ES2495748T3 - Procedimiento de control de productos pesados en una corriente de reciclado de catalizador - Google Patents
Procedimiento de control de productos pesados en una corriente de reciclado de catalizador Download PDFInfo
- Publication number
- ES2495748T3 ES2495748T3 ES09774522.8T ES09774522T ES2495748T3 ES 2495748 T3 ES2495748 T3 ES 2495748T3 ES 09774522 T ES09774522 T ES 09774522T ES 2495748 T3 ES2495748 T3 ES 2495748T3
- Authority
- ES
- Spain
- Prior art keywords
- products
- stream
- rectification column
- head gas
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- 239000000047 product Substances 0.000 abstract 10
- 239000006227 byproduct Substances 0.000 abstract 3
- 239000003153 chemical reaction reagent Substances 0.000 abstract 3
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 150000008301 phosphite esters Chemical class 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
- B01D1/22—Evaporating by bringing a thin layer of the liquid into contact with a heated surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7804608P | 2008-07-03 | 2008-07-03 | |
| US78046P | 2008-07-03 | ||
| PCT/US2009/049540 WO2010003073A1 (en) | 2008-07-03 | 2009-07-02 | Process of controlling heavies in a recycle catalyst stream |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2495748T3 true ES2495748T3 (es) | 2014-09-17 |
Family
ID=41128560
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13184322.9T Active ES2558465T3 (es) | 2008-07-03 | 2009-07-02 | Procedimiento de tratamiento de una descarga de hidroformilación |
| ES09774522.8T Active ES2495748T3 (es) | 2008-07-03 | 2009-07-02 | Procedimiento de control de productos pesados en una corriente de reciclado de catalizador |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13184322.9T Active ES2558465T3 (es) | 2008-07-03 | 2009-07-02 | Procedimiento de tratamiento de una descarga de hidroformilación |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8404903B2 (enExample) |
| EP (2) | EP2297077B1 (enExample) |
| JP (1) | JP5587877B2 (enExample) |
| KR (1) | KR101629043B1 (enExample) |
| CN (1) | CN102143933B (enExample) |
| CA (1) | CA2729643C (enExample) |
| ES (2) | ES2558465T3 (enExample) |
| MX (1) | MX2010014570A (enExample) |
| MY (1) | MY155290A (enExample) |
| PL (2) | PL2703380T3 (enExample) |
| WO (1) | WO2010003073A1 (enExample) |
| ZA (1) | ZA201100027B (enExample) |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101310552B1 (ko) | 2010-04-20 | 2013-09-23 | 주식회사 엘지화학 | 올레핀의 하이드로포르밀화에 의한 알데히드 제조 방법 |
| WO2014056736A1 (de) * | 2012-10-12 | 2014-04-17 | Evonik Degussa Gmbh | Gemisch von bisphosphiten und dessen verwendung als katalysatorgemisch in der hydroformylierung |
| EP2740535A1 (en) | 2012-12-04 | 2014-06-11 | Dow Technology Investments LLC | Bidentate ligands for hydroformylation of ethylene |
| US9382180B2 (en) * | 2012-12-06 | 2016-07-05 | Dow Technology Investments Llc | Hydroformylation process |
| DE102012223572A1 (de) | 2012-12-18 | 2014-06-18 | Evonik Industries Ag | Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren |
| CN104725170B (zh) * | 2013-12-19 | 2019-08-23 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
| CN106103399B (zh) | 2013-12-19 | 2019-07-09 | 陶氏技术投资有限责任公司 | 氢甲酰化方法 |
| MY184826A (en) * | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| EP3374340B1 (en) * | 2015-11-10 | 2021-12-29 | Dow Technology Investments LLC | Process for producing aldehydes |
| CA3014177C (en) | 2016-02-11 | 2023-12-12 | Dow Technology Investments Llc | Processes for converting olefins to alcohols, ethers, or combinations thereof |
| CN107141204B (zh) * | 2016-03-01 | 2022-03-15 | 陶氏技术投资有限责任公司 | 氢甲酰化工艺 |
| RU2724349C2 (ru) * | 2016-03-18 | 2020-06-23 | Дау Текнолоджи Инвестментс Ллк | Способ гидроформилирования |
| TW201840363A (zh) | 2016-11-08 | 2018-11-16 | 美商陶氏科技投資有限公司 | 處理氫甲醯化催化劑溶液之方法 |
| TW201840362A (zh) | 2016-11-08 | 2018-11-16 | 美商陶氏科技投資有限公司 | 使去活化的氫甲醯化催化劑溶液再生的方法 |
| TWI758353B (zh) | 2016-11-08 | 2022-03-21 | 美商陶氏科技投資有限公司 | 使去活化的氫甲醯化催化劑溶液再生的方法 |
| TWI788364B (zh) | 2017-06-23 | 2023-01-01 | 美商陶氏科技投資有限公司 | 氫甲醯化反應製程 |
| US11214533B2 (en) | 2017-06-28 | 2022-01-04 | Dow Global Technologies Llc | Readily biodegradable alkoxylate mixtures |
| CN107469860B (zh) * | 2017-08-22 | 2020-05-19 | 中国海洋石油集团有限公司 | 一种提高铑/双亚膦酸酯催化剂稳定性的方法 |
| TWI793216B (zh) | 2017-12-07 | 2023-02-21 | 美商陶氏科技投資公司 | 氫甲醯化方法 |
| CN112055614A (zh) | 2018-05-30 | 2020-12-08 | 陶氏技术投资有限责任公司 | 包括单膦、四膦配位体的组合的催化剂组合物和使用其的加氢甲酰化过程 |
| MX2020011380A (es) | 2018-05-30 | 2020-11-24 | Dow Technology Investments Llc | Metodos de control de procesos de hidroformilacion. |
| KR20210013702A (ko) | 2018-05-30 | 2021-02-05 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 하이드로포밀화 공정에서 촉매의 탈활성화를 느리게 하고/하거나 테트라포스핀 리간드 사용을 느리게 하는 방법 |
| JP7447116B2 (ja) * | 2018-11-29 | 2024-03-11 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセス |
| GB201907659D0 (en) * | 2019-05-30 | 2019-07-17 | Johnson Matthey Davy Technologies Ltd | Process |
| KR102489172B1 (ko) | 2019-07-04 | 2023-01-18 | 주식회사 엘지화학 | 디에스터계 물질의 제조 유닛 및 이를 포함하는 디에스터계 물질의 제조 시스템 |
| KR102489171B1 (ko) | 2019-07-04 | 2023-01-18 | 주식회사 엘지화학 | 디에스터계 물질의 제조 유닛 및 이를 포함하는 디에스터계 물질의 제조 시스템 |
| CN112441892B (zh) * | 2019-08-30 | 2023-03-14 | 中国石油化工股份有限公司 | 来自混合丁烯烃氢甲酰化反应装置的液相物流的分离方法和装置 |
| CN114929660A (zh) | 2019-12-19 | 2022-08-19 | 陶氏技术投资有限责任公司 | 用于制备异戊二烯和包含至少六个碳原子的单烯烃的方法 |
| GB202012930D0 (en) | 2020-08-19 | 2020-09-30 | Johnson Matthey Davy Technologies Ltd | Process for hydroformylation with removal of dissolved hydrogen |
| EP4008711B1 (en) * | 2020-09-17 | 2024-10-02 | Lg Chem, Ltd. | Aldehyde preparation method and aldehyde preparation apparatus |
| CN112403401B (zh) * | 2020-11-06 | 2022-06-21 | 中国海洋石油集团有限公司 | 一种烯烃氢甲酰化制醛中醛和催化剂分离的装置和方法 |
| CA3201268A1 (en) | 2020-12-14 | 2022-06-23 | Michael A. Brammer | Processes to improve catalytic metal accountability in hydroformylation processes |
| GB202102673D0 (en) * | 2021-02-25 | 2021-04-14 | Johnson Matthey Davy Technologies Ltd | Process |
| JP2024543330A (ja) | 2021-11-11 | 2024-11-21 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセスからロジウムを回収するためのプロセス |
| JP2024545133A (ja) | 2021-12-16 | 2024-12-05 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 化合物、そのような化合物を含む遷移金属錯体ヒドロホルミル化触媒前駆体組成物、及びヒドロホルミル化プロセス |
| WO2023114578A1 (en) | 2021-12-16 | 2023-06-22 | Dow Technology Investments Llc | Transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes |
| CN114773172B (zh) * | 2022-06-20 | 2022-10-18 | 中海油天津化工研究设计院有限公司 | 一种烯烃氢甲酰化制醛工艺优化方法 |
| EP4630394A1 (en) * | 2022-12-06 | 2025-10-15 | Dow Technology Investments LLC | Process of controlling heavies in a recycle catalyst stream |
| CN120282943A (zh) | 2022-12-13 | 2025-07-08 | 陶氏技术投资有限责任公司 | 通过利用降解产物使多膦使用最小化的方法 |
| WO2025006020A1 (en) | 2023-06-26 | 2025-01-02 | Dow Technology Investments Llc | Methods of controlling hydroformylation processes |
| WO2025029349A1 (en) | 2023-08-03 | 2025-02-06 | Dow Technology Investments Llc | Hydroformylation process |
| WO2025029369A1 (en) | 2023-08-03 | 2025-02-06 | Dow Technology Investments Llc | Process for improving rhodium/phosphite- based homogenous hydroformylation catalyst activity |
| CN119925959B (zh) * | 2023-11-03 | 2025-10-31 | 中国石油化工股份有限公司 | 一种羰基合成催化剂与羰基合成产物的分离系统、分离方法及应用 |
| CN119925960B (zh) * | 2023-11-03 | 2025-10-31 | 中国石油化工股份有限公司 | 一种羰基合成催化剂的回收系统、回收方法及应用 |
Family Cites Families (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3415906A (en) | 1964-05-29 | 1968-12-10 | Hooker Chemical Corp | Phosphite phospholane and phosphorinane compounds |
| US3527809A (en) | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
| US4148830A (en) | 1975-03-07 | 1979-04-10 | Union Carbide Corporation | Hydroformylation of olefins |
| US4166773A (en) * | 1977-12-22 | 1979-09-04 | Union Carbide Corporation | Continuous process for separating high boiling, heat sensitive materials |
| DE2965158D1 (en) | 1979-03-21 | 1983-05-11 | Davy Mckee London | Hydroformylation process |
| NO156742C (no) | 1979-03-28 | 1987-11-18 | Union Carbide Corp | Fremgangsmaate for fremstilling av et hydroformyleringsmedium, og fremgangsmaate for fremstilling av aldehyder. |
| GB8334359D0 (en) | 1983-12-23 | 1984-02-01 | Davy Mckee Ltd | Process |
| US4599206A (en) | 1984-02-17 | 1986-07-08 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| US4789753A (en) | 1984-02-17 | 1988-12-06 | Union Carbide Corporation | Phosphite ligands |
| US4567302A (en) | 1984-07-20 | 1986-01-28 | Angus Chemical | Polymeric quaternary ammonium salts possessing antimicrobial activity and methods for preparation and use thereof |
| US4737588A (en) | 1984-12-28 | 1988-04-12 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| US4668651A (en) | 1985-09-05 | 1987-05-26 | Union Carbide Corporation | Transition metal complex catalyzed processes |
| US4885401A (en) | 1985-09-05 | 1989-12-05 | Union Carbide Corporation | Bis-phosphite compounds |
| US4748261A (en) | 1985-09-05 | 1988-05-31 | Union Carbide Corporation | Bis-phosphite compounds |
| US4774361A (en) | 1986-05-20 | 1988-09-27 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| US4835299A (en) | 1987-03-31 | 1989-05-30 | Union Carbide Corporation | Process for purifying tertiary organophosphites |
| US5059710A (en) | 1988-08-05 | 1991-10-22 | Union Carbide Chemicals And Plastics Technology Corporation | Ionic phosphites and their use in homogeneous transition metal catalyzed processes |
| US5113022A (en) | 1988-08-05 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Ionic phosphites used in homogeneous transition metal catalyzed processes |
| US5114473A (en) | 1988-08-25 | 1992-05-19 | Union Carbide Chemicals And Plastics Technology Corporation | Transition metal recovery |
| US5001274A (en) * | 1989-06-23 | 1991-03-19 | Union Carbide Chemicals And Plastics Company Inc. | Hydroformylation process |
| US5277532A (en) | 1989-07-31 | 1994-01-11 | Cefin S.P.A. | Mechanical acceleration device in can welding machines |
| US5210318A (en) | 1990-05-04 | 1993-05-11 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes |
| DE4026406A1 (de) | 1990-08-21 | 1992-02-27 | Basf Ag | Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden |
| US5179055A (en) | 1990-09-24 | 1993-01-12 | New York University | Cationic rhodium bis(dioxaphosphorus heterocycle) complexes and their use in the branched product regioselective hydroformylation of olefins |
| US5087763A (en) | 1990-11-09 | 1992-02-11 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process |
| TW213465B (enExample) | 1991-06-11 | 1993-09-21 | Mitsubishi Chemicals Co Ltd | |
| DE4204808A1 (de) | 1992-02-18 | 1993-08-19 | Basf Ag | Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern |
| US5312996A (en) | 1992-06-29 | 1994-05-17 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process for producing 1,6-hexanedials |
| US5364950A (en) | 1992-09-29 | 1994-11-15 | Union Carbide Chimicals & Plastics Technology Corporation | Process for stabilizing phosphite ligands in hydroformylation reaction mixtures |
| US5463137A (en) * | 1993-09-30 | 1995-10-31 | The Boc Group, Inc. | Process for the production of oxo products |
| DE19530698A1 (de) * | 1995-08-21 | 1997-02-27 | Basf Ag | Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrags |
| US5874640A (en) | 1996-11-26 | 1999-02-23 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| US5892119A (en) | 1996-11-26 | 1999-04-06 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| US6090987A (en) | 1998-07-06 | 2000-07-18 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| DE19913352A1 (de) | 1999-03-24 | 2000-09-28 | Basf Ag | Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines Phospinamiditliganden |
| DE10006489A1 (de) * | 2000-02-14 | 2001-08-16 | Basf Ag | Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrages |
| US6294700B1 (en) | 2000-03-15 | 2001-09-25 | Union Carbide Chemicals & Plastics Technology Corporation | Separation processes |
| DE10031520A1 (de) * | 2000-06-28 | 2002-01-10 | Basf Ag | Verfahren zur Hydroformylierung von Olefinen mit 2 bis 8 Kohlenstoffatomen |
| DE10031519A1 (de) * | 2000-06-28 | 2002-01-10 | Basf Ag | Verfahren zur Hydroformylierung von Olefinen mit 2 bis 8 Kohlenstoffatomen, I |
| BRPI0411948B1 (pt) | 2003-07-03 | 2014-03-25 | Dow Technology Investments Llc | Método para minimizar a produção de um ou mais produtos de degradação de ligantes de íons fosfônio e processo para minimizar a formação de um ou mais produtos de degradação de ligantes de íons fosfônio |
| CN100526279C (zh) * | 2006-04-11 | 2009-08-12 | 中国科学院兰州化学物理研究所 | 连续制备正戊醛的工艺过程 |
-
2009
- 2009-07-02 PL PL13184322T patent/PL2703380T3/pl unknown
- 2009-07-02 ES ES13184322.9T patent/ES2558465T3/es active Active
- 2009-07-02 EP EP09774522.8A patent/EP2297077B1/en active Active
- 2009-07-02 MX MX2010014570A patent/MX2010014570A/es active IP Right Grant
- 2009-07-02 MY MYPI2010006276A patent/MY155290A/en unknown
- 2009-07-02 PL PL09774522T patent/PL2297077T3/pl unknown
- 2009-07-02 EP EP13184322.9A patent/EP2703380B1/en active Active
- 2009-07-02 CN CN200980134089.8A patent/CN102143933B/zh active Active
- 2009-07-02 JP JP2011516877A patent/JP5587877B2/ja not_active Expired - Fee Related
- 2009-07-02 KR KR1020117002619A patent/KR101629043B1/ko not_active Expired - Fee Related
- 2009-07-02 WO PCT/US2009/049540 patent/WO2010003073A1/en not_active Ceased
- 2009-07-02 ES ES09774522.8T patent/ES2495748T3/es active Active
- 2009-07-02 US US13/002,078 patent/US8404903B2/en active Active
- 2009-07-02 CA CA2729643A patent/CA2729643C/en not_active Expired - Fee Related
-
2011
- 2011-01-03 ZA ZA2011/00027A patent/ZA201100027B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN102143933B (zh) | 2014-09-17 |
| WO2010003073A1 (en) | 2010-01-07 |
| US20110269997A1 (en) | 2011-11-03 |
| CA2729643C (en) | 2016-08-16 |
| EP2297077A1 (en) | 2011-03-23 |
| JP5587877B2 (ja) | 2014-09-10 |
| PL2703380T3 (pl) | 2016-05-31 |
| PL2297077T3 (pl) | 2014-11-28 |
| EP2297077B1 (en) | 2014-06-04 |
| EP2703380B1 (en) | 2015-11-04 |
| MY155290A (en) | 2015-09-30 |
| ES2558465T3 (es) | 2016-02-04 |
| EP2703380A1 (en) | 2014-03-05 |
| KR20110047189A (ko) | 2011-05-06 |
| CA2729643A1 (en) | 2010-01-07 |
| ZA201100027B (en) | 2012-08-29 |
| KR101629043B1 (ko) | 2016-06-09 |
| MX2010014570A (es) | 2011-08-15 |
| JP2011527287A (ja) | 2011-10-27 |
| US8404903B2 (en) | 2013-03-26 |
| CN102143933A (zh) | 2011-08-03 |
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