ES2579946T3 - Formulaciones de aceite que comprenden 1-metil-ciclopropeno - Google Patents
Formulaciones de aceite que comprenden 1-metil-ciclopropeno Download PDFInfo
- Publication number
- ES2579946T3 ES2579946T3 ES11703802.6T ES11703802T ES2579946T3 ES 2579946 T3 ES2579946 T3 ES 2579946T3 ES 11703802 T ES11703802 T ES 11703802T ES 2579946 T3 ES2579946 T3 ES 2579946T3
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- Spain
- Prior art keywords
- drops
- dispersed
- cyclopropene
- methyl
- solid particles
- Prior art date
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Fertilizers (AREA)
- Detergent Compositions (AREA)
- Medicinal Preparation (AREA)
- Lubricants (AREA)
Abstract
Una composición que comprende: (a) un fluido vertible no acuoso que comprende uno o más carbonatos de alquileno; (b) gotas dispersadas en dicho fluido vertible (a), en donde dichas gotas comprenden: (i) una fase continua no acuosa que es un sólido y (ii) partículas sólidas dispersadas en dicha fase continua (i); en donde (ii) la mediana del tamaño de dichas partículas sólidas, medido por la mayor dimensión, es de 100 micrómetros o menos; y en donde dichas partículas sólidas (ii) comprenden 1-metilciclopropeno (1-MCP) y alfa-ciclodextrina.
Description
Ejemplos
En los Ejemplos que siguen, se usaron los siguientes materiales.
5 Complejo 1 = Polvo seco que contiene complejo de 1MCP y alfaciclodextrina, con 4,7 % de 1MCP en peso. El Complejo 1 fue molido con aire de modo que la mediana del tamaño, medida por la mayor dimensión, fue inferior a 50 micrómetros. HC01 = ISOPAR™ V hidrocarburo, hidrocarburos de petróleo C12 a C20, de ExxonMobil Chemical. PAVP = AGRIMER™ AL22 dispersante, polímero de vinilpirrolidona alquilada, ISP Corporation.
10 PVPVA = AGRIMER™ VA51 dispersante, copolímero de vinilpirrolidona y acetato de vinilo, ISP Corporation. BCP = TOXIMUL™ 8320 emulsionante, copolímero de bloques a base de butilo, Stepan Co. Sílice 1 = AEROSIL™ R972 sílice, sílice de humo, tratada con dimetildiclorosilano, tamaño de partícula 5 a 50 nanómetros, Evonik Industries. PC = JEFFSOL™ AG1550 disolvente, contiene carbonato de propileno, Huntsman Performance Products.
15 Cera = cera de parafina, punto de fusión: 5357 °C, Aldrich Chemical. Soja = DRITEX™ S aceite de soja hidrogenado, completamente hidrogenado, Stratus Foods. EVA = ELVAX™ 250 copolímero de etilenoacetato de vinilo, DuPont. HC02 = UNIPAR™ 260 hidrocarburos de petróleo, UniSource Energy, Inc.
20 “Base” (para fluido vertible (a))
Se mezclaron 2,50 g de Sílice 1 y 55,51 g de PC y se dispersaron con una mezcladora de alto corte a fin de formar una suspensión, que se calentó de 60 °C a 70 °C.
25 Ejemplo Comparativo A
Formulación de gotas. Se mezclaron 13,44 g de HC01 y 0,65 g de PAVP y se calentaron de 60 °C a 70 °C, y a continuación se mezclaron con 21,50 g de Complejo 1. Estando aún a 60 °C a 70 °C, esta formulación de gotas se combinó con base (también de 60 a 70 °C) y se dispersó con una mezcladora de alto corte hasta que la viscosidad
30 tenía una apariencia muy espesa. Se agregaron 1,4 g de PVPVA, y la mezcla se agitó a mano. A continuación, se agregaron 5,00 g de BCP, y la mezcla se agitó a mano. Después de la adición de PVPVA y BCP, la viscosidad pareció disminuir algo. La emulsión resultante se dejó enfriar hasta 25 °C. Este es un Ejemplo Comparativo, ya que HC01 no es un líquido de alta viscosidad a 25 °C.
35 Ejemplos 1, 3 y 4
Se prepararon composiciones usando el método del Ejemplo Comparativo A, excepto que se reemplazaron los 13,44 g de HC01 con 13,44 g de un ingrediente diferente, de la siguiente manera.
40 El Ejemplo 1 utilizó cera (sólida a 25 °C). El Ejemplo 2 utilizó soja (sólida a 25 °C). El Ejemplo 3 utilizó una solución de EVA en HC02 (EVA 10 % en peso referido al peso de la solución) (gel a 25 °C).
45 Observaciones:
Cada ejemplo se diluyó en carbonato de propileno, y se observó el resultado con un microscopio óptico con un aumento de 400 X. Además, cada ejemplo se diluyó en agua, y se observó el resultado con un microscopio óptico con un aumento de 400 X. En cada caso, se observó que las partículas del Complejo 1 se dispersaban dentro de las
50 gotas y se observó que las gotas se dispersaban a través de todo el campo de visión.
Se observó que las partículas del Complejo 1 se dispersaban dentro de las gotas, cuya composición era aquella de la Formulación de Gotas, en cada ejemplo.
55 Las observaciones de las formulaciones diluidas mostraron que cada uno de los Ejemplos 1, 3 y 4 tenía partículas de Complejo 1 que actuaron como las partículas sólidas (ii). Estas partículas se dispersaron dentro de las gotas preparadas de las diversas Formulaciones de Gotas, que actuaron como las gotas (b). Las gotas se dispersaron dentro del carbonato de propileno, que actuó como el fluido vertible (a).
11
Claims (1)
-
imagen1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30907310P | 2010-03-01 | 2010-03-01 | |
| US309073P | 2010-03-01 | ||
| PCT/US2011/024120 WO2011109144A1 (en) | 2010-03-01 | 2011-02-09 | Oil formulations comprising cylcopropene compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2579946T3 true ES2579946T3 (es) | 2016-08-17 |
| ES2579946T9 ES2579946T9 (es) | 2016-10-20 |
Family
ID=43859621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES11703802.6T Active ES2579946T3 (es) | 2010-03-01 | 2011-02-09 | Formulaciones de aceite que comprenden 1-metil-ciclopropeno |
Country Status (28)
| Country | Link |
|---|---|
| US (1) | US8986723B2 (es) |
| EP (1) | EP2542054B9 (es) |
| JP (1) | JP5814950B2 (es) |
| KR (1) | KR20130018736A (es) |
| CN (1) | CN102770021B (es) |
| AR (1) | AR081726A1 (es) |
| AU (1) | AU2011221503B2 (es) |
| BR (1) | BR112012022025B1 (es) |
| CA (1) | CA2791209C (es) |
| CL (1) | CL2012002421A1 (es) |
| CO (1) | CO6602159A2 (es) |
| CR (1) | CR20120463A (es) |
| ES (1) | ES2579946T3 (es) |
| HK (1) | HK1174494A1 (es) |
| HU (1) | HUE029004T2 (es) |
| IL (1) | IL221558A (es) |
| MX (1) | MX2012010123A (es) |
| MY (1) | MY160530A (es) |
| NZ (1) | NZ601618A (es) |
| PL (1) | PL2542054T3 (es) |
| PT (1) | PT2542054T (es) |
| RU (1) | RU2560851C2 (es) |
| SG (1) | SG183832A1 (es) |
| SI (1) | SI2542054T1 (es) |
| TW (1) | TWI536907B (es) |
| UA (1) | UA111716C2 (es) |
| WO (1) | WO2011109144A1 (es) |
| ZA (1) | ZA201205951B (es) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9012515B2 (en) | 2007-08-03 | 2015-04-21 | Rohm And Haas Company | Oil formulations with thickeners |
| RS55276B1 (sr) * | 2009-01-09 | 2017-02-28 | Syngenta Participations Ag | Stabilizovana agrohemijska kompozicija |
| US8343634B2 (en) * | 2009-01-27 | 2013-01-01 | Momentive Specialty Chemicals Inc. | Triglyceride compositions useful for preparing composite panels and applications thereof |
| BR112012027528A2 (pt) * | 2010-04-28 | 2016-07-26 | Syngenta Participations Ag | composição agroquímica estabilizada |
| CA2801265C (en) | 2010-06-07 | 2018-07-31 | Syngenta Participations Ag | Cyclopropene compositions |
| CN104812822A (zh) * | 2012-09-17 | 2015-07-29 | 农鲜股份有限公司 | 包含分散在树脂基质中的环丙烯复合物的颗粒的悬浮体 |
| RU2015114260A (ru) * | 2012-09-17 | 2016-11-10 | Агрофреш Инк. | Композиции и способы двойного капсулирования летучего соединения |
| RU2015116683A (ru) * | 2012-10-05 | 2016-11-27 | Агрофреш Инк. | Масляные препаративные формы, содержащие загустители |
| US9320288B2 (en) | 2012-11-30 | 2016-04-26 | Cellresin Technologies, Llc | Controlled release compositions and methods of using |
| US8802140B2 (en) * | 2013-05-05 | 2014-08-12 | Nazir Mir | Situ mixing and application of hydrocolloid systems for pre- and post harvest use on agricultural crops |
| US8822382B2 (en) | 2013-05-05 | 2014-09-02 | Nazir Mir | Hydrocolloid systems for reducing loss of volatile active compounds from their liquid formulations for pre- and post harvest use on agricultural crops |
| US9421793B2 (en) | 2014-06-26 | 2016-08-23 | Cellresin Technologies, Llc | Electrostatic printing of cyclodextrin compositions |
| EP3434103B1 (en) * | 2017-07-25 | 2020-02-12 | Certis Europe BV | Daminozide composition |
| WO2023225459A2 (en) | 2022-05-14 | 2023-11-23 | Novozymes A/S | Compositions and methods for preventing, treating, supressing and/or eliminating phytopathogenic infestations and infections |
| WO2023288294A1 (en) | 2021-07-16 | 2023-01-19 | Novozymes A/S | Compositions and methods for improving the rainfastness of proteins on plant surfaces |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6017849A (en) * | 1998-08-20 | 2000-01-25 | Biotechnologies For Horticulture, Inc. | Synthesis methods, complexes and delivery methods for the safe and convenient storage, transport and application of compounds for inhibiting the ethylene response in plants |
| TWI240613B (en) * | 2001-02-26 | 2005-10-01 | Rohm & Haas | Delivery systems for cyclopropenes |
| GB0104698D0 (en) * | 2001-02-26 | 2001-04-11 | Syngenta Ltd | Process for producing microcapsules |
| RU2267272C1 (ru) * | 2004-07-01 | 2006-01-10 | Общество с ограниченной ответственностью "Вега-хим" | Способ получения препаратов для послеуборочной обработки урожая сельскохозяйственной продукции |
| CA2565427A1 (en) * | 2005-11-08 | 2007-05-08 | Rohm And Haas Company | Compositions with cyclopropenes and non-hydrocarbon oils |
| EP1922927A1 (en) * | 2006-10-26 | 2008-05-21 | Syngeta Participations AG | A method for controlling soybean rust |
| WO2008089140A1 (en) * | 2007-01-17 | 2008-07-24 | Dow Agrosciences Llc | Delivery of ethylene blocking and/or promoting agents |
| JP5128392B2 (ja) | 2007-08-03 | 2013-01-23 | ローム アンド ハース カンパニー | 油配合物 |
| US8058335B2 (en) | 2008-05-14 | 2011-11-15 | Eastman Kodak Company | Wax dispersions for toners |
| ES2371603T3 (es) * | 2008-08-25 | 2012-01-05 | Rohm And Haas Company | Tratamiento de platanos. |
| RS55276B1 (sr) * | 2009-01-09 | 2017-02-28 | Syngenta Participations Ag | Stabilizovana agrohemijska kompozicija |
-
2011
- 2011-02-09 NZ NZ601618A patent/NZ601618A/xx not_active IP Right Cessation
- 2011-02-09 RU RU2012141559/13A patent/RU2560851C2/ru not_active IP Right Cessation
- 2011-02-09 PL PL11703802.6T patent/PL2542054T3/pl unknown
- 2011-02-09 BR BR112012022025-0A patent/BR112012022025B1/pt not_active IP Right Cessation
- 2011-02-09 ES ES11703802.6T patent/ES2579946T3/es active Active
- 2011-02-09 AU AU2011221503A patent/AU2011221503B2/en not_active Ceased
- 2011-02-09 KR KR1020127025666A patent/KR20130018736A/ko not_active Application Discontinuation
- 2011-02-09 EP EP11703802.6A patent/EP2542054B9/en active Active
- 2011-02-09 HU HUE11703802A patent/HUE029004T2/en unknown
- 2011-02-09 SG SG2012064234A patent/SG183832A1/en unknown
- 2011-02-09 MY MYPI2012003900A patent/MY160530A/en unknown
- 2011-02-09 CN CN201180010669.3A patent/CN102770021B/zh not_active Expired - Fee Related
- 2011-02-09 MX MX2012010123A patent/MX2012010123A/es active IP Right Grant
- 2011-02-09 PT PT117038026T patent/PT2542054T/pt unknown
- 2011-02-09 SI SI201130893A patent/SI2542054T1/sl unknown
- 2011-02-09 US US13/581,532 patent/US8986723B2/en active Active
- 2011-02-09 WO PCT/US2011/024120 patent/WO2011109144A1/en active Application Filing
- 2011-02-09 JP JP2012556080A patent/JP5814950B2/ja not_active Expired - Fee Related
- 2011-02-09 CA CA2791209A patent/CA2791209C/en active Active
- 2011-02-22 TW TW100105718A patent/TWI536907B/zh not_active IP Right Cessation
- 2011-02-28 AR ARP110100608A patent/AR081726A1/es active IP Right Grant
- 2011-09-02 UA UAA201211291A patent/UA111716C2/uk unknown
-
2012
- 2012-08-07 ZA ZA2012/05951A patent/ZA201205951B/en unknown
- 2012-08-21 IL IL221558A patent/IL221558A/en active IP Right Grant
- 2012-08-31 CL CL2012002421A patent/CL2012002421A1/es unknown
- 2012-09-12 CR CR20120463A patent/CR20120463A/es unknown
- 2012-09-14 CO CO12159131A patent/CO6602159A2/es active IP Right Grant
-
2013
- 2013-02-05 HK HK13101589.0A patent/HK1174494A1/xx not_active IP Right Cessation
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