ES2544857T3 - Uso de ésteres de lactato para la mejora del efecto de agentes fitosanitarios - Google Patents
Uso de ésteres de lactato para la mejora del efecto de agentes fitosanitarios Download PDFInfo
- Publication number
- ES2544857T3 ES2544857T3 ES06791755.9T ES06791755T ES2544857T3 ES 2544857 T3 ES2544857 T3 ES 2544857T3 ES 06791755 T ES06791755 T ES 06791755T ES 2544857 T3 ES2544857 T3 ES 2544857T3
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- Spain
- Prior art keywords
- effect
- improve
- lactate esters
- phytosanitary agents
- agents
- Prior art date
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- MLGCXEBRWGEOQX-UHFFFAOYSA-N tetradifon Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC(Cl)=C(Cl)C=C1Cl MLGCXEBRWGEOQX-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
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- 150000003918 triazines Chemical class 0.000 description 1
- YMXOXAPKZDWXLY-QWRGUYRKSA-N tribenuron methyl Chemical group COC(=O)[C@H]1CCCC[C@@H]1S(=O)(=O)NC(=O)N(C)C1=NC(C)=NC(OC)=N1 YMXOXAPKZDWXLY-QWRGUYRKSA-N 0.000 description 1
- REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 description 1
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- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Uso de ésteres de lactato de fórmula (I)**Fórmula** en la que R representa alquilo C4-C8 saturado o insaturado, no ramificado o ramificado, para la mejora del efecto de agentes fitosanitarios a nivel de plantas.
Description
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Agonistas/disruptores de ecdisona diacilhidrazinas, por ejemplo, cromafenozida, halofenozida, metoxifenozida, tebufenozida
Inhibidores de biosíntesis de quitina benzoilureas, por ejemplo, bistriflurón, clofluazurón, diflubenzurón, fluazurón, flucicloxurón, flufenoxurón, hexaflumurón,
lufenurón, novalurón, noviflumurón, penflurón, teflubenzurón, triflumurón, buprofezina ciromazina
Inhibidores de la fosforilación oxidativa, disruptores de ATP diafentiurón compuestos de organoestaño por ejemplo, azociclotina, cihexatina, óxidos de fenbutatina
Desacopladores de la fosforilación oxidativa mediante interrupción del gradiente de protón H pirroles, por ejemplo, clorofenapir dinitrofenoles, por ejemplo, binapacirl, dinobutón, dinocap, DNOC, meptildinocap
Inhibidores del transporte de electrones de sitio I METI, por ejemplo, fenazaquina, fenpiroximato, pirimidifén, piridabén, tebufenpirad, tolfenpirad hidrametilnón dicofol
Inhibidores del transporte de electrones de sitio II rotenonas Inhibidores del transporte de electrones de sitio III acequinocilo, fluacripirim Disruptores microbianos de la membrana intestinal de insectos cepas de Bacillus thuringiensis
Inhibidores de la síntesis de las grasa ácidos tetrónicos, por ejemplo, espirodiclofeno, espiromesifeno ácidos tetrámicos, por ejemplo, espirotetramato, cis-3-(2,5-dimetilfenil)-4-hidroxi-8-metoxi-1-azaespiro[4.5]dec-3-en-2-ona, carboxamidas, por ejemplo, flonicamida agonistas octopaminérgicos,
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por ejemplo, amitraz
Inhibidores de ATPasa estimulada por magnesio,
propargitas
análogos de nereistoxina,
por ejemplo, hidrogenoxalato de tiociclam, triosultap-sodio
Agonistas del receptor de rianodina,
dicarboxamidas del ácido benzoico, por ejemplo, flubendiamida
antranilamidas, por ejemplo rinaxipir (3-bromo-N-{4-cloro-2-metil-6-[(metilamino)carbonil]fenil}-1-(3
cloropiridin-2-il)-1H-pirazol-5-carboxamida)
Productos biológicos, hormonas o feromonas,
azadiractina, Bacillus spec, Beauveria spec., Codlemona, Metarrhizium spec., Paecilomyces spec.,
turingiensina, Verticillium spec.
Principios activos con mecanismos de acción desconocidos o no específicos
agentes fumigantes, por ejemplo, fosfuros de aluminio, bromuros de metilo, fluoruros de sulfurilo.
antinutritivos, por ejemplo, criolita, flonicamid, pimetrozina
inhibidores del crecimiento de ácaros, por ejemplo, clofetezina, etoxazol, hexitiazox.
amidoflumet, benclotiaz, benzoximato, bifenazato, bromopropilato, buprofezina, quinometionato, clordimeform, clorobenzilato, cloropicrina, clotiazobeno, ciclopreno, ciflumetofeno, diciclanilo, fenoxacrim, fentrifanilo, flubenzimina, flufenerim, flutenzina, Gossyplure, hidrametilnona, japoniluro, metoxadiazona, vaselina, butóxido de piperonilo, oleato de potasio, piridalilo, sulfluramida, tetradifón, tetrasul, triarateno, verbutín.
Como ejemplos de herbicidas son de citar:
anilidas, como por ejemplo diflufenicano y propanilo; ácidos arilcarboxílicos, como por ejemplo ácido dicloropicolínico, dicamba y picloram; ácidos ariloxialcanoicos, como por ejemplo 2,4-D, 2,4-DB, 2,4-DP, fluroxipir, MCPA, MCPP y triclopir; éster de ácido ariloxi-fenoxi-alcanoico, como por ejemplo diclofop-metilo, fenoxaprop-etilo, fluazifop-butilo, haloxifopmetilo y quizalofop-etilo; azinonas, como por ejemplo cloroidazón y norflurazón; carbamatos, como por ejemplo cloroprofam, desmedifam, fenmedifam y profam; cloroacetanilidas, como por ejemplo alacloro, acetocloro, butacloro, metazacloro, metolacloro, pretilacloro y propacloro; dinitroanilinas, como por ejemplo orizalina, pendimetalina y trifluralina; difeniléteres, como por ejemplo acifluorfén, bifenox, fluoroglicofén, fomesafén, halosafén, lactofén y oxifluorfén; ureas, como por ejemplo clorotolurón, diurón, fluometurón, isoproturón, linurón y metabenztiazurón; hidroxilaminas, como por ejemplo aloxidim, cletodim, cicloxidim, setoxidim y tralcoxidim; imidazolinonas, como por ejemplo imazetapir, imazametabenz, imazapir y imazaquina; nitrilos, como por ejemplo bromoxinilo, diclobenilo y ioxinilo; oxiacetamidas, como por ejemplo mefenacet; sulfonilureas, como por ejemplo amidosulfurón, bensulfurónmetilo, cloroimurón-etilo, clorosulfurón, cinosulfurón, metsulfurón-metilo, nicosulfurón, primisulfurón, pirazosulfurón-etilo, tifensulfurón-metilo, triasulfurón y tribenurón-metilo; tiolcarbamatos, como por ejemplo butilatos, cicloatos, dialatos, EPTC, esprocarb, molinatos, prosulfocarb, tiobencarb y trialatos; triazinas, como por ejemplo atrazina, cianazina, simazina, simetrina, terbutrina y terbutilazina; triazinonas, como por ejemplo hexazinón, metamitrón y metribuzina; compuestos similares, como por ejemplo aminotriazol, 4-amino-N-(1,1dimetiletil)-4,5-dihidro-3-(1-metiletil)-5-oxo-1H-1,2,4-triazol-1-carboxamida, benfuresatos, Bentazona, cinmetilina, clomazona, clopiralida, difenzoquat, ditiopir, etofumesato, fluoro-cloroidona, glufosinato, glifosato, isoxabén, piridato, quincloroac, quinmerac, sulfosato y tridifano.
Como ejemplos de reguladores del crecimiento de plantas son de citar cloruro de clorocolina, tidiazurón y etefón. Además de auxinas incluyendo las sintéticas como NAA, 2,4-D, ácido giberélico, cinetina, ácido abscísico, ácido salicílico, ácido jasmónico o bien sus ésteres y brasinoesteroides.
Como ejemplos de nutrientes de plantas son de citar fertilizantes inorgánicos u orgánicos habituales para el abastecimiento de plantas con macro-y/o micronutrientes.
Como ejemplos de repelentes son de citar dietiltolilamida, etilhexanodiol y butopironoxilo.
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Como cargas se tienen en cuenta todas las sustancias usadas normalmente para este fin en agentes fitosanitarios. Son de citar preferiblemente partículas inorgánicas como carbonatos, silicatos y óxidos con un tamaño de partícula medio de 0,005 a 5 μm, con especial preferencia de 0,02 a 2 μm. A modo de ejemplo son de citar dióxido de silicio, el denominado ácido silícico de alta dispersión, geles de sílice así como silicatos naturales y sintéticos y alumosilicatos.
Como compuestos que actúan como estabilizantes de emulsión y/o inhibidores de la cristalización se tienen en cuenta todas las sustancias usadas normalmente para este fin en agentes fitosanitarios.
Como favorecedores de la penetración se tienen en cuenta, por ejemplo, alcoxilatos de alcanol de fórmula (I)
R-O-(AO)mR’ (I)
en la que
R representa alquilo de cadena lineal o ramificada con 4 a 20 átomos de carbono,
R’ representa H, metilo, etilo, n-propilo, i-propilo, n-butilo, i-butilo, t-butilo, n-pentilo o n-hexilo,
AO representa un resto de óxido de etileno, un resto de óxido de propileno, un resto de óxido de butileno o
representa mezclas de restos de óxido de etileno y óxido de propileno o mezclas de restos de óxidos etileno y
óxido de butileno y
m representa números de 2 a 30.
Estas sustancias se tratan de mezclas de sustancias del tipo indicado con distintas longitudes de cadena. Para los índices se alcanzan por tanto valores promedio que se pueden desviar también de números enteros.
Como favorecedores de la penetración se tienen en cuenta otras sustancias tensioactivas usadas en formulaciones de principios activos agroquímicos. A modo de ejemplo son de citar nonilfenoles etoxilados, tributilfenolpoliglicoléteres, productos de reacción con óxido de etileno y/o óxido de propileno, alquilaminas alcoxiladas, mono-, di-o triglicéridos alcoxilados, ésteres de poli(óxido de etileno)-sorbitán de ácido graso además de ésteres de ácido graso y poliglicol, diésteres y diéteres de poli(óxido de alquileno), etoxilatos de ésteres de ácido graso así como etoxilatos de alquilo y etoxilatos alquilarilo, que pueden estar fosfatados y dado el caso neutralizados con bases. Como tensioactivos aniónicos se tienen en cuenta otras sustancias de este tipo que se pueden usar todas normalmente en agentes agroquímicos. Se prefieren sales de metal alcalino, de amonio y de metal alcalinotérreo de ácidos alquilsulfónicos o ácidos alquilarilsulfónicos, así como étersulfatos o -sulfonatos de alquil(poli)etilenglicoléteres. Como favorecedores de la penetración no tensioactivos son de citar ésteres de ácido graso, mono-y diésteres de ácidos dicarboxílicos así como ésteres de fosfato.
El contenido en los componentes individuales puede variar en las formulaciones de acuerdo con la invención dentro de un amplio intervalo.
La preparación de formulaciones de acuerdo con la invención se realiza, por ejemplo, en forma que se mezclen entre sí componentes en las relaciones deseadas respectivamente. Si se trata el principio activo agroquímico de una sustancia sólida entonces se usa esta en general bien en forma finamente molida o en forma de una solución o suspensión en un disolvente orgánico o agua. Si el principio activo agroquímico es líquido entonces sobra frecuentemente el uso de un disolvente orgánico. Es posible además usar un principio activo agroquímico sólido en forma de una masa fundida.
Las temperaturas se pueden variar en la realización del procedimiento en un determinado intervalo. Se trabaja por lo general a temperaturas entre 0 ºC y 80 ºC, preferiblemente entre 10 ºC y 60 ºC.
En la realización del procedimiento de acuerdo con la invención se parte por lo general de que el éster de lactato (I) se mezcla con uno o varios principios activos así como dado el caso con aditivos. La secuencia en la que se mezclan los componentes entre sí es discrecional.
Para la realización del procedimiento de acuerdo con la invención se pueden tener en cuenta equipos habituales, que se usan para la preparación de formulaciones agroquímicas.
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Claims (1)
-
imagen1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005042876 | 2005-09-09 | ||
| DE102005042876A DE102005042876A1 (de) | 2005-09-09 | 2005-09-09 | Verwendung von Laktatestern zur Verbesserung der Wirkung von Pflanzenschutzmitteln |
| PCT/EP2006/008513 WO2007028538A2 (de) | 2005-09-09 | 2006-08-31 | Verwendung von laktatestern zur verbesserung der wirkung von pflanzenschutzmitteln |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2544857T3 true ES2544857T3 (es) | 2015-09-04 |
Family
ID=37775641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES06791755.9T Active ES2544857T3 (es) | 2005-09-09 | 2006-08-31 | Uso de ésteres de lactato para la mejora del efecto de agentes fitosanitarios |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US20080318791A1 (es) |
| EP (1) | EP1926369B1 (es) |
| JP (1) | JP5188974B2 (es) |
| KR (1) | KR20080044898A (es) |
| CN (1) | CN101262761B (es) |
| AR (1) | AR056502A1 (es) |
| AU (1) | AU2006289348B2 (es) |
| BR (1) | BRPI0615648B1 (es) |
| CA (1) | CA2621633C (es) |
| DE (1) | DE102005042876A1 (es) |
| EA (1) | EA014782B1 (es) |
| ES (1) | ES2544857T3 (es) |
| MX (1) | MXPA08003197A (es) |
| PH (1) | PH12008500597A1 (es) |
| PL (1) | PL1926369T3 (es) |
| TW (1) | TW200731925A (es) |
| UA (1) | UA90342C2 (es) |
| WO (1) | WO2007028538A2 (es) |
| ZA (1) | ZA200802072B (es) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL148684A (en) * | 2002-03-14 | 2006-12-31 | Yoel Sasson | Pesticidal composition |
| DE102005042876A1 (de) | 2005-09-09 | 2007-03-22 | Bayer Cropscience Ag | Verwendung von Laktatestern zur Verbesserung der Wirkung von Pflanzenschutzmitteln |
| AR062587A1 (es) | 2006-08-30 | 2008-11-19 | Dow Agrosciences Llc | Composiciones agricolamente utiles |
| DE102007018983A1 (de) * | 2007-04-21 | 2008-10-23 | Cognis Ip Management Gmbh | Agrochemische Zubereitungen |
| MX2011000806A (es) * | 2008-07-24 | 2011-03-15 | Bayer Cropscience Ag | Espesante para concentrados compatibles con plantas, dispersables en agua. |
| EA020385B1 (ru) * | 2009-07-28 | 2014-10-30 | Басф Се | Пестицидные суспоэмульсионные композиции |
| US20110201500A1 (en) * | 2010-02-12 | 2011-08-18 | Basf Se | Anhydrous Composition Comprising a Dissolved and a Suspended Pesticide, Alkyl Lactate and Alcohol |
| TR201802433T4 (tr) | 2010-02-12 | 2018-03-21 | Basf Se | Çözülmüş ve süspansiyon yapılmış bir pestisit, alkillaktat ve alkol içeren susuz bir bileşim. |
| BR112012023044A2 (pt) | 2010-03-12 | 2016-08-30 | Monsanto Technology Llc | composições para saúde de planta compreendendo um pesticida solúvel em água e um agroquímico insolúvel em água. |
| BR112014001917A2 (pt) | 2011-07-26 | 2017-02-21 | Bayer Ip Gmbh | ésteres de lactato eterificados, processos para a sua produção e seu uso para melhorar o efeito de agentes para proteger plantas |
| WO2015121119A1 (en) * | 2014-02-14 | 2015-08-20 | BASF Agro B.V. | Emulsifiable concentrate comprising pesticide, alkyl lactate, and lactamide |
| US10785973B2 (en) | 2014-09-02 | 2020-09-29 | Basf Se | Aqueous pesticide microemulsion |
| AU2016378260A1 (en) * | 2015-12-22 | 2018-05-24 | Bayer Cropscience Aktiengesellschaft | Emulsion concentrates of lipophilic compounds |
| CN110235892A (zh) * | 2019-07-10 | 2019-09-17 | 四川国光农化股份有限公司 | 一种赤霉酸可溶液剂及其制备方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IE50142B1 (en) | 1979-07-11 | 1986-02-19 | Sampson Michael James | Improved method of using a plant-growth regulator |
| DE3247050A1 (de) * | 1982-12-20 | 1984-06-20 | Bayer Ag, 5090 Leverkusen | Herbizide mittel |
| US5059241A (en) * | 1983-07-06 | 1991-10-22 | Union Oil Company Of California | Plant growth regulation |
| CN1112846C (zh) * | 1993-12-28 | 2003-07-02 | 花王株式会社 | 农药增效剂组合物和农药组合物 |
| FR2721800B1 (fr) | 1994-07-01 | 1997-12-26 | Roussel Uclaf | Nouveaux concentres emulsionnables renfermant un u plussieurs pesticides |
| GB9500983D0 (en) | 1995-01-19 | 1995-03-08 | Agrevo Uk Ltd | Pesticidal compositions |
| US6165940A (en) * | 1998-09-25 | 2000-12-26 | American Cyanamid Co. | Non-aqueous suspension concentrate |
| ES2214890T3 (es) * | 1998-09-25 | 2004-09-16 | Basf Aktiengesellschaft | Concentrado no acuoso para suspensiones. |
| IL148684A (en) | 2002-03-14 | 2006-12-31 | Yoel Sasson | Pesticidal composition |
| US20040253287A1 (en) * | 2002-08-03 | 2004-12-16 | Denton Robert Michael | Environmentally safe insecticides |
| US20060199736A1 (en) * | 2002-12-16 | 2006-09-07 | Vertec Biosolvents, Inc. | Environmentally benign bioactive formulation |
| WO2005074685A1 (en) | 2004-02-06 | 2005-08-18 | Bayer Cropscience Gmbh | Plant protection compositions and use thereof |
| KR20070113281A (ko) * | 2005-03-10 | 2007-11-28 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 항미생물성 조성물 및 방법 |
| DE102005042876A1 (de) | 2005-09-09 | 2007-03-22 | Bayer Cropscience Ag | Verwendung von Laktatestern zur Verbesserung der Wirkung von Pflanzenschutzmitteln |
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2005
- 2005-09-09 DE DE102005042876A patent/DE102005042876A1/de not_active Withdrawn
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2006
- 2006-08-31 AU AU2006289348A patent/AU2006289348B2/en not_active Ceased
- 2006-08-31 KR KR1020087007966A patent/KR20080044898A/ko active IP Right Grant
- 2006-08-31 ES ES06791755.9T patent/ES2544857T3/es active Active
- 2006-08-31 JP JP2008529514A patent/JP5188974B2/ja active Active
- 2006-08-31 CN CN2006800331972A patent/CN101262761B/zh active Active
- 2006-08-31 UA UAA200804511A patent/UA90342C2/ru unknown
- 2006-08-31 EA EA200800777A patent/EA014782B1/ru not_active IP Right Cessation
- 2006-08-31 PL PL06791755T patent/PL1926369T3/pl unknown
- 2006-08-31 EP EP06791755.9A patent/EP1926369B1/de not_active Revoked
- 2006-08-31 US US12/066,040 patent/US20080318791A1/en not_active Abandoned
- 2006-08-31 CA CA2621633A patent/CA2621633C/en not_active Expired - Fee Related
- 2006-08-31 MX MX2008003197A patent/MXPA08003197A/es active IP Right Grant
- 2006-08-31 BR BRPI0615648A patent/BRPI0615648B1/pt active IP Right Grant
- 2006-08-31 WO PCT/EP2006/008513 patent/WO2007028538A2/de active Application Filing
- 2006-09-07 AR ARP060103896A patent/AR056502A1/es not_active Application Discontinuation
- 2006-09-08 TW TW095133130A patent/TW200731925A/zh unknown
-
2008
- 2008-03-05 ZA ZA200802072A patent/ZA200802072B/xx unknown
- 2008-03-07 PH PH12008500597A patent/PH12008500597A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA08003197A (es) | 2008-03-19 |
| EA200800777A1 (ru) | 2008-10-30 |
| US20080318791A1 (en) | 2008-12-25 |
| WO2007028538A2 (de) | 2007-03-15 |
| CA2621633A1 (en) | 2007-03-15 |
| AU2006289348A1 (en) | 2007-03-15 |
| BRPI0615648B1 (pt) | 2016-07-12 |
| UA90342C2 (ru) | 2010-04-26 |
| JP2009507799A (ja) | 2009-02-26 |
| DE102005042876A1 (de) | 2007-03-22 |
| MX290705B (es) | 2011-10-04 |
| EP1926369B1 (de) | 2015-06-17 |
| CA2621633C (en) | 2015-01-06 |
| KR20080044898A (ko) | 2008-05-21 |
| WO2007028538A3 (de) | 2007-05-31 |
| EA014782B1 (ru) | 2011-02-28 |
| CN101262761A (zh) | 2008-09-10 |
| TW200731925A (en) | 2007-09-01 |
| AR056502A1 (es) | 2007-10-10 |
| JP5188974B2 (ja) | 2013-04-24 |
| ZA200802072B (en) | 2009-08-26 |
| PH12008500597A1 (en) | 2013-01-28 |
| AU2006289348B2 (en) | 2011-04-21 |
| CN101262761B (zh) | 2012-02-29 |
| EP1926369A2 (de) | 2008-06-04 |
| BRPI0615648A2 (pt) | 2011-05-24 |
| PL1926369T3 (pl) | 2015-11-30 |
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