ES2628812T3 - Sistema iniciador para la síntesis de cauchos de dieno de alto contenido de vinilo, un procedimiento para la preparación y su uso para la preparación de cauchos de dieno de alto contenido de vinilo - Google Patents

Sistema iniciador para la síntesis de cauchos de dieno de alto contenido de vinilo, un procedimiento para la preparación y su uso para la preparación de cauchos de dieno de alto contenido de vinilo Download PDF

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Publication number
ES2628812T3
ES2628812T3 ES10702881.3T ES10702881T ES2628812T3 ES 2628812 T3 ES2628812 T3 ES 2628812T3 ES 10702881 T ES10702881 T ES 10702881T ES 2628812 T3 ES2628812 T3 ES 2628812T3
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ES
Spain
Prior art keywords
preparation
diene rubbers
high vinyl
vinyl diene
synthesis
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES10702881.3T
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English (en)
Inventor
Norbert Steinhauser
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Arlanxeo Deutschland GmbH
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Arlanxeo Deutschland GmbH
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Publication of ES2628812T3 publication Critical patent/ES2628812T3/es
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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/56Alkali metals being the only metals present, e.g. Alfin catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/56Alkali metals being the only metals present, e.g. Alfin catalysts
    • C08F4/565Lithium being present, e.g. butyllithium + sodiumphenoxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Sistema iniciador para la polimerización aniónica que contiene (A) al menos un compuesto de organolitio, (B) al menos un di(aminoalquil)éter y (C) al menos un alcóxido de sodio y/o un fenóxido de sodio.

Description

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Claims (1)

  1. imagen1
    imagen2
ES10702881.3T 2009-02-18 2010-02-09 Sistema iniciador para la síntesis de cauchos de dieno de alto contenido de vinilo, un procedimiento para la preparación y su uso para la preparación de cauchos de dieno de alto contenido de vinilo Active ES2628812T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102009009531 2009-02-18
DE102009009531A DE102009009531A1 (de) 2009-02-18 2009-02-18 Initiatorsystem zur Synthese von Hochvinyl-Dienkautschuken, ein Verfahren zur Herstellung und dessen Verwendung zur Herstellung von Hochvinyl-Dienkautschuken
PCT/EP2010/051532 WO2010094590A1 (de) 2009-02-18 2010-02-09 Initiatorsystem zur synthese von hochvinyl-dienkautschuken, ein verfahren zur herstellung und dessen verwendung zur herstellung von hochvinyl-dienkautschuken

Publications (1)

Publication Number Publication Date
ES2628812T3 true ES2628812T3 (es) 2017-08-04

Family

ID=42044402

Family Applications (1)

Application Number Title Priority Date Filing Date
ES10702881.3T Active ES2628812T3 (es) 2009-02-18 2010-02-09 Sistema iniciador para la síntesis de cauchos de dieno de alto contenido de vinilo, un procedimiento para la preparación y su uso para la preparación de cauchos de dieno de alto contenido de vinilo

Country Status (16)

Country Link
US (1) US20120004379A1 (es)
EP (1) EP2398833B1 (es)
JP (2) JP5504285B2 (es)
KR (1) KR101391036B1 (es)
CN (1) CN102317323B (es)
BR (1) BRPI1008908B1 (es)
DE (1) DE102009009531A1 (es)
ES (1) ES2628812T3 (es)
MX (1) MX2011008658A (es)
PL (1) PL2398833T3 (es)
RU (1) RU2568609C2 (es)
SA (1) SA110310134B1 (es)
SG (1) SG173700A1 (es)
TW (1) TWI537293B (es)
WO (1) WO2010094590A1 (es)
ZA (1) ZA201105984B (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009009531A1 (de) * 2009-02-18 2010-08-19 Lanxess Deutschland Gmbh Initiatorsystem zur Synthese von Hochvinyl-Dienkautschuken, ein Verfahren zur Herstellung und dessen Verwendung zur Herstellung von Hochvinyl-Dienkautschuken
CN104045772B (zh) * 2013-03-13 2017-02-01 中国石油化工股份有限公司 一种端基改性溶聚丁二烯和/或异戊二烯‑苯乙烯共聚物及其制备方法和应用
TWI506043B (zh) * 2013-12-31 2015-11-01 Chi Mei Corp 異戊二烯-乙烯基芳香烴共聚物及其合成方法
ITUB20150281A1 (it) 2015-03-13 2016-09-13 Fastech S R L Processo in soluzione per la produzione di copolimeri stirene-diene.
EP3458490B1 (en) * 2016-09-09 2022-11-02 Dynasol Elastómeros, S.A.de C.V. Polar modifier systems for high vinyl block copolymerization
RU2656855C1 (ru) * 2017-09-26 2018-06-07 Публичное Акционерное Общество "Нижнекамскнефтехим" Способ получения полимеров бутадиена или сополимеров бутадиена со стиролом и их функционализированных аналогов с высоким содержанием 1,2-звеньев в бутадиеновой части
US11542355B2 (en) * 2018-10-18 2023-01-03 Dynasol Elastómeros, S.A. De C.V. Polar modifier systems for high vinyl block copolymerization
US20240002569A1 (en) * 2020-05-21 2024-01-04 China Petroleum & Chemical Corporation Liquid butadiene-styrene polymer, preparation method for same and application of same, as well as composition, polymer coating, adhesive, and cross-linking agent

Family Cites Families (14)

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Publication number Priority date Publication date Assignee Title
CH388911A (de) * 1961-12-15 1965-03-15 Sulzer Ag Abscheider
US3301840A (en) 1964-09-17 1967-01-31 Phillips Petroleum Co Preparation of polymers of conjugated dienes using organolithium/polar compound catalyst systems
JPS5937014B2 (ja) 1978-07-11 1984-09-07 日本ゼオン株式会社 タイヤ・トレツド用ゴム組成物
DE3721538A1 (de) 1987-06-30 1989-01-12 Ruhrchemie Ag Verfahren zur herstellung von 2,2'-oxybis n,n-dimethyl-ethanamin
US5677402A (en) * 1995-09-22 1997-10-14 The Goodyear Tire & Rubber Company Process for preparing 3,4-polyisoprene rubber
US5534592A (en) * 1995-09-22 1996-07-09 The Goodyear Tire & Rubber Company High performance blend for tire treads
DE10055497A1 (de) * 2000-11-09 2002-05-29 Bayer Ag Modifizierungsmittel für die anionische Polymerisation
DE10243618A1 (de) * 2001-11-23 2003-06-05 Walter Hellermann Mikrostrukturregler zur Herstellung von Homo- und Copolymeren von Dienen und Vinylaromaten durch anionische Polymerisation
DE10234746B4 (de) * 2002-07-30 2004-04-29 Sasol Germany Gmbh Verfahren zur Herstellung von Polymerisaten unter Verwendung von konjugierten Dienen und vinylaromatischen Verbindungen, nach diesem Verfahren hergestellte Polymerisate und deren Verwendung
DE10240790B3 (de) * 2002-08-30 2004-04-22 Sasol Germany Gmbh Verfahren zur Herstellung von Polymerisaten unter Verwendung von konjugierten Dienen und gegebenenfalls vinylaromatischen Verbindungen, nach diesem Verfahren hergestellte Polymerisate und deren Verwendung
US7776965B2 (en) * 2004-11-09 2010-08-17 Chevron Phillips Chemical Company, Lp Monovinylarene conjugated diene copolymer compositions for acrylate blends
JP4716756B2 (ja) * 2005-03-03 2011-07-06 旭化成ケミカルズ株式会社 ランダム共重合体の製造方法
ES2401803T3 (es) * 2006-08-16 2013-04-24 Asahi Kasei Chemicals Corporation Procedimiento para producir copolímero de bloques, y copolímero de bloques o producto hidrogenado del mismo
DE102009009531A1 (de) * 2009-02-18 2010-08-19 Lanxess Deutschland Gmbh Initiatorsystem zur Synthese von Hochvinyl-Dienkautschuken, ein Verfahren zur Herstellung und dessen Verwendung zur Herstellung von Hochvinyl-Dienkautschuken

Also Published As

Publication number Publication date
CN102317323B (zh) 2014-02-05
KR101391036B1 (ko) 2014-04-30
JP2014080619A (ja) 2014-05-08
BRPI1008908B1 (pt) 2020-01-28
RU2011138063A (ru) 2013-03-27
ZA201105984B (en) 2012-11-28
SA110310134B1 (ar) 2014-08-25
EP2398833B1 (de) 2017-04-12
PL2398833T3 (pl) 2017-09-29
JP5504285B2 (ja) 2014-05-28
TWI537293B (zh) 2016-06-11
TW201041919A (en) 2010-12-01
WO2010094590A1 (de) 2010-08-26
BRPI1008908A2 (pt) 2016-03-15
KR20110118169A (ko) 2011-10-28
US20120004379A1 (en) 2012-01-05
DE102009009531A1 (de) 2010-08-19
CN102317323A (zh) 2012-01-11
SG173700A1 (en) 2011-09-29
EP2398833A1 (de) 2011-12-28
JP2012518065A (ja) 2012-08-09
MX2011008658A (es) 2011-09-06
RU2568609C2 (ru) 2015-11-20

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