ES2685439T3 - Proceso para preparar una espuma de poliuretano - Google Patents
Proceso para preparar una espuma de poliuretano Download PDFInfo
- Publication number
- ES2685439T3 ES2685439T3 ES06739138.3T ES06739138T ES2685439T3 ES 2685439 T3 ES2685439 T3 ES 2685439T3 ES 06739138 T ES06739138 T ES 06739138T ES 2685439 T3 ES2685439 T3 ES 2685439T3
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- ES
- Spain
- Prior art keywords
- process according
- foam
- polyisocyanate
- weight
- water
- Prior art date
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- 229920005830 Polyurethane Foam Polymers 0.000 title claims abstract description 16
- 239000011496 polyurethane foam Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims description 33
- 230000008569 process Effects 0.000 title claims description 22
- 239000000203 mixture Substances 0.000 claims abstract description 60
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 32
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000011541 reaction mixture Substances 0.000 claims abstract description 19
- 239000000010 aprotic solvent Substances 0.000 claims abstract description 18
- 229920005862 polyol Polymers 0.000 claims abstract description 16
- 150000003077 polyols Chemical class 0.000 claims abstract description 16
- 239000003054 catalyst Substances 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 10
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 150000007524 organic acids Chemical class 0.000 claims abstract description 9
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims abstract description 7
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 3
- 229920005906 polyester polyol Polymers 0.000 claims abstract description 3
- 229920000570 polyether Polymers 0.000 claims abstract description 3
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims abstract description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims abstract 3
- 239000006260 foam Substances 0.000 claims description 75
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethyl sulfoxide Natural products CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 22
- 238000007664 blowing Methods 0.000 claims description 10
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Chemical class CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 9
- 239000004604 Blowing Agent Substances 0.000 claims description 7
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical group C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- MCDJZKPTBCWNSJ-UHFFFAOYSA-N 2-methyl-1-(2-methylpropylsulfinyl)propane Chemical compound CC(C)CS(=O)CC(C)C MCDJZKPTBCWNSJ-UHFFFAOYSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- CCAFPWNGIUBUSD-UHFFFAOYSA-N diethyl sulfoxide Chemical compound CCS(=O)CC CCAFPWNGIUBUSD-UHFFFAOYSA-N 0.000 claims description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 claims 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims 1
- NYYLZXREFNYPKB-UHFFFAOYSA-N 1-[ethoxy(methyl)phosphoryl]oxyethane Chemical compound CCOP(C)(=O)OCC NYYLZXREFNYPKB-UHFFFAOYSA-N 0.000 claims 1
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 claims 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 claims 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 claims 1
- IAZDPXIOMUYVGZ-WFGJKAKNSA-N Dimethyl sulfoxide Chemical group [2H]C([2H])([2H])S(=O)C([2H])([2H])[2H] IAZDPXIOMUYVGZ-WFGJKAKNSA-N 0.000 claims 1
- 239000001273 butane Chemical class 0.000 claims 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 claims 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 claims 1
- WOAFDHWYKSOANX-UHFFFAOYSA-N diisopropyl methylphosphonate Chemical compound CC(C)OP(C)(=O)OC(C)C WOAFDHWYKSOANX-UHFFFAOYSA-N 0.000 claims 1
- VONWDASPFIQPDY-UHFFFAOYSA-N dimethyl methylphosphonate Chemical group COP(C)(=O)OC VONWDASPFIQPDY-UHFFFAOYSA-N 0.000 claims 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
- 229920002635 polyurethane Polymers 0.000 abstract description 16
- 239000004814 polyurethane Substances 0.000 abstract description 16
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 238000005187 foaming Methods 0.000 abstract 1
- -1 O-dimethyl Inorganic materials 0.000 description 18
- 239000002904 solvent Substances 0.000 description 16
- 239000011495 polyisocyanurate Substances 0.000 description 15
- 229920000582 polyisocyanurate Polymers 0.000 description 15
- 229920001296 polysiloxane Polymers 0.000 description 13
- 229910000831 Steel Inorganic materials 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000010959 steel Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 238000001723 curing Methods 0.000 description 5
- 239000003063 flame retardant Substances 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 229920000877 Melamine resin Polymers 0.000 description 4
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000003623 enhancer Substances 0.000 description 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
- 239000000123 paper Substances 0.000 description 4
- 229920006389 polyphenyl polymer Polymers 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 230000037373 wrinkle formation Effects 0.000 description 4
- HHDUMDVQUCBCEY-UHFFFAOYSA-N 4-[10,15,20-tris(4-carboxyphenyl)-21,23-dihydroporphyrin-5-yl]benzoic acid Chemical compound OC(=O)c1ccc(cc1)-c1c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc([nH]2)c(-c2ccc(cc2)C(O)=O)c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc1[nH]2 HHDUMDVQUCBCEY-UHFFFAOYSA-N 0.000 description 3
- 239000004114 Ammonium polyphosphate Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 3
- 229920001276 ammonium polyphosphate Polymers 0.000 description 3
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- PGYPOBZJRVSMDS-UHFFFAOYSA-N loperamide hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(C=1C=CC=CC=1)(C(=O)N(C)C)CCN(CC1)CCC1(O)C1=CC=C(Cl)C=C1 PGYPOBZJRVSMDS-UHFFFAOYSA-N 0.000 description 3
- 239000012766 organic filler Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- GTRSAMFYSUBAGN-UHFFFAOYSA-N tris(2-chloropropyl) phosphate Chemical compound CC(Cl)COP(=O)(OCC(C)Cl)OCC(C)Cl GTRSAMFYSUBAGN-UHFFFAOYSA-N 0.000 description 3
- ZIKIUDJDOOCMAN-UHFFFAOYSA-N 1,3-dioxolan-2-one 1-methylpyrrolidin-2-one Chemical compound C1(OCCO1)=O.CN1C(CCC1)=O ZIKIUDJDOOCMAN-UHFFFAOYSA-N 0.000 description 2
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 2
- UKRMTDMNPNQXHN-UHFFFAOYSA-N 4-methyl-1,3-dioxolan-2-one Chemical compound CC1COC(=O)O1.CC1COC(=O)O1 UKRMTDMNPNQXHN-UHFFFAOYSA-N 0.000 description 2
- ARSRBNBHOADGJU-UHFFFAOYSA-N 7,12-dimethyltetraphene Chemical compound C1=CC2=CC=CC=C2C2=C1C(C)=C(C=CC=C1)C1=C2C ARSRBNBHOADGJU-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VFZRZRDOXPRTSC-UHFFFAOYSA-N DMBA Natural products COC1=CC(OC)=CC(C=O)=C1 VFZRZRDOXPRTSC-UHFFFAOYSA-N 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 2
- 229920006335 epoxy glue Polymers 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- ZUFQCVZBBNZMKD-UHFFFAOYSA-M potassium 2-ethylhexanoate Chemical compound [K+].CCCCC(CC)C([O-])=O ZUFQCVZBBNZMKD-UHFFFAOYSA-M 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000001029 thermal curing Methods 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 1
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- VZDIRINETBAVAV-UHFFFAOYSA-N 2,4-diisocyanato-1-methylcyclohexane Chemical compound CC1CCC(N=C=O)CC1N=C=O VZDIRINETBAVAV-UHFFFAOYSA-N 0.000 description 1
- PAGNLMNHTONPDF-UHFFFAOYSA-N 2-chloroethoxy(methyl)phosphinic acid Chemical class CP(O)(=O)OCCCl PAGNLMNHTONPDF-UHFFFAOYSA-N 0.000 description 1
- KKZUMAMOMRDVKA-UHFFFAOYSA-N 2-chloropropane Chemical group [CH2]C(C)Cl KKZUMAMOMRDVKA-UHFFFAOYSA-N 0.000 description 1
- QZWKEPYTBWZJJA-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine-4,4'-diisocyanate Chemical compound C1=C(N=C=O)C(OC)=CC(C=2C=C(OC)C(N=C=O)=CC=2)=C1 QZWKEPYTBWZJJA-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
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- 229910001335 Galvanized steel Inorganic materials 0.000 description 1
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- 206010061218 Inflammation Diseases 0.000 description 1
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- 229910019142 PO4 Inorganic materials 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
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- 229920000265 Polyparaphenylene Polymers 0.000 description 1
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- WOURXYYHORRGQO-UHFFFAOYSA-N Tri(3-chloropropyl) phosphate Chemical compound ClCCCOP(=O)(OCCCCl)OCCCCl WOURXYYHORRGQO-UHFFFAOYSA-N 0.000 description 1
- PQYJRMFWJJONBO-UHFFFAOYSA-N Tris(2,3-dibromopropyl) phosphate Chemical compound BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr PQYJRMFWJJONBO-UHFFFAOYSA-N 0.000 description 1
- 239000013036 UV Light Stabilizer Substances 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
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- 229910052612 amphibole Inorganic materials 0.000 description 1
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- 229910000413 arsenic oxide Inorganic materials 0.000 description 1
- 229960002594 arsenic trioxide Drugs 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
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- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 1
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
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- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
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- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
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- 238000004132 cross linking Methods 0.000 description 1
- 150000007973 cyanuric acids Chemical class 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- WMWXXXSCZVGQAR-UHFFFAOYSA-N dialuminum;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3] WMWXXXSCZVGQAR-UHFFFAOYSA-N 0.000 description 1
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
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- 239000011521 glass Substances 0.000 description 1
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- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000005677 organic carbonates Chemical class 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
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- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000003880 polar aprotic solvent Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
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- 235000011056 potassium acetate Nutrition 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
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- 238000010561 standard procedure Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- CWBIFDGMOSWLRQ-UHFFFAOYSA-N trimagnesium;hydroxy(trioxido)silane;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].O[Si]([O-])([O-])[O-].O[Si]([O-])([O-])[O-] CWBIFDGMOSWLRQ-UHFFFAOYSA-N 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- JLEXUIVKURIPFI-UHFFFAOYSA-N tris phosphate Chemical compound OP(O)(O)=O.OCC(N)(CO)CO JLEXUIVKURIPFI-UHFFFAOYSA-N 0.000 description 1
- KVMPUXDNESXNOH-UHFFFAOYSA-N tris(1-chloropropan-2-yl) phosphate Chemical compound ClCC(C)OP(=O)(OC(C)CCl)OC(C)CCl KVMPUXDNESXNOH-UHFFFAOYSA-N 0.000 description 1
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
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- 239000002023 wood Substances 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0847—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of solvents for the polymers
- C08G18/0852—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of solvents for the polymers the solvents being organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/487—Polyethers containing cyclic groups
- C08G18/4883—Polyethers containing cyclic groups containing cyclic groups having at least one oxygen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US91945 | 2005-03-28 | ||
| US11/091,945 US20060217451A1 (en) | 2005-03-28 | 2005-03-28 | Polyurethane or polyisocyanurate foam composition |
| PCT/US2006/010232 WO2006104767A1 (en) | 2005-03-28 | 2006-03-20 | Polyurethane or polyisocyanurate foam composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2685439T3 true ES2685439T3 (es) | 2018-10-09 |
Family
ID=36636937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES06739138.3T Active ES2685439T3 (es) | 2005-03-28 | 2006-03-20 | Proceso para preparar una espuma de poliuretano |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20060217451A1 (enExample) |
| EP (1) | EP1871827B1 (enExample) |
| JP (1) | JP4904340B2 (enExample) |
| KR (1) | KR101310288B1 (enExample) |
| CN (1) | CN101180352B (enExample) |
| AR (1) | AR056287A1 (enExample) |
| BR (1) | BRPI0609624A2 (enExample) |
| CA (1) | CA2602443C (enExample) |
| ES (1) | ES2685439T3 (enExample) |
| MX (1) | MX2007011950A (enExample) |
| TW (1) | TW200700448A (enExample) |
| WO (1) | WO2006104767A1 (enExample) |
| ZA (1) | ZA200708205B (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090053490A1 (en) * | 2006-02-23 | 2009-02-26 | Clausi Robert N | Highly Filled Composite Materials |
| US8476329B2 (en) | 2009-06-11 | 2013-07-02 | Basf Se | Bioresin composition for use in forming a rigid polyurethane foam article |
| EP2591031B1 (en) * | 2010-07-09 | 2015-06-17 | Air Products and Chemicals, Inc. | Process for producing flexible polyurethane foam |
| CN102558594A (zh) * | 2010-12-16 | 2012-07-11 | 员和工业股份有限公司 | 聚氨酯泡棉或泡沫的物理改性处理方法 |
| US9145466B2 (en) * | 2011-07-07 | 2015-09-29 | Air Products And Chemicals, Inc. | Process for producing flexible polyurethane foam using natural oil polyols |
| RU2620414C2 (ru) | 2011-12-29 | 2017-05-25 | Фаэрстоун Билдинг Продактс Ко., Ллк | Кровельные мембраны, содержащие терморасширяющийся графит в качестве антипирена |
| CN104245773A (zh) * | 2012-04-26 | 2014-12-24 | 迈图高新材料日本合同公司 | 聚氨酯发泡组合物和软质聚氨酯泡沫的制造方法 |
| EP2842977A4 (en) | 2012-04-26 | 2015-10-21 | Momentive Performance Mat Jp | POLYURETHANE FOAM COMPOSITION, AND PROCESS FOR PRODUCING SOFT POLYURETHANE FOAM |
| US9441140B2 (en) | 2012-07-12 | 2016-09-13 | Firestone Building Products Co., LLC | Asphaltic sheet materials including expandable graphite |
| US10508193B2 (en) | 2012-11-07 | 2019-12-17 | Firestone Building Products Co., LLC | Pressure-sensitive adhesives including expandable graphite |
| US8968853B2 (en) | 2012-11-07 | 2015-03-03 | Firestone Building Products Company, Llc | Pressure-sensitive adhesives including expandable graphite |
| US9045904B2 (en) | 2012-11-16 | 2015-06-02 | Firestone Building Products Co., LLC | Thermoplastic membranes containing expandable graphite |
| TW201439287A (zh) * | 2013-01-20 | 2014-10-16 | Sekisui Chemical Co Ltd | 阻燃性胺甲酸乙酯樹脂組成物 |
| US9523203B2 (en) | 2013-01-23 | 2016-12-20 | Firestone Building Products Co., LLC | Fire-resistant roof system and membrane composite |
| US20140205789A1 (en) | 2013-01-23 | 2014-07-24 | Firestone Building Products Co., LLC | Coated fabrics including expandable graphite |
| US10017943B1 (en) | 2013-02-14 | 2018-07-10 | Firestone Building Products Co., LLC | Liquid coatings including expandable graphite |
| US10415249B2 (en) | 2014-07-03 | 2019-09-17 | Firestone Building Products Co., LLC | EPDM roofing membranes with expandable graphite as flame retardant |
| WO2016017797A1 (ja) * | 2014-08-01 | 2016-02-04 | 積水化学工業株式会社 | 難燃性ポリウレタン樹脂組成物 |
| CN106715589B (zh) * | 2014-09-26 | 2021-05-11 | 积水化学工业株式会社 | 阻燃性聚氨酯树脂组合物 |
| US20220064427A1 (en) * | 2020-08-28 | 2022-03-03 | Lawrence Livermore National Security, Llc | Actinic and thermal cure fluoropolymers with controlled porosity |
| EP4600285A1 (en) * | 2024-02-09 | 2025-08-13 | Henkel AG & Co. KGaA | Foamable polyurethane composition comprising a nitrile |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3210300A (en) * | 1961-10-23 | 1965-10-05 | Du Pont | Preparation of polyurethane foams having an open cell, skeletal structure |
| GB1190370A (en) * | 1966-10-22 | 1970-05-06 | Scholten Res N V | Improvements in or relating to Cellular Polyurethanes |
| US3625872A (en) * | 1967-06-15 | 1971-12-07 | Nisshin Spinning | Flame-resistive polyurethane foam composition |
| US3745133A (en) * | 1968-02-05 | 1973-07-10 | Upjohn Co | Cellular isocyanurate containing polymers |
| GB1290470A (enExample) * | 1968-10-04 | 1972-09-27 | ||
| US3849349A (en) * | 1971-05-12 | 1974-11-19 | K Frisch | Polyisocyanurate foam and process for producing the same |
| BE792028A (fr) * | 1971-12-13 | 1973-05-29 | Basf Wyandotte Corp | Catalyseurs a base d'hexahydrotriazine |
| US3959191A (en) * | 1973-01-11 | 1976-05-25 | W. R. Grace & Co. | Novel hydrophobic polyurethane foams |
| US3940517A (en) * | 1973-01-11 | 1976-02-24 | The Celotex Corporation | Polyisocyanurate foam, catalyst composition and process for producing such |
| US3903018A (en) * | 1974-01-30 | 1975-09-02 | Upjohn Co | Novel cocatalyst system for trimerizing polyisocyanates |
| US3899443A (en) * | 1974-01-30 | 1975-08-12 | Upjohn Co | Novel cocatalyst system for trimerizing polyisocyanates |
| US3896052A (en) * | 1974-01-30 | 1975-07-22 | Upjohn Co | Cocatalyst system for trimerizing polyisocyanates |
| GB1470066A (en) * | 1974-10-08 | 1977-04-14 | Ici Ltd | Laminates |
| GB1477658A (en) * | 1974-10-08 | 1977-06-22 | Ici Ltd | Laminates |
| US4033908A (en) * | 1975-08-25 | 1977-07-05 | General Latex And Chemical Corporation | Polyisocyanurate compositions and foams of improved friability and process of preparing same |
| US4071482A (en) * | 1976-10-27 | 1978-01-31 | General Latex And Chemical Corporation | Reduced-friability, highly cross-linked, flame-resistant, polyurethane foams |
| US4335228A (en) * | 1978-02-27 | 1982-06-15 | Air Products And Chemicals, Inc. | Isocyanate blocked imidazoles and imidazolines for epoxy powder coating |
| US4204019A (en) * | 1978-09-11 | 1980-05-20 | Shelter Insulation, Inc. | Polyisocyanurate foam laminate and process |
| US4335218A (en) * | 1980-10-27 | 1982-06-15 | The Upjohn Company | Process for the preparation of a foam-cored laminate having metal facers and rigid polyisocyanurate foam core prepared in the presence of a dipolar aprotic organic solvent |
| US4568702A (en) * | 1985-04-15 | 1986-02-04 | Atlantic Richfield Company | Method for the preparation of semi-rigid polyurethane modified polyurea foam compositions |
| US4621105A (en) * | 1985-08-20 | 1986-11-04 | Atlantic Richfield Company | Preparation of fire retardant flexible polyurethane foams having reduced discoloration and scorch |
| US4711910A (en) * | 1986-10-24 | 1987-12-08 | Atlantic Richfield Company | Preparation of fire retardant flexible polyester based polyurethane foams having reduced discoloration and scorch |
| JPH03172314A (ja) * | 1989-12-01 | 1991-07-25 | Mitsui Toatsu Chem Inc | 水発泡ポリウレタンフォーム製造用レジン原液 |
| CA2039241A1 (en) * | 1990-04-18 | 1991-10-19 | Bi Le-Khac | Superabsorbent foam composition |
| US5157056A (en) * | 1991-07-17 | 1992-10-20 | Arco Chemical Technology, L.P. | High resiliency polyurethane foams with improved static fatigue properties |
| EP0605105B1 (en) * | 1992-12-30 | 1999-05-06 | Imperial Chemical Industries Plc | Process for rigid foams |
| JP2972523B2 (ja) * | 1993-07-22 | 1999-11-08 | 日清紡績株式会社 | ポリイソシアヌレート発泡体の製造法 |
| DE69416209T2 (de) * | 1993-07-22 | 1999-06-10 | Nisshinbo Industries, Inc., Tokio/Tokyo | Verwendung eines halogenfreien Trialkylphosphats in einem Verfahren zur Herstellung von Polyisocyanurat-Schäumen |
| DE4339702A1 (de) * | 1993-11-22 | 1995-05-24 | Bayer Ag | Verfahren zur Herstellung von harten Polyurethanschaumstoffen |
| GB9324510D0 (en) * | 1993-11-30 | 1994-01-19 | Ici Plc | Process for rigid polyurethane foams |
| JP2002012644A (ja) * | 2000-06-30 | 2002-01-15 | Hodogaya Chem Co Ltd | ウレタン変性ポリイソシアヌレート発泡体の製造方法 |
| EP1291371A1 (en) * | 2001-03-16 | 2003-03-12 | Hodogaya Chemical Co., Ltd. | Process for producing urethane-modified polyisocyanurate foam |
| JP4159315B2 (ja) * | 2001-09-20 | 2008-10-01 | セントラル硝子株式会社 | 硬質ポリウレタンフォームまたはポリイソシアヌレートフォームの調製用のプレミックス、該フォームの製造方法および該フォーム |
-
2005
- 2005-03-28 US US11/091,945 patent/US20060217451A1/en not_active Abandoned
-
2006
- 2006-03-20 WO PCT/US2006/010232 patent/WO2006104767A1/en not_active Ceased
- 2006-03-20 MX MX2007011950A patent/MX2007011950A/es unknown
- 2006-03-20 ES ES06739138.3T patent/ES2685439T3/es active Active
- 2006-03-20 BR BRPI0609624-7A patent/BRPI0609624A2/pt not_active IP Right Cessation
- 2006-03-20 KR KR1020077024681A patent/KR101310288B1/ko active Active
- 2006-03-20 CN CN200680010546.9A patent/CN101180352B/zh active Active
- 2006-03-20 CA CA2602443A patent/CA2602443C/en active Active
- 2006-03-20 JP JP2008504146A patent/JP4904340B2/ja active Active
- 2006-03-20 EP EP06739138.3A patent/EP1871827B1/en active Active
- 2006-03-27 AR ARP060101175A patent/AR056287A1/es unknown
- 2006-03-28 TW TW095110789A patent/TW200700448A/zh unknown
-
2007
- 2007-09-26 ZA ZA200708205A patent/ZA200708205B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AR056287A1 (es) | 2007-10-03 |
| CA2602443C (en) | 2015-06-23 |
| ZA200708205B (en) | 2008-11-26 |
| KR20080000618A (ko) | 2008-01-02 |
| CN101180352A (zh) | 2008-05-14 |
| KR101310288B1 (ko) | 2013-09-25 |
| US20060217451A1 (en) | 2006-09-28 |
| CA2602443A1 (en) | 2006-10-05 |
| JP4904340B2 (ja) | 2012-03-28 |
| WO2006104767A1 (en) | 2006-10-05 |
| BRPI0609624A2 (pt) | 2008-12-30 |
| EP1871827B1 (en) | 2018-05-30 |
| CN101180352B (zh) | 2015-05-13 |
| MX2007011950A (es) | 2008-04-07 |
| JP2008534740A (ja) | 2008-08-28 |
| TW200700448A (en) | 2007-01-01 |
| EP1871827A1 (en) | 2008-01-02 |
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