ES2422297T3 - Proceso para la sulfinilación de un derivado de pirazol - Google Patents

Proceso para la sulfinilación de un derivado de pirazol

Info

Publication number
ES2422297T3
ES2422297T3 ES07822223T ES07822223T ES2422297T3 ES 2422297 T3 ES2422297 T3 ES 2422297T3 ES 07822223 T ES07822223 T ES 07822223T ES 07822223 T ES07822223 T ES 07822223T ES 2422297 T3 ES2422297 T3 ES 2422297T3
Authority
ES
Spain
Prior art keywords
acid
dimethylbenzenesulfonic
sulfinylation
cf3s
amines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES07822223T
Other languages
English (en)
Inventor
Martin Sukopp
Oliver Kuhn
Carsten Groening
Michael Keil
Jon J Longlet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Agro BV Arnhem NL Zweigniederlassung Freienbach
BASF SE
Original Assignee
BASF Agro BV Arnhem NL Zweigniederlassung Zuerich
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Agro BV Arnhem NL Zweigniederlassung Zuerich, BASF SE filed Critical BASF Agro BV Arnhem NL Zweigniederlassung Zuerich
Application granted granted Critical
Publication of ES2422297T3 publication Critical patent/ES2422297T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/33—Heterocyclic compounds
    • A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
    • A61K31/41—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having five-membered rings with two or more ring hetero atoms, at least one of which being nitrogen, e.g. tetrazole
    • A61K31/415—1,2-Diazoles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Medicinal Chemistry (AREA)
  • Public Health (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epidemiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Catalysts (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Proceso para la sulfinilación de un derivado de pirazol, caracterizado porque el 5-amino-1-[2,6-dicloro-4-(trifluorometil) fenil]-1H-pirazol-3-carbonitrilo (II) se hace reaccionar con un agente de sulfinilación S en presencia deal menos un complejo de amina-ácido, en donde la amina o las aminas se seleccionan de aminas secundarias y/oterciarias y el o los ácidos se seleccionan de ácido clorhídrico, ácido fluorhídrico, ácido bromhídrico, ácidoyodhídrico, ácido p-toluenosulfónico, ácido bencenosulfónico, ácido 4-etilbencenosulfónico, ácido 4-clorobencenosulfónico, ácido xilenosulfónico, ácido 2,3-dimetilbencenosulfónico, ácido 2,4-dimetilbencenosulfónico,ácido 2,5-dimetilbencenosulfónico, ácido 2,6-dimetilbencenosulfónico, ácido 1-naftalenosulfónico, ácido 2-naftalenosulfónico, mezclas de dos o más de los isómeros del ácido dimetilbencenosulfónico, ácidomesitilenosulfónico, ácido metanosulfónico, ácido canforsulfónico, y ácido trifluorometilsulfónico, y con la adición deun agente de halogenación, en donde S es [CF3S(O)]2O; o CF3S(O)X en donde X significa flúor, cloro, bromo, yodo, un grupo hidroxi, o una sal de metal alcalino o alcalinotérreo del grupo hidroxi; omezclas de estos, en donde la temperatura de la mezcla de reacción en ningún momento exceda 39°C.
ES07822223T 2006-11-10 2007-11-05 Proceso para la sulfinilación de un derivado de pirazol Active ES2422297T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US86517806P 2006-11-10 2006-11-10
US91364607P 2007-04-24 2007-04-24
PCT/EP2007/061894 WO2008055880A1 (en) 2006-11-10 2007-11-05 Process for the sulfinylation of a pyrazole derivative

Publications (1)

Publication Number Publication Date
ES2422297T3 true ES2422297T3 (es) 2013-09-10

Family

ID=38983360

Family Applications (1)

Application Number Title Priority Date Filing Date
ES07822223T Active ES2422297T3 (es) 2006-11-10 2007-11-05 Proceso para la sulfinilación de un derivado de pirazol

Country Status (17)

Country Link
US (1) US20100004307A1 (es)
EP (1) EP2084137B1 (es)
JP (1) JP5450079B2 (es)
KR (1) KR20090081421A (es)
AR (1) AR063648A1 (es)
AU (1) AU2007316721B2 (es)
BR (1) BRPI0718758A2 (es)
CA (1) CA2667565A1 (es)
DK (1) DK2084137T3 (es)
EA (1) EA016304B1 (es)
ES (1) ES2422297T3 (es)
IL (1) IL198261A0 (es)
MX (1) MX2009004259A (es)
NZ (1) NZ576638A (es)
PL (1) PL2084137T3 (es)
WO (1) WO2008055880A1 (es)
ZA (1) ZA200903973B (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1968578A4 (en) 2005-12-14 2011-02-23 Makhteshim Chem Works Ltd POLYMORPHIC AND AMORPHOUS FORMS OF 5-AMINO-L- [2,6-DICHLORO-4- (TRIFLUOROMETHYL) PHENYL] -4- [(TRIFLUOROMETHYL) SULFINYL] -IH-PYRAZOLE-3-CARBONITRIL
NZ576593A (en) 2006-11-10 2011-12-22 Basf Se Process for the sulfinylation of a pyrazole derivative
EA200900629A1 (ru) 2006-11-10 2009-10-30 Басф Се Способ сульфинилирования производной пиразола
FR2925493B1 (fr) * 2007-12-19 2011-09-30 Vetoquinol Procede de preparation du fipronil et d'analogues de celui-ci.
MX2011003455A (es) 2008-10-02 2011-05-23 Merial Ltd Metodo para producir y purificar acido trifluorometanosulfinico.
CN104926729B (zh) * 2014-03-18 2018-01-19 上海泰禾国际贸易有限公司 一种合成氟虫腈的方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2716453B1 (fr) * 1994-02-22 1996-03-29 Rhone Poulenc Agrochimie Procédé de sulfinylation de composés hétérocycliques.
DE3568455D1 (en) * 1984-05-23 1989-04-06 Rhone Poulenc Chimie Detergent compositions containing copolymers based on polyoxyethylene and polyoxyalkylene used as antisoil redeposition agents, and process for their preparation
GB8713768D0 (en) * 1987-06-12 1987-07-15 May & Baker Ltd Compositions of matter
ATE208752T1 (de) * 1996-08-01 2001-11-15 Rhone Poulenc Chimie Verfahren zum anbringen einer substituierten difluormethylgruppe
JPH11246555A (ja) * 1997-10-31 1999-09-14 Sumitomo Chem Co Ltd フッ素置換ベンゾヘテロ環化合物
JP2001220386A (ja) * 1999-11-30 2001-08-14 Takeda Chem Ind Ltd オキサジアゾリン誘導体の製造方法
JP2002020364A (ja) * 2000-07-06 2002-01-23 Konica Corp スルフィン酸ナトリウム、スルフィン酸カリウムの製造方法およびそれらを用いた写真用カプラーの製造方法
EP1331222A1 (en) * 2002-01-28 2003-07-30 Virbac S.A. Environment friendly reagents and process for halogenoalkylsulfinylation of organic compounds
CN1176078C (zh) * 2002-03-27 2004-11-17 江苏省农药研究所 带三氟甲基亚磺酰基的吡唑类化合物的亚磺酰化方法
MX2011003455A (es) * 2008-10-02 2011-05-23 Merial Ltd Metodo para producir y purificar acido trifluorometanosulfinico.

Also Published As

Publication number Publication date
EA016304B1 (ru) 2012-04-30
EP2084137A1 (en) 2009-08-05
AR063648A1 (es) 2009-02-04
EA200900628A1 (ru) 2009-12-30
AU2007316721B2 (en) 2013-05-09
BRPI0718758A2 (pt) 2013-12-03
IL198261A0 (en) 2009-12-24
PL2084137T3 (pl) 2013-11-29
ZA200903973B (en) 2012-02-29
DK2084137T3 (da) 2013-07-22
AU2007316721A1 (en) 2008-05-15
US20100004307A1 (en) 2010-01-07
MX2009004259A (es) 2009-05-05
CA2667565A1 (en) 2008-05-15
WO2008055880A1 (en) 2008-05-15
KR20090081421A (ko) 2009-07-28
JP5450079B2 (ja) 2014-03-26
EP2084137B1 (en) 2013-04-24
JP2010509273A (ja) 2010-03-25
NZ576638A (en) 2011-12-22

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