ES2679494T3 - Jarabe (met)acrílico líquido de impregnación de un sustrato fibroso, método de impregnación de un sustrato fibroso, material compuesto obtenido después de polimerización de dicho sustrato impregnado previamente - Google Patents
Jarabe (met)acrílico líquido de impregnación de un sustrato fibroso, método de impregnación de un sustrato fibroso, material compuesto obtenido después de polimerización de dicho sustrato impregnado previamente Download PDFInfo
- Publication number
- ES2679494T3 ES2679494T3 ES14715045.2T ES14715045T ES2679494T3 ES 2679494 T3 ES2679494 T3 ES 2679494T3 ES 14715045 T ES14715045 T ES 14715045T ES 2679494 T3 ES2679494 T3 ES 2679494T3
- Authority
- ES
- Spain
- Prior art keywords
- meth
- weight
- acrylic
- liquid
- syrup
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 173
- 239000006188 syrup Substances 0.000 title claims abstract description 144
- 235000020357 syrup Nutrition 0.000 title claims abstract description 144
- 239000007788 liquid Substances 0.000 title claims abstract description 74
- 239000000758 substrate Substances 0.000 title claims abstract description 74
- 239000002131 composite material Substances 0.000 title claims description 54
- 238000006116 polymerization reaction Methods 0.000 title claims description 38
- 238000000034 method Methods 0.000 title claims description 24
- 239000000178 monomer Substances 0.000 claims abstract description 100
- 239000000835 fiber Substances 0.000 claims abstract description 45
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 41
- 239000002245 particle Substances 0.000 claims abstract description 37
- 230000008961 swelling Effects 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- 238000001033 granulometry Methods 0.000 claims abstract description 3
- 239000011324 bead Substances 0.000 claims description 63
- 239000000203 mixture Substances 0.000 claims description 41
- 238000005470 impregnation Methods 0.000 claims description 29
- 229920001169 thermoplastic Polymers 0.000 claims description 26
- 239000011521 glass Substances 0.000 claims description 25
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 21
- 238000004519 manufacturing process Methods 0.000 claims description 18
- 239000011159 matrix material Substances 0.000 claims description 17
- 239000004416 thermosoftening plastic Substances 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 12
- 238000000465 moulding Methods 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 9
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- 230000002787 reinforcement Effects 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- 238000001802 infusion Methods 0.000 claims description 4
- 238000010276 construction Methods 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 238000012546 transfer Methods 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 description 25
- 206010042674 Swelling Diseases 0.000 description 19
- 229940102838 methylmethacrylate Drugs 0.000 description 14
- 229920001187 thermosetting polymer Polymers 0.000 description 9
- 230000007423 decrease Effects 0.000 description 8
- 230000007547 defect Effects 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- 239000011049 pearl Substances 0.000 description 6
- 239000004634 thermosetting polymer Substances 0.000 description 6
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 5
- 125000005395 methacrylic acid group Chemical group 0.000 description 5
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 5
- 238000001721 transfer moulding Methods 0.000 description 5
- 239000004342 Benzoyl peroxide Substances 0.000 description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 description 4
- 239000002657 fibrous material Substances 0.000 description 4
- 239000002557 mineral fiber Substances 0.000 description 4
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 4
- 239000012466 permeate Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000010411 cooking Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- DFPOZTRSOAQFIK-UHFFFAOYSA-N S,S-dimethyl-beta-propiothetin Chemical compound C[S+](C)CCC([O-])=O DFPOZTRSOAQFIK-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920002522 Wood fibre Polymers 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000012764 mineral filler Substances 0.000 description 2
- GYVGXEWAOAAJEU-UHFFFAOYSA-N n,n,4-trimethylaniline Chemical compound CN(C)C1=CC=C(C)C=C1 GYVGXEWAOAAJEU-UHFFFAOYSA-N 0.000 description 2
- 229920000193 polymethacrylate Polymers 0.000 description 2
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000001542 size-exclusion chromatography Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 229920006305 unsaturated polyester Polymers 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 239000002025 wood fiber Substances 0.000 description 2
- HSOOIVBINKDISP-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(CCC)OC(=O)C(C)=C HSOOIVBINKDISP-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- 244000198134 Agave sisalana Species 0.000 description 1
- 229920005440 Altuglas® Polymers 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 239000013566 allergen Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000004883 computer application Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002270 exclusion chromatography Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 238000009755 vacuum infusion Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/285—Acrylic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/28—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2333/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2433/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Textile Engineering (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1352119 | 2013-03-08 | ||
| FR1352119A FR3002941B1 (fr) | 2013-03-08 | 2013-03-08 | Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne |
| PCT/FR2014/050532 WO2014135816A1 (fr) | 2013-03-08 | 2014-03-07 | Sirop (meth) acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2679494T3 true ES2679494T3 (es) | 2018-08-27 |
Family
ID=48795655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES14715045.2T Active ES2679494T3 (es) | 2013-03-08 | 2014-03-07 | Jarabe (met)acrílico líquido de impregnación de un sustrato fibroso, método de impregnación de un sustrato fibroso, material compuesto obtenido después de polimerización de dicho sustrato impregnado previamente |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US10280271B2 (enExample) |
| EP (1) | EP2971327B1 (enExample) |
| JP (1) | JP6604853B2 (enExample) |
| ES (1) | ES2679494T3 (enExample) |
| FR (1) | FR3002941B1 (enExample) |
| WO (1) | WO2014135816A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3002941B1 (fr) * | 2013-03-08 | 2015-04-10 | Arkema France | Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne |
| FR3002943B1 (fr) | 2013-03-11 | 2015-03-27 | Arkema France | Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne. |
| FR3002942B1 (fr) | 2013-03-11 | 2016-01-22 | Arkema France | Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne. |
| FR3005057B1 (fr) | 2013-04-25 | 2015-05-15 | Arkema France | Sirop liquide (meth)acrylique, son procede de polymerisation, son utilisation et objet moule obtenu a partir de celui-ci |
| FR3016642B1 (fr) * | 2014-01-22 | 2020-02-21 | Arkema France | Procede d'impregnation pour un substrat fibreux, sirop monomere liquide pour le procede d'impregnation, sa methode de polymerisation et article structurel obtenu |
| FR3030585B1 (fr) * | 2014-12-22 | 2017-02-03 | Arkema France | Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique, composition dudit melange, et materiau composite obtenu apres polymerisation dudit melange. |
| CN108495866B (zh) * | 2015-12-28 | 2021-03-02 | 雅马哈株式会社 | 用于frp的树脂组合物、frp片材和成型产品 |
| FR3046605B1 (fr) * | 2016-01-11 | 2019-09-06 | Arkema France | Composition liquide comprenant un polymere a phases multiples, son procede de preparation et son utilisation |
| FR3046606B1 (fr) | 2016-01-11 | 2019-09-06 | Arkema France | Composition (meth)acrylique liquide comprenant un polymere a phases multiples et un monomere (meth)acrylique, son procede de preparation et son utilisation |
| FR3053350B1 (fr) * | 2016-06-29 | 2020-03-27 | Arkema France | Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci |
| WO2019011982A1 (en) | 2017-07-12 | 2019-01-17 | Hexcel Composites Limited | RESIN COMPOSITION |
| FR3073855B1 (fr) * | 2017-11-21 | 2020-12-18 | Arkema France | Composition liquide adaptee a des applications de composites thermoplastiques moulees a base de smc |
| FR3078683A1 (fr) | 2018-03-07 | 2019-09-13 | Francois Geli | Option a bas cout d’une deuxieme aile pour rendre ultra-sobre un avion de ligne |
| FR3083241B1 (fr) * | 2018-06-28 | 2021-12-17 | Arkema France | Composition (meth)acrylique, materiau composite obtenu a partir d'une telle composition, son procede de fabrication et ses utilisations |
| KR20210143910A (ko) * | 2019-03-29 | 2021-11-29 | 아르끄마 프랑스 | 3ｄ 인쇄용 아크릴 조성물 |
| CN116120600B (zh) * | 2023-01-17 | 2025-01-10 | 哈尔滨工业大学 | 一种纤维增强热塑性复合材料原位浸渍成型方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE556399A (enExample) | 1956-04-18 | |||
| FR1256929A (fr) | 1960-05-13 | 1961-03-24 | Continental Can Co | Procédé de fabrication de pièces tubulaires par laminage et gonflage et billettes pour la mise en oeuvre de ce procédé |
| JPS5531822A (en) * | 1978-08-24 | 1980-03-06 | Sumitomo Chem Co Ltd | Manufacture of glassfiber-reinforced transparent resin plate |
| JPS58209527A (ja) * | 1982-06-01 | 1983-12-06 | Les-Ben Yuuteiritei Kk | 成形用複合材料の製造方法 |
| US5200107A (en) * | 1991-08-26 | 1993-04-06 | Aristech Chemical Corporation | Polymethylmethacrylate syrup as medium for liquid crystals |
| JP3486537B2 (ja) * | 1997-09-25 | 2004-01-13 | 三菱レイヨン株式会社 | アクリル系樹脂組成物、プレミックス、ｓｍｃ又はｂｍｃ、及び人工大理石の製造方法 |
| JP2000119421A (ja) * | 1998-10-16 | 2000-04-25 | Mitsui Chemicals Inc | 繊維強化複合材料 |
| JP2000327876A (ja) * | 1999-05-24 | 2000-11-28 | Sekisui Chem Co Ltd | 加飾用アクリル系バルクモールディングコンパウンド及び加飾成形品の成形方法 |
| JP2001277270A (ja) * | 2000-03-30 | 2001-10-09 | Nippon Shokubai Co Ltd | 型内被覆された樹脂成形品の製造方法 |
| EP1160212A1 (en) * | 2000-05-31 | 2001-12-05 | Asahi Glass Co., Ltd. | Hollow glass microspheres and method for producing the same |
| US6703193B1 (en) * | 2002-12-20 | 2004-03-09 | Eastman Kodak Company | Microbead and immiscible polymer voided polyester for imaging medias |
| JP2005048059A (ja) * | 2003-07-29 | 2005-02-24 | Kuraray Co Ltd | 炭素繊維強化複合材用メタクリル系重合体組成物 |
| JP2005082612A (ja) * | 2003-09-04 | 2005-03-31 | Japan U-Pica Co Ltd | アクリル系樹脂成形材料 |
| JP2005089900A (ja) * | 2003-09-17 | 2005-04-07 | Kuraray Co Ltd | メタクリル系シラップを用いた繊維基材の複合化方法 |
| US8603624B2 (en) | 2009-11-20 | 2013-12-10 | Panasonic Corporation | Prepreg, laminate, metal clad laminate, circuit board, and circuit board for LED mounting |
| FR2969633B1 (fr) | 2010-12-23 | 2015-02-06 | Arkema France | Composition pour des plaques coulees nanostructurees reticulees |
| FR2981652B1 (fr) | 2011-10-21 | 2015-03-27 | Arkema France | Composites via la polymerisation in-situ de resines thermoplastiques methacryliques |
| FR2993581B1 (fr) | 2012-07-18 | 2016-01-22 | Arkema France | Procede d'impregnation pour un substrat fibreux, sirop (meth)acrylique liquide pour le procede d'impregnation, son procede de polymerisation et produit structure obtenu a partir de celui-ci |
| FR3002940B1 (fr) * | 2013-03-08 | 2016-01-22 | Arkema France | Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux et son procede de fabrication, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne. |
| FR3002941B1 (fr) * | 2013-03-08 | 2015-04-10 | Arkema France | Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne |
| FR3002942B1 (fr) * | 2013-03-11 | 2016-01-22 | Arkema France | Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne. |
| FR3002943B1 (fr) * | 2013-03-11 | 2015-03-27 | Arkema France | Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne. |
| FR3005057B1 (fr) * | 2013-04-25 | 2015-05-15 | Arkema France | Sirop liquide (meth)acrylique, son procede de polymerisation, son utilisation et objet moule obtenu a partir de celui-ci |
-
2013
- 2013-03-08 FR FR1352119A patent/FR3002941B1/fr not_active Expired - Fee Related
-
2014
- 2014-03-07 EP EP14715045.2A patent/EP2971327B1/fr active Active
- 2014-03-07 JP JP2015560754A patent/JP6604853B2/ja active Active
- 2014-03-07 WO PCT/FR2014/050532 patent/WO2014135816A1/fr not_active Ceased
- 2014-03-07 ES ES14715045.2T patent/ES2679494T3/es active Active
- 2014-03-07 US US14/772,862 patent/US10280271B2/en active Active
-
2019
- 2019-03-14 US US16/352,932 patent/US10882966B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US10280271B2 (en) | 2019-05-07 |
| US20190211166A1 (en) | 2019-07-11 |
| WO2014135816A1 (fr) | 2014-09-12 |
| FR3002941B1 (fr) | 2015-04-10 |
| EP2971327A1 (fr) | 2016-01-20 |
| FR3002941A1 (fr) | 2014-09-12 |
| JP6604853B2 (ja) | 2019-11-13 |
| US10882966B2 (en) | 2021-01-05 |
| JP2016513741A (ja) | 2016-05-16 |
| US20160009878A1 (en) | 2016-01-14 |
| EP2971327B1 (fr) | 2018-04-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2679494T3 (es) | Jarabe (met)acrílico líquido de impregnación de un sustrato fibroso, método de impregnación de un sustrato fibroso, material compuesto obtenido después de polimerización de dicho sustrato impregnado previamente | |
| ES2712733T3 (es) | Jarabe (met)acrílico líquido de impregnación de un sustrato fibroso y su procedimiento de fabricación, procedimiento de impregnación de un sustrato fibroso, material compuesto obtenido después de la polimerización de dicho sustrato pre-impregnado | |
| ES2662714T3 (es) | Partículas termoplásticas reticuladas manipuladas para el endurecimiento interlaminar | |
| US10131768B2 (en) | Liquid (meth)acrylic syrup for impregnating a fibrous substrate, method of impregnating a fibrous substrate, composite material obtained following polymerisation of the pre-impregnated substrate | |
| JP6778309B2 (ja) | イン・サイテュ重合で得られる熱可塑性（メタ）アクリル樹脂の複合材料と、その使用 | |
| ES2804100T3 (es) | Procedimiento de impregnación para un sustrato fibroso, un jarabe de monómero líquido para el procedimiento de impregnación, su método de polimerización y artículo estructurado obtenido del mismo | |
| US10683405B2 (en) | Liquid (meth)acrylic syrup for impregnating a fibrous substrate, method of impregnating a fibrous substrate, composite material obtained following polymerisation of the pre-impregnated substrate | |
| US10294358B2 (en) | Impregnation process for a fibrous substrate, a liquid (meth) acrylic syrup for the impregnation process, its method of polymerization and structured article obtained thereof | |
| ES2627738T3 (es) | Un jarabe (met) acrílico líquido, su método de polimerización, uso y articulo moldeado obtenido del mismo | |
| CN105246689A (zh) | 多层复合材料组合物、其制造方法及由其得到的制品 | |
| US11040504B2 (en) | Method for producing a multilayer composite material, multilayer composite material obtained by the method and mechanical parts or structures produced with said material | |
| BR112019011102A2 (pt) | composição líquida compreendendo dois iniciadores, seu processo de polimerização, uso e material ou composição obtida seguindo a polimerização de composição | |
| CN107567468A (zh) | 液体(甲基)丙烯酸系浆液，用上述浆液印刷纤维基材的方法，和在所述印刷浆液的聚合反应后获得的复合材料 | |
| CN114206574A (zh) | 风力发电厂的转子叶片中和船舶制造中作为芯材的聚甲基丙烯酸甲酯硬质泡沫的制备方法 | |
| BR112020017164A2 (pt) | Composição precursora para compósitos termoplásticos acrílicos e seu método de preparação e uso | |
| BR112020025345A2 (pt) | Composicão líquida compreendendo três iniciadores, seu processo de polimerização, uso e material ou composição obtida após a polimerização da composição |