CN101394922B - 除去氧气 - Google Patents

除去氧气 Download PDF

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Publication number
CN101394922B
CN101394922B CN200780007687.XA CN200780007687A CN101394922B CN 101394922 B CN101394922 B CN 101394922B CN 200780007687 A CN200780007687 A CN 200780007687A CN 101394922 B CN101394922 B CN 101394922B
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Prior art keywords
hydrogen
gas
catalyst
free oxygen
vessel
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Expired - Fee Related
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CN200780007687.XA
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English (en)
Chinese (zh)
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CN101394922A (zh
Inventor
P·J·H·卡尼尔
M·福尔斯
R·A·哈登
S·R·埃里斯
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Johnson Matthey PLC
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Johnson Matthey PLC
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
    • B01J8/0457—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being placed in separate reactors
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00203—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00038—Processes in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
    • C01B2203/1264—Catalytic pre-treatment of the feed
    • C01B2203/127—Catalytic desulfurisation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1276—Mixing of different feed components
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Gyroscopes (AREA)
CN200780007687.XA 2006-03-16 2007-03-05 除去氧气 Expired - Fee Related CN101394922B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB0605232.8A GB0605232D0 (en) 2006-03-16 2006-03-16 Oxygen removal
GB0605232.8 2006-03-16
PCT/GB2007/050100 WO2007105012A1 (en) 2006-03-16 2007-03-05 Oxygen removal

Publications (2)

Publication Number Publication Date
CN101394922A CN101394922A (zh) 2009-03-25
CN101394922B true CN101394922B (zh) 2012-06-27

Family

ID=36292814

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200780007687.XA Expired - Fee Related CN101394922B (zh) 2006-03-16 2007-03-05 除去氧气

Country Status (12)

Country Link
US (1) US9017642B2 (enExample)
EP (1) EP1993719B9 (enExample)
JP (1) JP5721310B2 (enExample)
CN (1) CN101394922B (enExample)
AT (1) ATE528070T1 (enExample)
AU (1) AU2007226323B2 (enExample)
BR (1) BRPI0708866A2 (enExample)
CA (1) CA2641183C (enExample)
ES (1) ES2373987T3 (enExample)
GB (1) GB0605232D0 (enExample)
NO (1) NO20083689L (enExample)
WO (1) WO2007105012A1 (enExample)

Families Citing this family (16)

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Publication number Priority date Publication date Assignee Title
JP5274802B2 (ja) * 2006-09-15 2013-08-28 株式会社日本触媒 酸素除去方法
JP5033829B2 (ja) * 2008-08-27 2012-09-26 株式会社神鋼環境ソリューション 消化ガスの脱酸素方法及び装置
EP2336083A1 (en) * 2009-12-17 2011-06-22 Topsøe Fuel Cell A/S Gas generator and processes for the conversion of a fuel into an oxygen-depleted gas and/or hydrogen-enriched gas
GB201000097D0 (en) * 2010-01-05 2010-12-29 Johnson Matthey Plc Apparatus and process for treating natural gas
JP5545719B2 (ja) * 2010-01-28 2014-07-09 住友精化株式会社 メタンを主成分とするガスの処理方法および処理装置
CA2709722A1 (en) * 2010-07-15 2012-01-15 Alakh Prasad Integrated biogas cleaning a system to remove water, siloxanes, sulfur, oxygen, chlorides, and volatile organic compounds
JP5389753B2 (ja) * 2010-07-27 2014-01-15 株式会社日立製作所 石炭ガス化ガスのｃｏ２分離回収装置
JP2012142173A (ja) * 2010-12-28 2012-07-26 Jx Nippon Oil & Energy Corp 燃料電池用脱硫システム、燃料電池用水素製造システム及び燃料電池システム、並びに、炭化水素系燃料の脱硫方法及び水素の製造方法
CN102161924A (zh) * 2011-01-25 2011-08-24 任国平 一种煤层气用生物质炭低温脱氧法
JP2012207145A (ja) * 2011-03-30 2012-10-25 Sumitomo Seika Chem Co Ltd メタンを主成分とするガスの処理方法
JP2012211213A (ja) * 2011-03-30 2012-11-01 Tokyo Gas Co Ltd バイオガスの精製方法
CN103160352B (zh) * 2013-03-11 2014-09-03 大连天元气体技术有限公司 一种含氧煤层气的脱氧方法
US9238601B2 (en) * 2013-10-15 2016-01-19 Uop Llc Method for providing oxygen free regeneration gas for natural gas dryers
DE102014223759A1 (de) * 2014-11-20 2016-05-25 Wacker Chemie Ag Entfernung von Sauerstoff aus Kohlenwasserstoff-haltigen Gasgemischen
US11987497B2 (en) * 2019-12-06 2024-05-21 Palo Alto Research Center Incorporated Liquid metal condensate catalyzed hydrocarbon pyrolysis
WO2023209423A1 (en) * 2022-04-28 2023-11-02 Kara Technologies Inc. Method of deoxygenation of a hydrocarbon in the presence of methane-containing gas environment and catalyst structure

Citations (5)

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GB944207A (en) * 1960-10-19 1963-12-11 Norsk Hydro Elek Sk Kv Aelstof Catalyst for removing oxygen from gaseous mixtures
EP0145262A2 (en) * 1983-11-10 1985-06-19 Westinghouse Electric Corporation Method for removing dissolved oxygen from aqueous media
EP0516401A1 (en) * 1991-05-30 1992-12-02 The Boc Group, Inc. Purification of gas streams
US5446232A (en) * 1994-02-14 1995-08-29 Occidental Chemical Corporation Removing oxygen from hydrocarbon gases
CN1167497C (zh) * 1998-12-15 2004-09-22 高级技术材料公司 现场处理废气流的装置和方法

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US4181503A (en) * 1978-10-30 1980-01-01 United Technologies Corporation Process for alternately steam reforming sulfur containing hydrocarbons that vary in oxygen content
NO152209C (no) 1982-09-13 1985-08-28 Norsk Hydro As Fremgangsmaate ved pumping og avgassing av vann
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GB944207A (en) * 1960-10-19 1963-12-11 Norsk Hydro Elek Sk Kv Aelstof Catalyst for removing oxygen from gaseous mixtures
EP0145262A2 (en) * 1983-11-10 1985-06-19 Westinghouse Electric Corporation Method for removing dissolved oxygen from aqueous media
EP0516401A1 (en) * 1991-05-30 1992-12-02 The Boc Group, Inc. Purification of gas streams
US5446232A (en) * 1994-02-14 1995-08-29 Occidental Chemical Corporation Removing oxygen from hydrocarbon gases
CN1167497C (zh) * 1998-12-15 2004-09-22 高级技术材料公司 现场处理废气流的装置和方法

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Publication number Publication date
AU2007226323A1 (en) 2007-09-20
BRPI0708866A2 (pt) 2011-06-14
ES2373987T3 (es) 2012-02-10
US9017642B2 (en) 2015-04-28
AU2007226323B2 (en) 2011-03-17
ATE528070T1 (de) 2011-10-15
CN101394922A (zh) 2009-03-25
EP1993719B9 (en) 2014-04-16
US20090242462A1 (en) 2009-10-01
GB0605232D0 (en) 2006-04-26
JP2009530435A (ja) 2009-08-27
WO2007105012A1 (en) 2007-09-20
JP5721310B2 (ja) 2015-05-20
NO20083689L (no) 2008-10-08
CA2641183C (en) 2013-04-30
EP1993719A1 (en) 2008-11-26
CA2641183A1 (en) 2007-09-20
EP1993719B1 (en) 2011-10-12

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Granted publication date: 20120627

Termination date: 20170305