Basf Se Układy sztywnych pianek spieniane za pomocą hfo/wody
US20150322225A1 (en) * 2011-12-09 2015-11-12 Honeywell International Inc. Foams and articles made from foams containing hcfo or hfo blowing agents
CN103509168B (zh) * 2012-06-15 2018-04-27 科思创聚合物(中国)有限公司 微孔聚氨酯的组合物、制备方法及其应用
JP6334523B2 (ja) * 2012-07-19 2018-05-30 ハネウェル・インターナショナル・インコーポレーテッドHoneywell International Inc. 押出ポリスチレンフォーム用の発泡剤、及び押出ポリスチレンフォーム、並びに発泡方法
US9522973B2 (en) * 2012-10-02 2016-12-20 Covestro Llc Polyurethane and polyisocyanurate rigid foams for roofing insulation
US10077330B2 (en) * 2013-03-06 2018-09-18 Honeywell International Inc. Storage stable foamable compositions containing 1,1,1,4,4,4-hexafluoro-2-butene
DK3495407T3 (da) 2013-03-15 2024-03-04 Owens Corning Intellectual Capital Llc Forarbejdsningshjælpemidler til anvendelse til fremstilling af ekstruderede polystyrenskum ved anvendelse af opskumningsmidler med lavt potentiale for global opvarmning
EP3119824B1 (en) 2014-03-20 2021-04-28 Dow Global Technologies LLC Formulated isocyanate-reactive blends including olefin based blowing agent
BR112017000892A2 (pt) * 2014-07-16 2017-11-21 Owens Corning Intellectual Capital Llc auxiliares de processamento sem voc para o uso na fabricação de espumas usando agentes de expansão potenciais de aquecimento global baixo
JP6626674B2 (ja) 2014-10-08 2019-12-25 積水ソフランウイズ株式会社 硬質ポリウレタンフォーム用ポリオール組成物、及び硬質ポリウレタンフォームの製造方法
RU2714081C2 (ru) 2015-03-13 2020-02-11 Басф Се Способ получения изделия из пенополиуретана
ES2932186T3 (es) * 2015-06-18 2023-01-16 Basf Se Procedimiento para la fabricación de espumas rígidas de poliuretano
JP6926660B2 (ja) * 2016-05-17 2021-08-25 東ソー株式会社 ハロアルケン発泡ポリウレタン製造用のアミン触媒組成物
JP6903427B2 (ja) * 2016-12-20 2021-07-14 日清紡ケミカル株式会社 2液型プレミックス組成物、裏込め注入用硬質ポリイソシアヌレートフォーム及び裏込め注入工法
US11649315B2 (en) * 2017-09-14 2023-05-16 Huntsman International Llc Polyurethane insulation foam composition comprising halogenated olefins and a tertiary amine compound
WO2019088035A1 (ja) * 2017-11-01 2019-05-09 Agc株式会社 硬質発泡合成樹脂の製造方法
US20210269579A1 (en) * 2018-06-27 2021-09-02 Basf Se Process for Producing a Rigid polyurethane Foam and use Thereof as an Insulation Material
CN112566955B (zh) * 2018-08-16 2023-04-14 巴斯夫欧洲公司 环境友好驱动的聚氨酯喷涂泡沫体系
KR102867104B1 (ko) * 2018-08-16 2025-09-30 바스프 에스이 폴리이소시아네이트 조성물, 이로부터 수득된 폴리우레탄 폼 및 이의 용도
US11578165B2 (en) 2019-01-21 2023-02-14 Talaco Holdings, LLC Methods of making foams exhibiting desired properties from aromatic polyester polyether polyols derived from polyethylene terephthalates and foams made therefrom
HUE064509T2 (hu) * 2019-12-17 2024-03-28 Basf Se Rugalmas habképzési eljárás hõszigetelt termékek elõállítására
JP7445290B2 (ja) * 2020-01-31 2024-03-07 アップコン株式会社 ビバリウム装飾品
KR102160534B1 (ko) * 2020-02-07 2020-09-28 최규술 준불연 폴리우레탄 폼블록 및 그 제조방법
CA3184900A1 (en) * 2020-06-02 2021-12-09 Huntsman International Llc Use of epoxy compounds as carbon dioxide scavengers in pir comprising foams for superior thermal insulation properties
US11655328B2 (en) 2020-09-02 2023-05-23 Ventrex Systems, LLC Dimensionally stable closed-cell and rigid foams produced with methylal blowing agent
JP7568523B2 (ja) * 2021-01-20 2024-10-16 株式会社ジェイエスピー ポリスチレン系樹脂押出発泡板の製造方法
US11753516B2 (en) 2021-10-08 2023-09-12 Covestro Llc HFO-containing compositions and methods of producing foams
WO2023137148A1 (en) * 2022-01-13 2023-07-20 Honeywell International Inc. Low density thermosetting foams having improved properties

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3277138A (en) 1966-10-04 Method for the chlorination of aromatic isocyanates
US3001973A (en) 1953-05-23 1961-09-26 Bayer Ag Production of cross-linked plastics
BE536296A (cg-RX-API-DMAC7.html) 1954-03-22
IT535373A (cg-RX-API-DMAC7.html) 1954-06-10
US2846458A (en) 1956-05-23 1958-08-05 Dow Corning Organosiloxane ethers
US3454606A (en) 1963-11-14 1969-07-08 Union Carbide Corp Isocyanatophenylsulfonyl isocyanates
US3124605A (en) 1963-12-05 1964-03-10 Biuret polyisocyanates
DE1202785B (de) 1964-07-21 1965-10-14 Scholven Chemie Ag Verfahren zur Herstellung von 1-Isocyanato-3-(isocyanatomethyl)-3, 5, 5-trimethylcyclohexan
US3394164A (en) 1965-10-24 1968-07-23 Upjohn Co Stabilized methylenebis-(phenyl isocyanate) compositions
US3492330A (en) 1965-12-09 1970-01-27 Union Carbide Corp Norbornane diisocyanates
US4147847A (en) 1973-11-14 1979-04-03 Dow Corning Corporation Method of preparing flexible flame retardant polyether based one-shot polyurethane foams and compositions therefore
US4426461A (en) 1982-07-14 1984-01-17 Thermocell Development, Ltd. Modified polyisocyanurate foam and method of preparation
US4868224A (en) 1988-10-21 1989-09-19 Mobay Corporation Process for the production of molded products using internal mold release agents
US5300531A (en) 1992-12-30 1994-04-05 The Dow Chemical Company Plastic skin cladded polyurethanes having improved surface appearance
US5308881A (en) * 1993-10-25 1994-05-03 The Celotex Corporation Surfactant for polyisocyanurate foams made with alternative blowing agents
US5762822A (en) 1994-12-29 1998-06-09 Basf Corporation Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture
KR100188298B1 (ko) * 1995-01-30 1999-06-01 모리시따요오이찌 단열발포체 및 그 제조방법
JP3859339B2 (ja) * 1996-12-26 2006-12-20 三井化学株式会社 ポリイソシアネート組成物及び硬質ポリウレタンフォームの製造方法
JP3804289B2 (ja) 1998-09-22 2006-08-02 ダイキン工業株式会社 1,1,1,3,3−ペンタフルオロプロパン及び/又は1−クロロ−3,3,3−トリフルオロプロペンの製造方法
US6395796B1 (en) 1999-01-05 2002-05-28 Crompton Corporation Process for preparing polyurethane foam
DE10025932A1 (de) * 2000-05-26 2001-12-06 Freudenberg Carl Fa Polyurethan-Formkörper
US7230146B2 (en) 2003-10-27 2007-06-12 Honeywell International Inc. Process for producing fluoropropenes
US7279451B2 (en) 2002-10-25 2007-10-09 Honeywell International Inc. Compositions containing fluorine substituted olefins
US6844475B1 (en) 2003-08-08 2005-01-18 Honeywell International Business Machines Low temperature production of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd)
US9499729B2 (en) * 2006-06-26 2016-11-22 Honeywell International Inc. Compositions and methods containing fluorine substituted olefins
CA2564991C (en) 2004-04-29 2013-03-19 Honeywell International Inc. Processes for synthesis of 1,3,3,3-tetrafluoropropene and 2,3,3,3-tetrafluoropropene
WO2006017433A2 (en) * 2004-08-04 2006-02-16 Foam Supplies, Inc. Reactivity drift and catalyst degradation in polyurethane foam
JP4440749B2 (ja) * 2004-11-02 2010-03-24 ローム株式会社 画像読み取り装置
US20060173128A1 (en) * 2004-11-15 2006-08-03 Huntsman International Llc Pultrusion systems and process
TWI708756B (zh) * 2005-06-24 2020-11-01 美商哈尼威爾國際公司 含有經氟取代之烯烴之組合物
TW201336906A (zh) 2005-06-24 2013-09-16 Honeywell Int Inc 含有經氟取代之烯烴之發泡劑及組合物,及發泡方法
CA2855233A1 (en) * 2005-11-01 2007-05-10 E.I. Du Pont De Nemours And Company Blowing agents for forming foam comprising unsaturated fluorocarbons
EP3564349A1 (en) 2005-11-01 2019-11-06 The Chemours Company FC, LLC Solvent compositions comprising unsaturated fluorinated hydrocarbons
PL2129713T3 (pl) * 2007-03-29 2012-10-31 Arkema Inc Kompozycja środka porotwórczego zawierająca chlorofluoroolefinę i fluoroolefinę oraz sposób wytwarzania termoutwardzalnej pianki
ES2607226T3 (es) * 2007-03-29 2017-03-29 Arkema Inc. Espuma de células cerradas y procedimiento
US9453115B2 (en) * 2007-10-12 2016-09-27 Honeywell International Inc. Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents
US9550854B2 (en) * 2007-10-12 2017-01-24 Honeywell International Inc. Amine catalysts for polyurethane foams
US20090099273A1 (en) * 2007-10-12 2009-04-16 Williams David J Non-silicone surfactants for polyurethane or polyisocyanurate foam containing halogenated olefins as blowing agents
US20090124719A1 (en) 2007-11-08 2009-05-14 E. I. Dupont De Nemours And Company Polyurethane foams from polytrimethylene ether glycol
DE102009028061A1 (de) * 2009-07-29 2011-02-10 Evonik Goldschmidt Gmbh Verfahren zur Herstellung von Polyurethanschaum

Also Published As

Publication number Publication date
CN107022103B (zh) 2020-11-27
EP2464684B1 (en) 2020-04-22
CN102575045B (zh) 2016-11-09
US20110039964A1 (en) 2011-02-17
JP2017039942A (ja) 2017-02-23
CN102575045A (zh) 2012-07-11
JP2014205845A (ja) 2014-10-30
IN2012DN01280A (cg-RX-API-DMAC7.html) 2015-05-15
JP6004939B2 (ja) 2016-10-12
US20180016379A1 (en) 2018-01-18
EP2464684A2 (en) 2012-06-20
JP2013501844A (ja) 2013-01-17
CN107022103A (zh) 2017-08-08
MX2012001820A (es) 2012-06-01
EP2464684A4 (en) 2014-05-14
PL2464684T3 (pl) 2020-09-07
WO2011019528A3 (en) 2011-06-09
BR112012003038A2 (pt) 2016-04-19
WO2011019528A2 (en) 2011-02-17
CA2770673A1 (en) 2011-02-17
JP2019131822A (ja) 2019-08-08
US9695267B2 (en) 2017-07-04

Similar Documents

Publication Publication Date Title
ES2795021T3 (es) Espumas y composiciones espumables que contienen agentes espumantes de olefina halogenada
US11746180B2 (en) Catalysts for polyurethane foam polyol premixes containing halogenated olefin blowing agents
US10941237B2 (en) Storage stable foamable compositions containing 1,1,1,4,4,4-hexafluoro-2-butene
ES2746532T3 (es) Premezclas de espuma de poliuretano que contienen agentes de soplado de olefina halogenada y espumas hechas a partir de estos
ES2435593T3 (es) Estabilización de premezclas de poliol con espumas de poliuretano que contienen agentes de soplado olefínicos halogenados
CN103619893B (zh) 用于含有卤代烯烃发泡剂的聚氨酯泡沫多元醇预混合料的催化剂
ES3037628T3 (en) Amine catalysts for polyurethane foams
CN103703042A (zh) 含有卤代烯烃发泡剂的聚氨酯泡沫预混料和由其制得的泡沫
ES2654795T3 (es) Agentes de soplado, pre-mezclas de espumas y espumas que contienen agente de soplado de olefina halogenada y absorbente
ES2994241T3 (en) Polyurethane rigid foam system with enhanced polyol shelf life and stability
HK1166338A (en) Foams and foamable compositions containing halogenated olefin blowing agents
HK1166338B (en) Foams and foamable compositions containing halogenated olefin blowing agents