ES2373987T3 - Separación de oxígeno. - Google Patents
Separación de oxígeno. Download PDFInfo
- Publication number
- ES2373987T3 ES2373987T3 ES07705384T ES07705384T ES2373987T3 ES 2373987 T3 ES2373987 T3 ES 2373987T3 ES 07705384 T ES07705384 T ES 07705384T ES 07705384 T ES07705384 T ES 07705384T ES 2373987 T3 ES2373987 T3 ES 2373987T3
- Authority
- ES
- Spain
- Prior art keywords
- hydrogen
- gas
- hydrocarbon
- catalyst
- free oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 239000001301 oxygen Substances 0.000 title claims abstract description 83
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 83
- 238000000926 separation method Methods 0.000 title description 6
- 239000007789 gas Substances 0.000 claims abstract description 118
- 239000001257 hydrogen Substances 0.000 claims abstract description 91
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 91
- 239000003054 catalyst Substances 0.000 claims abstract description 80
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 76
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 76
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 71
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 69
- 239000000203 mixture Substances 0.000 claims abstract description 38
- 238000006243 chemical reaction Methods 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 25
- 238000002156 mixing Methods 0.000 claims abstract description 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 41
- 238000006073 displacement reaction Methods 0.000 claims description 29
- 150000002431 hydrogen Chemical class 0.000 claims description 22
- 238000002485 combustion reaction Methods 0.000 claims description 21
- 239000003345 natural gas Substances 0.000 claims description 21
- 230000003647 oxidation Effects 0.000 claims description 19
- 238000007254 oxidation reaction Methods 0.000 claims description 19
- 230000015572 biosynthetic process Effects 0.000 claims description 17
- 238000002407 reforming Methods 0.000 claims description 17
- 239000008246 gaseous mixture Substances 0.000 claims description 15
- 238000002453 autothermal reforming Methods 0.000 claims description 10
- 239000010970 precious metal Substances 0.000 claims description 9
- 238000011144 upstream manufacturing Methods 0.000 claims description 9
- 238000000629 steam reforming Methods 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 239000011593 sulfur Substances 0.000 claims description 7
- 239000006096 absorbing agent Substances 0.000 claims description 5
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 5
- 229910052753 mercury Inorganic materials 0.000 claims description 5
- 229910052723 transition metal Inorganic materials 0.000 claims description 5
- 150000003624 transition metals Chemical class 0.000 claims description 5
- 229910052785 arsenic Inorganic materials 0.000 claims description 4
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 239000002574 poison Substances 0.000 claims description 2
- 231100000614 poison Toxicity 0.000 claims description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 15
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
- 229910002091 carbon monoxide Inorganic materials 0.000 description 13
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 10
- 239000003570 air Substances 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 description 8
- 229910052697 platinum Inorganic materials 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000010948 rhodium Substances 0.000 description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 229910052763 palladium Inorganic materials 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 229910002090 carbon oxide Inorganic materials 0.000 description 4
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 4
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000006356 dehydrogenation reaction Methods 0.000 description 4
- 239000003949 liquefied natural gas Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052703 rhodium Inorganic materials 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000003915 liquefied petroleum gas Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000006057 reforming reaction Methods 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 229910026161 MgAl2O4 Inorganic materials 0.000 description 1
- 229910002837 PtCo Inorganic materials 0.000 description 1
- 229910002836 PtFe Inorganic materials 0.000 description 1
- 229910002847 PtSn Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- -1 argon Chemical compound 0.000 description 1
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical compound [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 1
- 229910000070 arsenic hydride Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
- VODBHXZOIQDDST-UHFFFAOYSA-N copper zinc oxygen(2-) Chemical group [O--].[O--].[Cu++].[Zn++] VODBHXZOIQDDST-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003635 deoxygenating effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910001676 gahnite Inorganic materials 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 229910003452 thorium oxide Inorganic materials 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
- B01J8/0457—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being placed in separate reactors
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- C—CHEMISTRY; METALLURGY
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00203—Coils
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00504—Controlling the temperature by means of a burner
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00038—Processes in parallel
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/0004—Processes in series
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1258—Pre-treatment of the feed
- C01B2203/1264—Catalytic pre-treatment of the feed
- C01B2203/127—Catalytic desulfurisation
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1276—Mixing of different feed components
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Industrial Gases (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Gyroscopes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0605232 | 2006-03-16 | ||
| GBGB0605232.8A GB0605232D0 (en) | 2006-03-16 | 2006-03-16 | Oxygen removal |
| PCT/GB2007/050100 WO2007105012A1 (en) | 2006-03-16 | 2007-03-05 | Oxygen removal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2373987T3 true ES2373987T3 (es) | 2012-02-10 |
Family
ID=36292814
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES07705384T Active ES2373987T3 (es) | 2006-03-16 | 2007-03-05 | Separación de oxígeno. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US9017642B2 (enExample) |
| EP (1) | EP1993719B9 (enExample) |
| JP (1) | JP5721310B2 (enExample) |
| CN (1) | CN101394922B (enExample) |
| AT (1) | ATE528070T1 (enExample) |
| AU (1) | AU2007226323B2 (enExample) |
| BR (1) | BRPI0708866A2 (enExample) |
| CA (1) | CA2641183C (enExample) |
| ES (1) | ES2373987T3 (enExample) |
| GB (1) | GB0605232D0 (enExample) |
| NO (1) | NO20083689L (enExample) |
| WO (1) | WO2007105012A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5274802B2 (ja) * | 2006-09-15 | 2013-08-28 | 株式会社日本触媒 | 酸素除去方法 |
| JP5033829B2 (ja) * | 2008-08-27 | 2012-09-26 | 株式会社神鋼環境ソリューション | 消化ガスの脱酸素方法及び装置 |
| EP2336083A1 (en) * | 2009-12-17 | 2011-06-22 | Topsøe Fuel Cell A/S | Gas generator and processes for the conversion of a fuel into an oxygen-depleted gas and/or hydrogen-enriched gas |
| GB201000097D0 (en) * | 2010-01-05 | 2010-12-29 | Johnson Matthey Plc | Apparatus and process for treating natural gas |
| JP5545719B2 (ja) * | 2010-01-28 | 2014-07-09 | 住友精化株式会社 | メタンを主成分とするガスの処理方法および処理装置 |
| CA2709722A1 (en) * | 2010-07-15 | 2012-01-15 | Alakh Prasad | Integrated biogas cleaning a system to remove water, siloxanes, sulfur, oxygen, chlorides, and volatile organic compounds |
| JP5389753B2 (ja) * | 2010-07-27 | 2014-01-15 | 株式会社日立製作所 | 石炭ガス化ガスのｃｏ２分離回収装置 |
| JP2012142173A (ja) * | 2010-12-28 | 2012-07-26 | Jx Nippon Oil & Energy Corp | 燃料電池用脱硫システム、燃料電池用水素製造システム及び燃料電池システム、並びに、炭化水素系燃料の脱硫方法及び水素の製造方法 |
| CN102161924A (zh) * | 2011-01-25 | 2011-08-24 | 任国平 | 一种煤层气用生物质炭低温脱氧法 |
| JP2012207145A (ja) * | 2011-03-30 | 2012-10-25 | Sumitomo Seika Chem Co Ltd | メタンを主成分とするガスの処理方法 |
| JP2012211213A (ja) * | 2011-03-30 | 2012-11-01 | Tokyo Gas Co Ltd | バイオガスの精製方法 |
| CN103160352B (zh) * | 2013-03-11 | 2014-09-03 | 大连天元气体技术有限公司 | 一种含氧煤层气的脱氧方法 |
| US9238601B2 (en) * | 2013-10-15 | 2016-01-19 | Uop Llc | Method for providing oxygen free regeneration gas for natural gas dryers |
| DE102014223759A1 (de) * | 2014-11-20 | 2016-05-25 | Wacker Chemie Ag | Entfernung von Sauerstoff aus Kohlenwasserstoff-haltigen Gasgemischen |
| US11987497B2 (en) * | 2019-12-06 | 2024-05-21 | Palo Alto Research Center Incorporated | Liquid metal condensate catalyzed hydrocarbon pyrolysis |
| WO2023209423A1 (en) * | 2022-04-28 | 2023-11-02 | Kara Technologies Inc. | Method of deoxygenation of a hydrocarbon in the presence of methane-containing gas environment and catalyst structure |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2384065A (en) * | 1941-07-18 | 1945-09-04 | Air Reduction | Purification of gases |
| GB844971A (en) | 1957-11-26 | 1960-08-17 | Johnson Matthey Co Ltd | Improvements in and relating to the purification of gases or gaseous mixtures |
| NL270250A (enExample) * | 1960-10-19 | |||
| US4181503A (en) * | 1978-10-30 | 1980-01-01 | United Technologies Corporation | Process for alternately steam reforming sulfur containing hydrocarbons that vary in oxygen content |
| NO152209C (no) | 1982-09-13 | 1985-08-28 | Norsk Hydro As | Fremgangsmaate ved pumping og avgassing av vann |
| GB2149391B (en) | 1983-11-10 | 1987-10-07 | Westinghouse Electric Corp | Method for removing dissolved oxygen from aqueous media |
| US4579723A (en) * | 1985-03-28 | 1986-04-01 | The Boc Group, Inc. | Methods for purifying inert gas streams |
| NO158283C (no) | 1986-02-13 | 1988-08-17 | Norsk Hydro As | Fremgangsmaate og anordning for behandling av blandinger vaeske/gass. |
| GB8610196D0 (en) | 1986-04-25 | 1986-05-29 | Ici Plc | Sulphur compounds removal |
| US4755498A (en) * | 1986-04-30 | 1988-07-05 | International Fuel Cells Corporation | Steam reforming catalyst |
| GB8623482D0 (en) | 1986-09-30 | 1986-11-05 | Johnson Matthey Plc | Catalytic generation of hydrogen |
| GB8805447D0 (en) * | 1988-03-08 | 1988-04-07 | British Petroleum Co Plc | Chemical process |
| EP0391839B1 (de) * | 1989-04-05 | 1992-06-03 | GebràDer Sulzer Aktiengesellschaft | Verfahren zum Anfahren eines Prozesses zum Deoxidieren von Wasser, insbesondere von Meerwasser |
| GB9022060D0 (en) | 1990-10-10 | 1990-11-21 | Ici Plc | Mercury removal |
| US5204075A (en) * | 1991-05-30 | 1993-04-20 | The Boc Group, Inc. | Process for the purification of the inert gases |
| US5446232A (en) * | 1994-02-14 | 1995-08-29 | Occidental Chemical Corporation | Removing oxygen from hydrocarbon gases |
| FR2731693B1 (fr) * | 1995-03-16 | 1997-05-23 | Air Liquide | Procede et installation de generation d'azote pour le traitement thermique |
| US20020007595A1 (en) * | 1997-06-24 | 2002-01-24 | Uli Maier-Roeltgen | Method for reforming hydrocarbons autothermally |
| GB9806199D0 (en) | 1998-03-24 | 1998-05-20 | Johnson Matthey Plc | Catalytic generation of hydrogen |
| TW492891B (en) * | 1998-12-15 | 2002-07-01 | Atmi Ecosys Corp | A scrubbing system and method for point-of-use treatment of effluent gas streams using an aqueous medium and/or gas/liquid contacting article |
| AU768496B2 (en) | 1999-05-03 | 2003-12-11 | Nuvera Fuel Cells | Autothermal reforming system with integrated shift beds, preferential oxidation reactor, auxiliary reactor, and system controls |
| US6280864B1 (en) * | 1999-06-18 | 2001-08-28 | Uop Llc | Control system for providing hydrogen for use with fuel cells |
| AU2001249645A1 (en) * | 2000-03-31 | 2001-10-15 | The Regents Of The University Of Michigan | Transition metal carbides, nitrides and borides and their oxygen containing analogs useful as water gas shift catalysts |
| GB0223300D0 (en) * | 2002-10-08 | 2002-11-13 | Bp Chem Int Ltd | Process |
| NO20030647D0 (no) | 2003-02-10 | 2003-02-10 | Minox Technology As | Fremgangsmåte og anlegg for rensing av produsert vann |
| DE112004000293T5 (de) * | 2003-02-18 | 2006-10-19 | HydrogenSource LLC, South Windsor | Wasserstoffgenerator zur Wasserstoffentschwefelung für Kohlenwasserstoff-Rohrstoffe |
| US20040159584A1 (en) * | 2003-02-18 | 2004-08-19 | Ke Liu | Mini-CPO providing hydrogen for hydrogen desulfurization of hydrocarbon feeds |
-
2006
- 2006-03-16 GB GBGB0605232.8A patent/GB0605232D0/en not_active Ceased
-
2007
- 2007-03-05 AU AU2007226323A patent/AU2007226323B2/en not_active Ceased
- 2007-03-05 AT AT07705384T patent/ATE528070T1/de not_active IP Right Cessation
- 2007-03-05 US US12/293,175 patent/US9017642B2/en not_active Expired - Fee Related
- 2007-03-05 BR BRPI0708866-3A patent/BRPI0708866A2/pt active Search and Examination
- 2007-03-05 CN CN200780007687.XA patent/CN101394922B/zh not_active Expired - Fee Related
- 2007-03-05 JP JP2008558910A patent/JP5721310B2/ja not_active Expired - Fee Related
- 2007-03-05 CA CA2641183A patent/CA2641183C/en not_active Expired - Fee Related
- 2007-03-05 EP EP07705384.1A patent/EP1993719B9/en not_active Not-in-force
- 2007-03-05 ES ES07705384T patent/ES2373987T3/es active Active
- 2007-03-05 WO PCT/GB2007/050100 patent/WO2007105012A1/en not_active Ceased
-
2008
- 2008-08-27 NO NO20083689A patent/NO20083689L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU2007226323A1 (en) | 2007-09-20 |
| BRPI0708866A2 (pt) | 2011-06-14 |
| US9017642B2 (en) | 2015-04-28 |
| AU2007226323B2 (en) | 2011-03-17 |
| ATE528070T1 (de) | 2011-10-15 |
| CN101394922A (zh) | 2009-03-25 |
| EP1993719B9 (en) | 2014-04-16 |
| US20090242462A1 (en) | 2009-10-01 |
| GB0605232D0 (en) | 2006-04-26 |
| JP2009530435A (ja) | 2009-08-27 |
| WO2007105012A1 (en) | 2007-09-20 |
| JP5721310B2 (ja) | 2015-05-20 |
| CN101394922B (zh) | 2012-06-27 |
| NO20083689L (no) | 2008-10-08 |
| CA2641183C (en) | 2013-04-30 |
| EP1993719A1 (en) | 2008-11-26 |
| CA2641183A1 (en) | 2007-09-20 |
| EP1993719B1 (en) | 2011-10-12 |
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