ES2764198T3 - Pigmentos de efecto - Google Patents
Pigmentos de efecto Download PDFInfo
- Publication number
- ES2764198T3 ES2764198T3 ES15798867T ES15798867T ES2764198T3 ES 2764198 T3 ES2764198 T3 ES 2764198T3 ES 15798867 T ES15798867 T ES 15798867T ES 15798867 T ES15798867 T ES 15798867T ES 2764198 T3 ES2764198 T3 ES 2764198T3
- Authority
- ES
- Spain
- Prior art keywords
- refractive index
- high refractive
- layer
- layers
- diffused
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
- C09C3/063—Coating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
- C09C1/0024—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating high and low refractive indices, wherein the first coating layer on the core surface has the high refractive index
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/01—Crystal-structural characteristics depicted by a TEM-image
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/85—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/65—Chroma (C*)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/66—Hue (H*)
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/102—Interference pigments characterized by the core material the core consisting of glass or silicate material like mica or clays, e.g. kaolin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/20—Interference pigments comprising a layer with a concentration gradient or a gradient of the refractive index
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
- C09C2200/301—Thickness of the core
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/40—Interference pigments comprising an outermost surface coating
- C09C2200/401—Inorganic protective coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/40—Interference pigments comprising an outermost surface coating
- C09C2200/402—Organic protective coating
- C09C2200/403—Low molecular weight materials, e.g. fatty acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Cosmetics (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Compounds Of Iron (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462004007P | 2014-05-28 | 2014-05-28 | |
| US201562137918P | 2015-03-25 | 2015-03-25 | |
| PCT/US2015/031882 WO2015183674A1 (en) | 2014-05-28 | 2015-05-21 | Effect pigments |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2764198T3 true ES2764198T3 (es) | 2020-06-02 |
Family
ID=54699589
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES15798867T Active ES2764198T3 (es) | 2014-05-28 | 2015-05-21 | Pigmentos de efecto |
| ES19181921T Active ES2900620T3 (es) | 2014-05-28 | 2015-05-21 | Pigmentos de efecto |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES19181921T Active ES2900620T3 (es) | 2014-05-28 | 2015-05-21 | Pigmentos de efecto |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9815970B2 (enExample) |
| EP (2) | EP3149089B1 (enExample) |
| JP (1) | JP7020779B2 (enExample) |
| KR (1) | KR102396623B1 (enExample) |
| CN (1) | CN106536640B (enExample) |
| BR (1) | BR112016027743B1 (enExample) |
| ES (2) | ES2764198T3 (enExample) |
| MX (1) | MX379277B (enExample) |
| WO (1) | WO2015183674A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2123721B1 (de) | 2008-04-15 | 2013-11-27 | Eckart GmbH | Perlglanzpigmente auf Basis von feinen und dünnen Substraten |
| ES2733082T3 (es) | 2014-12-19 | 2019-11-27 | Eckart Gmbh | Pigmentos de efecto de color rojo con croma alto y brillo alto, procedimiento para su preparación y uso de los mismos |
| PL3034562T5 (pl) * | 2014-12-19 | 2022-04-19 | Eckart Gmbh | Pigmenty do uzyskiwania efektów absorbujących o wysokim nasyceniu barwy i wysokiej jasności, sposób ich wytwarzania i ich zastosowanie |
| EP3034566B2 (de) | 2014-12-19 | 2022-06-08 | Eckart GmbH | Metalleffektpigmente mit hohem Chroma und hoher Brillanz, Verfahren zu ihrer Herstellung und Verwendung derselben |
| EP3034564B1 (de) * | 2014-12-19 | 2018-02-07 | Eckart GmbH | Effektpigmente mit hoher Transparenz, hohem Chroma und hoher Brillanz, Verfahren zu ihrer Herstellung und Verwendung derselben |
| ES2726181T5 (en) * | 2014-12-19 | 2025-03-05 | Eckart Gmbh | Gold-coloured effect pigments with high chroma and a high brilliance, method for their preparation and their use |
| JP7432364B2 (ja) * | 2017-03-17 | 2024-02-16 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 干渉顔料 |
| CN110914371A (zh) * | 2017-04-04 | 2020-03-24 | 巴斯夫色彩与效果有限公司 | 无机效果颜料 |
| CN110128880A (zh) * | 2019-05-24 | 2019-08-16 | 上海应用技术大学 | 一种宝蓝色陶瓷喷墨打印墨水 |
| CN110283479B (zh) * | 2019-08-02 | 2021-05-25 | 四川赛和新材料科技有限责任公司 | 一种超白复合绢云母及其制备方法 |
| US20230295443A1 (en) | 2020-07-23 | 2023-09-21 | Eckart Gmbh | Solvochromic effect pigments, method of production and use thereof |
| KR102553132B1 (ko) * | 2021-06-08 | 2023-07-10 | (주)스파코 | 진주광택 안료 입자 및 이의 제조 장치 및 제조 방법 |
| CN114276700A (zh) * | 2022-01-06 | 2022-04-05 | 广西七色珠光材料股份有限公司 | 一种无钛金色珠光颜料及其制备方法和用途 |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4373963A (en) | 1981-09-03 | 1983-02-15 | Titan Kogyo K.K. | Lustrous pigment and process for producing same |
| JPS5876461A (ja) | 1981-10-26 | 1983-05-09 | メルク・パテント・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | 透明性着色顔料およびその製造法 |
| DE3528256A1 (de) * | 1985-08-07 | 1987-02-19 | Merck Patent Gmbh | Eisenoxidbeschichtete perlglanzpigmente |
| DE3636076A1 (de) | 1986-10-23 | 1988-04-28 | Merck Patent Gmbh | Plaettchenfoermige eisenoxidpigmente |
| EP0683808A1 (en) * | 1993-02-11 | 1995-11-29 | Corveagh Limited | Colouring pigment and method of manufacture |
| JP3542388B2 (ja) | 1994-10-11 | 2004-07-14 | 株式会社資生堂 | 低次酸化チタン含有顔料及びその製造方法 |
| US5584925A (en) * | 1995-06-26 | 1996-12-17 | Thiele Kaolin Company | Chemically aggregated kaolin clay pigment and process for making the same by phosphate bonding |
| DE19618562A1 (de) | 1996-05-09 | 1997-11-13 | Merck Patent Gmbh | Plättchenförmiges Titandioxidreduktionspigment |
| DE19618569A1 (de) | 1996-05-09 | 1997-11-13 | Merck Patent Gmbh | Mehrschichtige Interferenzpigmente |
| US6132873A (en) | 1996-09-21 | 2000-10-17 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Multilayered interference pigments |
| DE19746067A1 (de) * | 1997-10-17 | 1999-04-22 | Merck Patent Gmbh | Interferenzpigmente |
| DE19817286A1 (de) * | 1998-04-18 | 1999-10-21 | Merck Patent Gmbh | Mehrschichtiges Perlglanzpigment auf Basis eines opaken Substrates |
| DE19951869A1 (de) * | 1999-10-28 | 2001-05-03 | Merck Patent Gmbh | Farbstarke Interferenzpigmente |
| US7604862B2 (en) * | 2001-07-12 | 2009-10-20 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Multilayer pigments based on glass flakes |
| CN1281690C (zh) | 2001-08-10 | 2006-10-25 | 日本光研工业株式会社 | 高虹彩色氧化钛组合物及其制法 |
| DE10151844A1 (de) | 2001-10-24 | 2003-05-08 | Merck Patent Gmbh | Farbige Interferenzpigmente |
| DE10204336A1 (de) * | 2002-02-01 | 2003-08-14 | Merck Patent Gmbh | Verwendung von Mehrschichtpigmenten im Lebensmittel- und Pharmabereich |
| EP1375601A1 (de) * | 2002-06-28 | 2004-01-02 | MERCK PATENT GmbH | Fünfschichtpigmente |
| US7993444B2 (en) * | 2003-01-17 | 2011-08-09 | Basf Catalysts Llc | Multi-layer effect pigment |
| DE10346167A1 (de) * | 2003-10-01 | 2005-05-25 | Merck Patent Gmbh | Glänzende schwarze Interferenzpigmente |
| CN1323117C (zh) * | 2004-04-19 | 2007-06-27 | 付建生 | 随角异色颜料及其生产方法 |
| CN1266229C (zh) * | 2004-08-10 | 2006-07-26 | 汕头市龙华珠光颜料有限公司 | 一种随角异色的多层变色颜料及其生产方法 |
| JP2006160683A (ja) * | 2004-12-08 | 2006-06-22 | Kao Corp | 水系美爪料 |
| US7842130B2 (en) * | 2005-08-22 | 2010-11-30 | Basf Corporation | Complex inorganic effect materials |
| US20070048239A1 (en) * | 2005-08-26 | 2007-03-01 | Engelhard Corporation | Cosmetic and Personal Care Formulations with Goniochromatic Non-Quarter Wave Multi-Quadrant Multi-Layer Effect Materials |
| WO2008048922A2 (en) * | 2006-10-18 | 2008-04-24 | Basf Corporation | Multiple layered pigments exhibiting color travel |
| KR20100066460A (ko) * | 2007-07-31 | 2010-06-17 | 바스프 에스이 | 광학적 가변성 효과 안료 |
| CN100562544C (zh) * | 2007-10-16 | 2009-11-25 | 汕头市龙华珠光颜料有限公司 | 一种具有强烈金属质感的金色珠光颜料及其生产方法 |
| CN101962492B (zh) * | 2009-07-24 | 2014-01-08 | 林文广 | 多层涂覆的随角异色干涉色珠光颜料 |
| DE102009037935A1 (de) * | 2009-08-19 | 2011-02-24 | Eckart Gmbh | Hochglänzende Mehrschichtperlglanzpigmente mit silberner Interferenzfarbe und enger Größenverteilung und Verfahren zu deren Herstellung |
| DE102009051171A1 (de) | 2009-10-29 | 2011-05-05 | Merck Patent Gmbh | Pigmente |
| EP2508571A4 (en) | 2010-02-24 | 2016-06-15 | Shantou Longhua Pearl Lustre Pigments Co Ltd | NEW FLIP FLOP INTERFERENCE PIGMENTS |
| EP2607432A1 (de) * | 2011-12-21 | 2013-06-26 | Merck Patent GmbH | Effektpigmente basierend auf Substraten die einen Kreisformfaktor von 1,2-2 aufweisen |
| KR101399954B1 (ko) * | 2012-09-10 | 2014-05-29 | 씨큐브 주식회사 | 높은 색강도를 갖는 간섭안료 및 그 제조 방법 |
-
2015
- 2015-05-21 EP EP15798867.6A patent/EP3149089B1/en active Active
- 2015-05-21 MX MX2016015556A patent/MX379277B/es unknown
- 2015-05-21 ES ES15798867T patent/ES2764198T3/es active Active
- 2015-05-21 WO PCT/US2015/031882 patent/WO2015183674A1/en not_active Ceased
- 2015-05-21 CN CN201580041051.1A patent/CN106536640B/zh active Active
- 2015-05-21 EP EP19181921.8A patent/EP3578610B1/en active Active
- 2015-05-21 ES ES19181921T patent/ES2900620T3/es active Active
- 2015-05-21 US US14/718,501 patent/US9815970B2/en active Active
- 2015-05-21 JP JP2016570047A patent/JP7020779B2/ja active Active
- 2015-05-21 BR BR112016027743-0A patent/BR112016027743B1/pt active IP Right Grant
- 2015-05-21 KR KR1020167034830A patent/KR102396623B1/ko active Active
Also Published As
| Publication number | Publication date |
|---|---|
| BR112016027743A8 (pt) | 2021-05-04 |
| US9815970B2 (en) | 2017-11-14 |
| EP3578610A1 (en) | 2019-12-11 |
| CN106536640A (zh) | 2017-03-22 |
| EP3149089A1 (en) | 2017-04-05 |
| KR102396623B1 (ko) | 2022-05-12 |
| JP2017524752A (ja) | 2017-08-31 |
| EP3149089B1 (en) | 2019-10-02 |
| EP3578610B1 (en) | 2021-09-01 |
| JP7020779B2 (ja) | 2022-02-16 |
| MX2016015556A (es) | 2017-02-27 |
| MX379277B (es) | 2025-03-10 |
| EP3149089A4 (en) | 2017-12-27 |
| CN106536640B (zh) | 2019-05-21 |
| BR112016027743B1 (pt) | 2022-04-12 |
| WO2015183674A1 (en) | 2015-12-03 |
| BR112016027743A2 (pt) | 2017-08-15 |
| KR20170012313A (ko) | 2017-02-02 |
| ES2900620T3 (es) | 2022-03-17 |
| US20150344677A1 (en) | 2015-12-03 |
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