ES2742131T3 - Procedimiento de debilitamiento de tintes en textiles - Google Patents
Procedimiento de debilitamiento de tintes en textiles Download PDFInfo
- Publication number
- ES2742131T3 ES2742131T3 ES17700613T ES17700613T ES2742131T3 ES 2742131 T3 ES2742131 T3 ES 2742131T3 ES 17700613 T ES17700613 T ES 17700613T ES 17700613 T ES17700613 T ES 17700613T ES 2742131 T3 ES2742131 T3 ES 2742131T3
- Authority
- ES
- Spain
- Prior art keywords
- organic acid
- salt
- weak organic
- acid
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 30
- 230000003313 weakening effect Effects 0.000 title claims abstract description 15
- 239000000975 dye Substances 0.000 title description 48
- 239000004753 textile Substances 0.000 title description 6
- 239000004744 fabric Substances 0.000 claims abstract description 35
- 238000004043 dyeing Methods 0.000 claims abstract description 28
- 150000007524 organic acids Chemical class 0.000 claims abstract description 28
- 229920000728 polyester Polymers 0.000 claims abstract description 23
- 150000003839 salts Chemical class 0.000 claims abstract description 20
- 230000009467 reduction Effects 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 239000002253 acid Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000011668 ascorbic acid Substances 0.000 claims description 9
- 229960005070 ascorbic acid Drugs 0.000 claims description 9
- 235000010323 ascorbic acid Nutrition 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- -1 alkali metal salt Chemical class 0.000 claims description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 230000003028 elevating effect Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 239000000126 substance Substances 0.000 description 7
- 239000002270 dispersing agent Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- 229920001410 Microfiber Polymers 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000003658 microfiber Substances 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 230000002085 persistent effect Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000007848 Bronsted acid Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical class [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
- Cleaning By Liquid Or Steam (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB1600098.6A GB201600098D0 (en) | 2016-01-04 | 2016-01-04 | Ascorbic acid dye clearing process patent |
| PCT/EP2017/050163 WO2017118671A1 (en) | 2016-01-04 | 2017-01-04 | Method of dye clearing textiles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2742131T3 true ES2742131T3 (es) | 2020-02-13 |
Family
ID=55406678
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES17700613T Active ES2742131T3 (es) | 2016-01-04 | 2017-01-04 | Procedimiento de debilitamiento de tintes en textiles |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US10533279B2 (enExample) |
| EP (1) | EP3390711B1 (enExample) |
| JP (1) | JP6773805B2 (enExample) |
| KR (1) | KR20180098595A (enExample) |
| CN (1) | CN108779602B (enExample) |
| AR (1) | AR107286A1 (enExample) |
| BR (1) | BR112018013726B1 (enExample) |
| CA (1) | CA3010538C (enExample) |
| CL (1) | CL2018001831A1 (enExample) |
| CO (1) | CO2018006994A2 (enExample) |
| ES (1) | ES2742131T3 (enExample) |
| GB (1) | GB201600098D0 (enExample) |
| PL (1) | PL3390711T3 (enExample) |
| PT (1) | PT3390711T (enExample) |
| TW (1) | TWI738699B (enExample) |
| WO (1) | WO2017118671A1 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102365561B1 (ko) * | 2021-08-03 | 2022-02-23 | (주)두원부라더스아이앤씨 | 비정형 디자인을 형성하는 친환경 에코 웨이브 염색 방법 및 이를 통해 생산된 에코 웨이브 원단 |
| TWI781761B (zh) * | 2021-09-13 | 2022-10-21 | 南亞塑膠工業股份有限公司 | 聚酯織物的脫色方法 |
| TWI800920B (zh) * | 2021-09-13 | 2023-05-01 | 南亞塑膠工業股份有限公司 | 聚酯織物的回收方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3619111A (en) * | 1970-02-17 | 1971-11-09 | Du Pont | Desizing, scouring and bleaching cotton/polyester fabrics containing portions dyed with sensitive dyestuffs |
| US4003880A (en) * | 1975-05-19 | 1977-01-18 | Monsanto Company | Fabric dye stripping, separation and recovery of polyester |
| CH619587B (de) * | 1977-02-04 | Sandoz Ag | Verfahren zum faerben oder bedrucken von polyester/cellulosefaser mischungen. | |
| US4137393A (en) * | 1977-04-07 | 1979-01-30 | Monsanto Company | Polyester polymer recovery from dyed polyester fibers |
| DE2739092A1 (de) | 1977-08-30 | 1979-03-08 | Brueckner Apparatebau Gmbh | Verfahren und vorrichtung zum nachwaschen von textilmaterial |
| JPS5645995A (en) | 1979-09-21 | 1981-04-25 | Kao Corp | Soaping agent |
| JPS5915584A (ja) * | 1982-07-13 | 1984-01-26 | 三井東圧化学株式会社 | 繊維の後処理方法 |
| JPS62282085A (ja) * | 1986-05-28 | 1987-12-07 | 日本化薬株式会社 | 染色物の後処理法 |
| JPS63243388A (ja) * | 1987-03-30 | 1988-10-11 | 住友化学工業株式会社 | ポリエステル起毛繊維材料の染色法 |
| JPH0291285A (ja) | 1988-09-21 | 1990-03-30 | Sanyo Chem Ind Ltd | ソーピング剤および処理法 |
| JPH05287687A (ja) * | 1992-04-09 | 1993-11-02 | Toray Ind Inc | ポリエステル系繊維の処理方法 |
| DE4329762A1 (de) * | 1993-09-03 | 1995-03-09 | Cassella Ag | Verfahren zum Färben von Polyester und polyesterhaltigen Textilmaterialien |
| US5855623A (en) | 1996-09-20 | 1999-01-05 | Intera Technologies, Inc. | Process for improving polyamide, acrylic, aramid, cellulosic and polyester properties, and modified polymers produced thereby |
| CN101130717B (zh) * | 2006-08-21 | 2010-05-12 | 上海德桑精细化工有限公司 | 涤纶及其混纺染物净洗剂 |
| MX2011001326A (es) * | 2008-08-11 | 2011-03-21 | Basf Se | Metodo para tratamiento posterior suave de textiles teñidos. |
| CN102199887B (zh) * | 2010-09-28 | 2012-07-11 | 刘静 | 一种织物花型的转移方法 |
| CN104562790A (zh) * | 2013-10-18 | 2015-04-29 | 青岛三秀新科技复合面料有限公司 | 涤纶毛毯分散染料印花工艺 |
| CN104562776A (zh) * | 2015-01-12 | 2015-04-29 | 张家港市德宝化工有限公司 | 一种低聚物去除剂用于聚酯纤维类材料染色的方法 |
| CN104878618B (zh) * | 2015-05-21 | 2017-03-22 | 互太(番禺)纺织印染有限公司 | 一种超细涤纶织物的染色方法 |
| CN106120374A (zh) * | 2016-06-23 | 2016-11-16 | 浙江恒生印染有限公司 | 一种多工艺组合印花的制备工艺 |
-
2016
- 2016-01-04 GB GBGB1600098.6A patent/GB201600098D0/en not_active Ceased
- 2016-12-28 TW TW105143602A patent/TWI738699B/zh not_active IP Right Cessation
-
2017
- 2017-01-03 AR ARP170100009A patent/AR107286A1/es active IP Right Grant
- 2017-01-04 PL PL17700613T patent/PL3390711T3/pl unknown
- 2017-01-04 EP EP17700613.7A patent/EP3390711B1/en active Active
- 2017-01-04 WO PCT/EP2017/050163 patent/WO2017118671A1/en not_active Ceased
- 2017-01-04 JP JP2018553315A patent/JP6773805B2/ja not_active Expired - Fee Related
- 2017-01-04 CN CN201780014202.3A patent/CN108779602B/zh active Active
- 2017-01-04 KR KR1020187021098A patent/KR20180098595A/ko not_active Abandoned
- 2017-01-04 CA CA3010538A patent/CA3010538C/en active Active
- 2017-01-04 PT PT17700613T patent/PT3390711T/pt unknown
- 2017-01-04 US US16/068,126 patent/US10533279B2/en active Active
- 2017-01-04 ES ES17700613T patent/ES2742131T3/es active Active
- 2017-01-04 BR BR112018013726-0A patent/BR112018013726B1/pt not_active IP Right Cessation
-
2018
- 2018-07-04 CL CL2018001831A patent/CL2018001831A1/es unknown
- 2018-07-04 CO CONC2018/0006994A patent/CO2018006994A2/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2019506545A (ja) | 2019-03-07 |
| GB201600098D0 (en) | 2016-02-17 |
| WO2017118671A1 (en) | 2017-07-13 |
| CA3010538A1 (en) | 2017-07-13 |
| CO2018006994A2 (es) | 2018-07-19 |
| KR20180098595A (ko) | 2018-09-04 |
| BR112018013726A2 (en) | 2018-12-11 |
| CL2018001831A1 (es) | 2018-09-07 |
| US10533279B2 (en) | 2020-01-14 |
| CN108779602B (zh) | 2021-06-11 |
| AR107286A1 (es) | 2018-04-18 |
| JP6773805B2 (ja) | 2020-10-21 |
| TWI738699B (zh) | 2021-09-11 |
| BR112018013726B1 (pt) | 2022-07-19 |
| EP3390711B1 (en) | 2019-05-15 |
| EP3390711A1 (en) | 2018-10-24 |
| US20190024305A1 (en) | 2019-01-24 |
| TW201728804A (zh) | 2017-08-16 |
| CN108779602A (zh) | 2018-11-09 |
| PL3390711T3 (pl) | 2019-11-29 |
| PT3390711T (pt) | 2019-09-03 |
| CA3010538C (en) | 2022-05-10 |
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