ES2651856T3 - Colectores de compuestos de poliésteres de amonio policuaternario para la flotación inversa por espuma de silicatos de menas no sulfídicas - Google Patents

Colectores de compuestos de poliésteres de amonio policuaternario para la flotación inversa por espuma de silicatos de menas no sulfídicas Download PDF

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Publication number
ES2651856T3
ES2651856T3 ES14811922.5T ES14811922T ES2651856T3 ES 2651856 T3 ES2651856 T3 ES 2651856T3 ES 14811922 T ES14811922 T ES 14811922T ES 2651856 T3 ES2651856 T3 ES 2651856T3
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formula
group
collectors
reverse flotation
polyquaternary ammonium
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ES14811922.5T
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English (en)
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Natalija Smolko-Schvarzmayr
Anders Klingberg
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Nouryon Chemicals International BV
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Akzo Nobel Chemicals International BV
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/916—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D219/00—Heterocyclic compounds containing acridine or hydrogenated acridine ring systems
    • C07D219/04—Heterocyclic compounds containing acridine or hydrogenated acridine ring systems with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the ring system
    • C07D219/06—Oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/01—Organic compounds containing nitrogen
    • B03D1/011—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/016—Macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/02—Froth-flotation processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/02—Froth-flotation processes
    • B03D1/021—Froth-flotation processes for treatment of phosphate ores
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C229/24—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having more than one carboxyl group bound to the carbon skeleton, e.g. aspartic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C229/26—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having more than one amino group bound to the carbon skeleton, e.g. lysine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/02—Collectors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/06—Depressants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00—Specified materials treated by the flotation agents; Specified applications
    • B03D2203/02—Ores
    • B03D2203/04—Non-sulfide ores
    • B03D2203/06—Phosphate ores

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

Un compuesto que puede obtenerse por condensación de al menos un poliol que tiene 3-4 grupos hidroxilo o un producto alcoxilado del mismo, preferiblemente glicerol o glicerol alcoxilado, que tiene la formula**Fórmula** donde Z>= -(CH2CH(CH3)O)m1(CH2CH2O) o(CH2CH(CH3)O)m2T, donde T es H, m1 y m2 son, de forma independiente, un número de 0-4, preferiblemente m1 y/o m2 son 0, y o es 0 o un número desde 1, preferiblemente desde 2, hasta 10, preferiblemente hasta 5; preferiblemente, la suma de todas las o es 0; Y>= -CH2OZ, -CH2CH3 u -OZ; X>= H o CH2OZ; y V>= Z o**Fórmula** al menos un ácido dicarboxílico o un derivado del mismo que tiene la fórmula (IIa) o (IIb)**Fórmula** donde D es -OH, -Cl, o -OR4, donde R4 es un grupo alquilo C1-C4; R3 es un enlace, un radical alquileno de fórmula -(CH2)z-, en la que z es un número entero de 1 a 10, preferiblemente de 2 a 4, y lo más preferiblemente 2, y en la que el radical alquileno puede estar sustituido por 1 o 2 grupos -OH; el grupo -CH>=CH-, un cicloalquileno, un cicloalquenileno o un grupo arileno; al menos una alcanolamina que tiene la fórmula (III)**Fórmula** en donde cada x es, de forma independiente, un número entre 1 y 5, y la suma de todas las x, de media, es un número entre 2 y 10, AO es un grupo alquilenoxi que tiene 2-4 átomos de carbono, R5 es un grupo alquilo C1-C4, preferiblemente un grupo metilo, o [AO]xH; y al menos un ácido graso que tiene la fórmula R(C>=O)OH (IV) donde R es un grupo hidrocarbilo que tiene de 7 a 23, preferiblemente de 11 a 21, átomos de carbono, opcionalmente sustituidos; seguido por reacción con un agente alquilante, de forma adecuada un haluro de alquilo C1-C4, preferiblemente cloruro de metilo o sulfato de dimetilo en donde el procedimiento incluye las siguientes etapas 1) reacción de una mezcla que consiste en al menos una alcanolamina, al menos un ácido graso monocarboxílico, al menos un ácido dicarboxílico y al menos un poliol que tiene 3-4 grupos hidroxilo, para formar un poliéster, y 2) cuaternización del poliéster resultante por el agente alquilante.

Description

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Claims (1)

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ES14811922.5T 2013-12-18 2014-12-15 Colectores de compuestos de poliésteres de amonio policuaternario para la flotación inversa por espuma de silicatos de menas no sulfídicas Active ES2651856T3 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP13198074 2013-12-18
EP13198086 2013-12-18
EP13198086 2013-12-18
EP13198074 2013-12-18
PCT/EP2014/077669 WO2015091308A1 (en) 2013-12-18 2014-12-15 Polyester polyquaternary ammonium compound collectors for reverse froth flotation of silicates from nonsulfidic ores

Publications (1)

Publication Number Publication Date
ES2651856T3 true ES2651856T3 (es) 2018-01-30

Family

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ES14811922.5T Active ES2651856T3 (es) 2013-12-18 2014-12-15 Colectores de compuestos de poliésteres de amonio policuaternario para la flotación inversa por espuma de silicatos de menas no sulfídicas

Country Status (11)

Country Link
US (1) US10100146B2 (es)
EP (1) EP3083553B1 (es)
KR (1) KR102343677B1 (es)
BR (1) BR112016013120B1 (es)
CA (1) CA2932866C (es)
EA (1) EA031803B1 (es)
ES (1) ES2651856T3 (es)
NO (1) NO3083553T3 (es)
SA (1) SA516371322B1 (es)
UA (1) UA119757C2 (es)
WO (1) WO2015091308A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3386473B1 (en) * 2015-12-08 2022-04-20 Clariant International Ltd Oligoester ammonium salts and their use in cosmetic compositions
FR3047674B1 (fr) 2016-02-16 2018-02-16 Arkema France Utilisation d'amines alkoxylees en tant qu'agents collecteurs pour l'enrichissement de minerai
FR3047675B1 (fr) * 2016-02-16 2018-02-16 Arkema France Utilisation d'amines alkoxylees en tant qu'agents collecteurs pour l'enrichissement de minerai
EP3444036A1 (en) * 2017-08-16 2019-02-20 Omya International AG Indirect flotation process for manufacturing white pigment containing products
MX2020005410A (es) * 2018-01-16 2020-08-13 Clariant Int Ltd Esterquats para la flotacion de minerales y menas no sulfidicos, y metodo.
CA3103864A1 (en) * 2018-07-03 2020-01-09 Nouryon Chemicals International B.V. Collector composition containing biodegradable compound and process for treating siliceous ores
CN113692318B (zh) * 2019-04-19 2023-06-06 诺力昂化学品国际有限公司 包含n-酰化氨基酸的捕集剂组合物和处理非硫化矿的方法
CN111036416B (zh) * 2019-11-28 2021-11-16 东北大学 一种高效抑制剂5′-ATP-2Na在菱镁矿正浮选脱钙中的应用
CN111036415B (zh) * 2019-11-28 2021-11-16 东北大学 一种抑制剂hedp在菱镁矿正浮选脱钙中的应用
WO2022243367A1 (en) 2021-05-18 2022-11-24 Nouryon Chemicals International B.V. Polyester polyquats in cleaning applications

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19539876C1 (de) * 1995-10-26 1996-12-05 Henkel Kgaa Sorbitolesterquats
ES2130993B1 (es) 1997-04-30 2000-03-01 Kao Corp Sa Nueva materia activa suavizante para textiles, procedimiento para su obtencion y composiciones suavizantes para textiles que la contienen.
ES2180372B1 (es) 2000-03-22 2003-10-16 Kao Corp Sa Esteres derivados de alcanolaminas, acidos dicarboxilicos y alcoholes grasos, y los tensioactivos cationicos obtenibles a partir de los mismos.
US6562780B2 (en) * 2001-06-07 2003-05-13 Kao Corporation Esters derived from alkanolamines, dicarboxylic acids and fatty alcohols and the cationic surfactants obtainable therefrom
GB0607500D0 (en) * 2006-04-13 2006-05-24 Ici Plc Structurants for oil phases
ES2354119T5 (es) * 2007-01-26 2014-05-16 Cognis Ip Management Gmbh Uso de esterquats poliméricos para la flotación de minerales y menas no sulfurosos
WO2011147855A2 (en) 2010-05-28 2011-12-01 Akzo Nobel Chemicals International B.V. Quaternary ammonium compounds and their use as collectors in froth flotation processes
DE102010017635A1 (de) 2010-06-29 2011-12-29 G+R Technology Group Ag Recyclingsystem und Verfahren zum Betreiben eines Recyclingsystems
EA024280B1 (ru) 2010-08-30 2016-09-30 Акцо Нобель Кемикалз Интернэшнл Б.В. Применение сложнополиэфирполиаминных и четвертичных сложнополиэфирполиаммонийных соединений в качестве ингибиторов коррозии
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Publication number Publication date
EA031803B1 (ru) 2019-02-28
EP3083553B1 (en) 2017-10-18
KR20160098286A (ko) 2016-08-18
CA2932866A1 (en) 2015-06-25
CA2932866C (en) 2023-03-07
US10100146B2 (en) 2018-10-16
BR112016013120B1 (pt) 2020-12-29
US20160304663A1 (en) 2016-10-20
SA516371322B1 (ar) 2019-05-06
NO3083553T3 (es) 2018-03-17
EA201691195A1 (ru) 2016-10-31
KR102343677B1 (ko) 2021-12-27
WO2015091308A1 (en) 2015-06-25
EP3083553A1 (en) 2016-10-26
UA119757C2 (uk) 2019-08-12

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