ES2401799R1 - Procedimiento para la preparacion de un aditivo que comprende particulas de tio2 soportadas y dispersas - Google Patents

Procedimiento para la preparacion de un aditivo que comprende particulas de tio2 soportadas y dispersas

Info

Publication number
ES2401799R1
ES2401799R1 ES201131372A ES201131372A ES2401799R1 ES 2401799 R1 ES2401799 R1 ES 2401799R1 ES 201131372 A ES201131372 A ES 201131372A ES 201131372 A ES201131372 A ES 201131372A ES 2401799 R1 ES2401799 R1 ES 2401799R1
Authority
ES
Spain
Prior art keywords
additive
preparation
support
tio2 particles
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES201131372A
Other languages
English (en)
Other versions
ES2401799B1 (es
ES2401799A2 (es
Inventor
Berenguer Antonio Alvarez
Barrasa Aurora Maria Casado
Cubillo Antonio Esteban
Moreno Javier Gravalos
Rojo Antonio Jose Sanchez
Rome Julio Santaren
Agullo Jose Vera
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tolsa SA
Acciona Construccion SA
Original Assignee
Tolsa SA
Acciona Infraestructuras SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tolsa SA, Acciona Infraestructuras SA filed Critical Tolsa SA
Priority to ES201131372A priority Critical patent/ES2401799B1/es
Priority to PCT/EP2012/065410 priority patent/WO2013020972A2/en
Priority to JP2014524362A priority patent/JP5973569B2/ja
Priority to EP12743737.4A priority patent/EP2753423A2/en
Priority to US14/237,716 priority patent/US9724672B2/en
Publication of ES2401799A2 publication Critical patent/ES2401799A2/es
Publication of ES2401799R1 publication Critical patent/ES2401799R1/es
Application granted granted Critical
Publication of ES2401799B1 publication Critical patent/ES2401799B1/es
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063Titanium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16Clays or other mineral silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/19Catalysts containing parts with different compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39Photocatalytic properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/393Metal or metal oxide crystallite size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009Preparation by separation, e.g. by filtration, decantation, screening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0207Pretreatment of the support
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0209Impregnation involving a reaction between the support and a fluid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • B01J37/0217Pretreatment of the substrate before coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • B01J37/0221Coating of particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30Ion-exchange
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10Coating or impregnating
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10Coating or impregnating
    • C04B20/1055Coating or impregnating with inorganic materials
    • C04B20/1066Oxides, Hydroxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0081Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
    • C04B2111/00827Photocatalysts
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2038Resistance against physical degradation
    • C04B2111/2069Self cleaning materials, e.g. using lotus effect

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Toxicology (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Catalysts (AREA)
  • Civil Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

Procedimiento para la preparación de un aditivo que comprende partículas de TiO2 soportadas y dispersas. Proceso para la preparación de un aditivo que comprende partículas de TiO2 dispersas sobre un soporte del tipo de los filosilicatos pseudolaminares que comprende la dispersión en agua del soporte, la activación ácida del soporte y la dispersión en alta cizalla del soporte con las partículas de TiO2. Uso de las partículas obtenidas por este procedimiento como aditivos con actividad fotocatalítica para purificación y desinfección de aguas, para purificación de corrientes gaseosas contaminadas y para proporcionar a los materiales, en particular a los materiales de construcción, propiedades de autolimpieza, biocida, desodorización y/o descontaminación en presencia de aire y luz ultravioleta.
ES201131372A 2011-08-08 2011-08-08 Procedimiento para la preparación de un aditivo que comprende partículas de tio2 soportadas y dispersas Expired - Fee Related ES2401799B1 (es)

Priority Applications (5)

Application Number Priority Date Filing Date Title
ES201131372A ES2401799B1 (es) 2011-08-08 2011-08-08 Procedimiento para la preparación de un aditivo que comprende partículas de tio2 soportadas y dispersas
PCT/EP2012/065410 WO2013020972A2 (en) 2011-08-08 2012-08-07 Process for the preparation of an additive comprising supported and dispersed tio2 particles
JP2014524362A JP5973569B2 (ja) 2011-08-08 2012-08-07 担持され且つ分散されているTiO2粒子を含む添加剤を調製する方法
EP12743737.4A EP2753423A2 (en) 2011-08-08 2012-08-07 Process for the preparation of an additive comprising supported and dispersed tio2 particles
US14/237,716 US9724672B2 (en) 2011-08-08 2012-08-07 Process for the preparation of an additive comprising supported and dispersed TiO2 particles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES201131372A ES2401799B1 (es) 2011-08-08 2011-08-08 Procedimiento para la preparación de un aditivo que comprende partículas de tio2 soportadas y dispersas

Publications (3)

Publication Number Publication Date
ES2401799A2 ES2401799A2 (es) 2013-04-24
ES2401799R1 true ES2401799R1 (es) 2013-08-05
ES2401799B1 ES2401799B1 (es) 2014-06-03

Family

ID=46634152

Family Applications (1)

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ES201131372A Expired - Fee Related ES2401799B1 (es) 2011-08-08 2011-08-08 Procedimiento para la preparación de un aditivo que comprende partículas de tio2 soportadas y dispersas

Country Status (5)

Country Link
US (1) US9724672B2 (es)
EP (1) EP2753423A2 (es)
JP (1) JP5973569B2 (es)
ES (1) ES2401799B1 (es)
WO (1) WO2013020972A2 (es)

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WO2014052074A2 (en) * 2012-09-26 2014-04-03 3M Innovative Properties Company Coatable composition, photocatalytic articles, and methods of making the same
WO2014106143A1 (en) * 2012-12-28 2014-07-03 Univation Technologies, Llc Supported catalyst with improved flowability
CN103816861B (zh) * 2014-03-19 2016-04-06 盐城工学院 凹凸棒黏土脱硫剂的准备方法
JP5851578B1 (ja) * 2014-08-27 2016-02-03 シャープ株式会社 光触媒組成物およびその製造方法
CN104310891B (zh) * 2014-10-15 2016-06-29 浙江大学宁波理工学院 一种生态型纳米光催化全再生混凝土
SG11201703554RA (en) * 2014-11-03 2017-05-30 Univ Nanyang Tech Engineered self-cleaning cementitious composites
CN104525172A (zh) * 2014-11-05 2015-04-22 朱忠良 一种改性覆炭氧化钛-高岭土载体的制备方法
CN106540684B (zh) * 2016-12-06 2019-05-10 北京国电龙源环保工程有限公司 高活性蜂窝式scr催化剂的制备方法
ES2705088B2 (es) 2017-09-20 2020-03-30 Liderkit S L Nuevo gel-coat aditivado con particulas de dioxido de titanio y alumina
WO2019079731A1 (en) * 2017-10-19 2019-04-25 Kevern John T GRANULAR FILTRATION MEDIUM
CN109225206A (zh) * 2018-08-31 2019-01-18 合肥师范学院 一种凹凸棒负载过渡金属氧化物复合材料的制备方法及其应用
KR102201165B1 (ko) * 2018-11-16 2021-01-12 한국생산기술연구원 광촉매 자기세정 내지문성 코팅 용액, 그 제조 방법 및 상기 코팅 용액을 이용한 코팅 방법
IT201900000665A1 (it) * 2019-01-16 2020-07-16 Afon Casa S R L Manufatto edile di arredo urbano per il miglioramento della qualita' dell' aria
CN112007698A (zh) * 2019-05-28 2020-12-01 夏普株式会社 组成物、涂覆方法和多层结构体
CN111646775A (zh) * 2020-05-29 2020-09-11 西安工程大学 一种利用天然凹凸棒石制备薄片分子筛膜支撑体的方法
CN112246271A (zh) * 2020-10-23 2021-01-22 南京信息工程大学 一种凹土基光催化污水处理剂及其制备方法
CN113683247B (zh) * 2021-08-31 2023-04-18 湖南工程学院 一种光和热协同活化海泡石用于处理研磨废水反渗透浓水的方法
CN115959866A (zh) * 2022-09-30 2023-04-14 中建商品混凝土有限公司 一种采用铝基复合材料水解副产物的自清洁混凝土及其制备方法
PL442761A1 (pl) * 2022-11-09 2024-05-13 Politechnika Gdańska Zewnętrzna warstwa powłokotwórcza oraz dwa sposoby wytwarzania zewnętrznej warstwy powłokotwórczej
PL442762A1 (pl) * 2022-11-09 2024-05-13 Politechnika Gdańska Zewnętrzna warstwa powłokotwórcza oraz sposób wytwarzania zewnętrznej warstwy powłokotwórczej

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US9724672B2 (en) 2017-08-08
WO2013020972A3 (en) 2013-07-18
WO2013020972A2 (en) 2013-02-14
US20150290619A1 (en) 2015-10-15
ES2401799A2 (es) 2013-04-24
JP2014521508A (ja) 2014-08-28
JP5973569B2 (ja) 2016-08-23
EP2753423A2 (en) 2014-07-16

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