ES2524617T3 - Composición de moldeo termoplástica retardante a la llama y resistente al impacto - Google Patents

Composición de moldeo termoplástica retardante a la llama y resistente al impacto Download PDF

Info

Publication number
ES2524617T3
ES2524617T3 ES07873445.6T ES07873445T ES2524617T3 ES 2524617 T3 ES2524617 T3 ES 2524617T3 ES 07873445 T ES07873445 T ES 07873445T ES 2524617 T3 ES2524617 T3 ES 2524617T3
Authority
ES
Spain
Prior art keywords
parts
phr
weight
methacrylate
crust
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES07873445.6T
Other languages
English (en)
Inventor
Xiangyang Li
James P. Mason
Marty Boykin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro LLC
Original Assignee
Bayer MaterialScience LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience LLC filed Critical Bayer MaterialScience LLC
Application granted granted Critical
Publication of ES2524617T3 publication Critical patent/ES2524617T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18—Homopolymers or copolymers or tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C08L69/005—Polyester-carbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Una composición de moldeo termoplástica que comprende A) de 70 a 99 partes en peso de policarbonato aromático y/o poliéster carbonato aromático, B) de 1 a 30 partes en peso de poli(tereftalato de alquileno), en la que el peso de A) y B) suman 100 partes de resina, y C) de 5 a 12 partes por cien partes de resina (phr) de polímero o copolímero de injerto que tiene una morfología núcleo-corteza, que incluye una corteza injertada que contiene acrilato o metacrilato de alquilo polimerizado y un núcleo de un caucho compuesto que contiene componentes de poliorganosiloxano y poli(metacrilato o acrilato de alquilo) interpenetrados e inseparables, en el que dicho núcleo está en forma de partículas que tienen un tamaño medio de partícula de 0,05 a 5 micrómetros y una temperatura de transición vítrea por debajo de 0 °C, y en el que la relación en peso de polisiloxano/metacrilato o acrilato de alquilo/ corteza rígida es 70-90/5-15/5-15. D) de 2 a 20 phr de un compuesto que contiene fósforo, y E) de 0,1 a 2 phr de poliolefina fluorada.

Description

imagen1
imagen2
imagen3
imagen4
imagen5
imagen6
imagen7
imagen8
E07873445
24-11-2014
imagen9
Todas las composiciones ejemplo contenían 0,25 phr de poliolefina fluorada (PTFE) introducida en forma de un lote maestro que contenía un 50 % p/p de copolímero estireno-acrilonitrilo y un 50 % p/p de PTFE.
La resistencia al impacto con muesca (NI) a la temperatura indicada se determinó de acuerdo con ASTM D256 5 usando probetas de 1/8" (3,175 mm) de espesor. El modo de fallo (modo) se determinó por observación, P significa rotura parcial, C significa rotura completa.
El índice de inflamabilidad se determinó de acuerdo con UL-94 V en probetas que tenían el espesor indicado
Los índices de fluidez del fundido (MFR) de las composiciones se determinaron de acuerdo con ASTM D-1238 a 265 °C, 5 Kg de carga. La temperatura Vicat (Vicat) se determinó de acuerdo con ASTM D 1525 con una carga de 50 10 Newton y una velocidad de calentamiento de 120 °C/hora.
Tabla 1
Ejemplo
1 2 3 4 5
Policarbonato, p/p
85 85 85 85 85
PET, p/p,
15 15 15 15 15
Elastómero 2, phr
10 0 0 0 0
Elastómero 1, phr
10 6 10 6
Compuesto P, phr
10 10 10 6 6
PTFE, phr
0,25 0,25 0,25 0,25 0,25
Propiedades
MFR, g/10 min
18,9 15,1 15,7 12,5 12,2
NI a 23 °C/modo, ftlb/in (kg-cm/cm)
18,5/P(1) (100,64) 18,5/P (100,64) 19,6/P (106,62) 19,6/P (106,62) 20,4/P (110,98)
NI a 20 °C/modo, ftlb/in (kg-cm/cm)
2,1/C(2) (11,42) 8,0/P (43,52) 1,6/C (8,7) 8,9/P (48,42) 8,9/P (48,42)
Vicat, °C
109,4 108,1 110,7 118,4 121,0
Inflamabilidad,UL94 1,6 mm
V-2 V-1 V-1 V-1 V-1
(1)-P indica rotura parcial (2)-C indica rotura completa
Los ejemplos 1 (comparativo) y 2 (inventivo) permiten una comparación directa de la composición de la invención con composiciones estrechamente relacionadas. La diferencia entre estas composiciones es la estructura del 15 elastómero incluido. Los resultados muestran mayor ductilidad y la ventajosa resistencia al impacto a baja temperatura de la composición de la invención. Los resultados también muestran que la inclusión de un compuesto P y la poliolefina fluorada imparte una mejor resistencia a la llama (UL-94 a 1,6 mm) a la composición de la invención (V-1). El ejemplo 3 muestra que con una carga menor del modificador de caucho, la composición de la invención mantiene su buena resistencia al impacto Izod con muesca a temperatura ambiente y a -20 °C con un mejor índice 20 UL-94 (V-1). El ejemplo 4 muestra que, incluso con una carga menor de compuesto P, la composición de la
10
imagen10

Claims (1)

  1. imagen1
ES07873445.6T 2006-10-13 2007-10-10 Composición de moldeo termoplástica retardante a la llama y resistente al impacto Active ES2524617T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/580,502 US9127154B2 (en) 2006-10-13 2006-10-13 Impact resistant, flame retardant thermoplastic molding composition
US580502 2006-10-13
PCT/US2007/021665 WO2008127286A2 (en) 2006-10-13 2007-10-10 Impact resistant, flame retardant thermoplastic molding composition

Publications (1)

Publication Number Publication Date
ES2524617T3 true ES2524617T3 (es) 2014-12-10

Family

ID=39303833

Family Applications (1)

Application Number Title Priority Date Filing Date
ES07873445.6T Active ES2524617T3 (es) 2006-10-13 2007-10-10 Composición de moldeo termoplástica retardante a la llama y resistente al impacto

Country Status (12)

Country Link
US (1) US9127154B2 (es)
EP (1) EP2074177B1 (es)
JP (1) JP5237953B2 (es)
KR (1) KR101516437B1 (es)
CN (2) CN103740074B (es)
BR (1) BRPI0717825A2 (es)
CA (1) CA2665249C (es)
ES (1) ES2524617T3 (es)
MX (1) MX2009003561A (es)
RU (1) RU2448993C2 (es)
TW (1) TWI417341B (es)
WO (1) WO2008127286A2 (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8584885B2 (en) * 2006-07-07 2013-11-19 Covidien Lp Mailbox style sharps container
WO2010100936A1 (ja) 2009-03-04 2010-09-10 株式会社日本触媒 吸水性樹脂の製造方法
TW201137033A (en) 2010-03-02 2011-11-01 Styron Europe Gmbh Improved flow ignition resistant carbonate polymer composition
TWI521051B (zh) 2010-03-11 2016-02-11 盛禧奧歐洲有限責任公司 經衝擊改質之抗引燃性碳酸酯聚合物組成物
EP2377899A1 (en) 2010-04-14 2011-10-19 Styron Europe GmbH Carbonate blend compostion having improved resistance to environmental stress cracking
CN103797070B (zh) 2011-06-28 2016-08-24 住化斯泰隆Pc有限公司 聚碳酸酯树脂组合物
EP2554597B1 (en) 2011-08-02 2014-12-31 Styron Europe GmbH Chemical resistant and fire retardant polycarbonate polyester composition
US10017640B2 (en) * 2013-03-08 2018-07-10 Covestro Llc Halogen free flame retarded polycarbonate
US9856406B2 (en) 2013-03-11 2018-01-02 Covestro Llc Flame retardant polycarbonate
WO2014164097A1 (en) * 2013-03-12 2014-10-09 Bayer Materialscience Llc Polycarbonate blend with law smoke generation
EP3401070B1 (en) 2013-08-28 2021-04-21 Nippon Shokubai Co., Ltd. Water absorbent resin powder comprising polyacrylic acid (salt)-based water absorbent resin
KR102297640B1 (ko) 2013-08-28 2021-09-06 가부시키가이샤 닛폰 쇼쿠바이 겔 분쇄 장치, 폴리아크릴산(염)계 흡수성 수지 분말의 제조 방법, 및 흡수성 수지 분말
WO2015116509A1 (en) * 2014-01-28 2015-08-06 Sabic Global Technologies B.V. Halogen free flame retardant polycarbonate/thermoplastic polyester molding compositions with polymeric phosphorus flame retardant
WO2016104201A1 (ja) * 2014-12-26 2016-06-30 ウィンテックポリマー株式会社 ポリアルキレンテレフタレート樹脂組成物
US10240036B2 (en) * 2015-04-30 2019-03-26 Samsung Electronics Co., Ltd. Polymer composition, molded article, and method of manufacturing the molded article
KR101933758B1 (ko) * 2016-06-03 2018-12-28 롯데첨단소재(주) 난연성 수지 조성물 및 이로부터 제조된 성형품
CN109206922A (zh) * 2017-07-04 2019-01-15 镇江市睿泽文化传播有限公司 一种耐冲击树脂塑料
CN109206921A (zh) * 2017-07-04 2019-01-15 镇江市睿泽文化传播有限公司 一种抗氧化树脂塑料
CN109206923A (zh) * 2017-07-04 2019-01-15 镇江市睿泽文化传播有限公司 一种阻燃型树脂塑料
EP3546520A1 (en) 2018-03-28 2019-10-02 SABIC Global Technologies B.V. Impact modified polyestercarbonate-polysiloxane composition and associated article and additive manufacturing method
EP3771723A1 (en) 2019-07-31 2021-02-03 SHPP Global Technologies B.V. Additive manufacturing article and method
EP3828236B1 (de) 2019-11-27 2022-06-01 Covestro Intellectual Property GmbH & Co. KG Flammgeschützter polycarbonat-polyester blend
CN114981357B (zh) * 2020-01-27 2023-05-16 三菱工程塑料株式会社 聚对苯二甲酸丁二醇酯树脂组合物及成形体
CN114085495A (zh) * 2021-10-15 2022-02-25 南京聚隆科技股份有限公司 一种玻纤增强pbt材料及其制备方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1321431C (en) 1987-09-21 1993-08-17 Masafumi Hongo Polycarbonate resin composition
DE3737637A1 (de) 1987-11-06 1989-05-18 Bayer Ag Mischungen von polycarbonaten mit siloxanhaltigen pfropfpolymerisaten
JPH04345657A (ja) 1991-05-23 1992-12-01 Mitsubishi Kasei Corp 難燃性ポリカーボネート樹脂組成物
JP3841312B2 (ja) 1994-05-27 2006-11-01 三菱レイヨン株式会社 難燃性樹脂組成物
JPH08259791A (ja) 1995-01-23 1996-10-08 Mitsubishi Rayon Co Ltd 難燃性樹脂組成物
TWI234574B (en) 1997-05-06 2005-06-21 Idemitsu Kosan Co Battery pack obtained from a flame-retardant polycarbonate resin composition
JP3471225B2 (ja) 1998-06-29 2003-12-02 三菱レイヨン株式会社 難燃性熱可塑性樹脂組成物
JP2000034397A (ja) * 1998-07-21 2000-02-02 Kanegafuchi Chem Ind Co Ltd 難燃性熱可塑性樹脂組成物
JP3432434B2 (ja) 1998-11-12 2003-08-04 出光石油化学株式会社 難燃性ポリカーボネート樹脂組成物及び成形品
US6562887B1 (en) * 1999-02-26 2003-05-13 Mitsubishi Engineering-Plastics Corporation Polycarbonate resin composition
JP2000336420A (ja) * 1999-05-26 2000-12-05 Kawasaki Steel Corp 金属の製・精錬未燃ガスを利用した、アルミ残灰処理ガスの分解回収方法
JP2001031860A (ja) 1999-07-23 2001-02-06 Teijin Chem Ltd 難燃性熱可塑性樹脂組成物および該組成物から形成されてなる印刷機器の内部機構部品
JP4778601B2 (ja) * 2000-03-27 2011-09-21 出光興産株式会社 難燃性ポリカーボネート樹脂組成物および成形品
DE10100591A1 (de) * 2001-01-09 2002-07-11 Bayer Ag Phosphorhaltiges Flammschutzmittel und Flammwidrige thermoplastische Formmassen
TWI317749B (en) 2002-02-15 2009-12-01 Kaneka Corp Graft copolymers and impact-resistant flame-retardant resin compositions containing the same
US7091267B2 (en) * 2002-03-19 2006-08-15 General Electric Company Resinous compositions, method of manufacture thereof and articles fabricated from the composition
DE10234420A1 (de) * 2002-07-29 2004-02-12 Bayer Ag Schlagzähmodifizierte Polycarbonat Blends
EP1527138B1 (de) 2002-07-29 2007-09-26 Bayer MaterialScience AG Flammwidrige polycarbonat-formmassen
JP2005179597A (ja) * 2003-12-22 2005-07-07 Sekisui Chem Co Ltd 不燃性シート材料
US7226956B2 (en) * 2004-06-30 2007-06-05 Gary Richard Wilkes Low density polymeric foam using a three-polymer blend
US8217101B2 (en) * 2007-03-02 2012-07-10 Bayer Materialscience Llc Flame retardant thermoplastic molding composition
DE102008062945A1 (de) * 2008-12-23 2010-06-24 Bayer Materialscience Ag Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen

Also Published As

Publication number Publication date
KR101516437B1 (ko) 2015-05-07
CA2665249A1 (en) 2008-10-23
TWI417341B (zh) 2013-12-01
WO2008127286A3 (en) 2008-12-31
JP2010506963A (ja) 2010-03-04
RU2009117696A (ru) 2010-11-20
MX2009003561A (es) 2009-05-11
US9127154B2 (en) 2015-09-08
CN103740074A (zh) 2014-04-23
EP2074177A2 (en) 2009-07-01
CA2665249C (en) 2015-12-08
CN103740074B (zh) 2016-10-05
JP5237953B2 (ja) 2013-07-17
TW200838930A (en) 2008-10-01
EP2074177B1 (en) 2014-10-01
RU2448993C2 (ru) 2012-04-27
BRPI0717825A2 (pt) 2014-04-15
KR20090064574A (ko) 2009-06-19
US20080090961A1 (en) 2008-04-17
WO2008127286A2 (en) 2008-10-23
CN101522803A (zh) 2009-09-02

Similar Documents

Publication Publication Date Title
ES2524617T3 (es) Composición de moldeo termoplástica retardante a la llama y resistente al impacto
TWI492987B (zh) 非鹵素阻燃劑及高硬度聚碳酸酯樹脂組成物
KR101340539B1 (ko) 표면 특성이 우수한 고광택 고충격 폴리카보네이트계 수지 조성물 및 이를 이용한 성형품
KR101297160B1 (ko) 폴리카보네이트 수지 조성물　및 이를 이용한 성형품
JP4990965B2 (ja) 耐スクラッチ性−難燃性の熱可塑性樹脂組成物
KR101309808B1 (ko) 내스크래치성과 내충격성이 우수한 난연 폴리카보네이트 수지 조성물 및 이를 이용한 성형품
US9631087B2 (en) Thermoplastic resin composition and molded products thereof
US20180355177A1 (en) Preparation method for polycarbonate resin composition
KR101351614B1 (ko) 난연 내스크래치성 폴리카보네이트 수지 조성물
WO2003072620A1 (fr) Composition de resine thermoplastique et composition de matieres plastiques d'ingenierie
US10066038B2 (en) Polycarbonate-based thermoplastic resin composition and product using same
KR20180081834A (ko) 보강된 난연제 폴리카보네이트 조성물 및 이를 포함하는 성형 물품
KR20170084296A (ko) 보강된 폴리카보네이트 조성물
KR101411004B1 (ko) 아크릴계 공중합체 수지 조성물
US20160319126A1 (en) Reinforced Thermoplastic Resin Composition And Molded Article Thereof
US9803083B2 (en) Reinforced thermoplastic resin composition and molding
KR101447273B1 (ko) 내스크래치성 폴리카보네이트계 수지 조성물 및 그 성형품
BR112012014934A2 (pt) composições de moldagem de policarbonato resistentes a riscos e resistentes ao impacto com boas propriedades mecânicas i
JP5805949B2 (ja) ポリオルガノシロキサン含有グラフト共重合体からなる流動性改良剤、及びこれを用いた樹脂の流動性を高める方法
JP2006348098A (ja) 鉛蓄電池ケーシング用樹脂組成物
KR100582420B1 (ko) 비할로겐 난연성 폴리카보네이트 수지 조성물
JP2002194100A (ja) （半）透明難燃性薄肉樹脂成形品およびその用途
KR20120100516A (ko) 우수한 난연성, 광특성 및 내열성을 가지는 폴리카보네이트 수지 조성물
JP2006306958A (ja) 芳香族ポリカーボネート系樹脂用流動性向上剤、芳香族ポリカーボネート系樹脂組成物およびその成形品
JP6730028B2 (ja) 白色樹脂組成物及び成形体