ES2267981T3 - Productos de condensacion de acidos hidroxicarboxilicos y glicoles o gricerol. - Google Patents
Productos de condensacion de acidos hidroxicarboxilicos y glicoles o gricerol. Download PDFInfo
- Publication number
- ES2267981T3 ES2267981T3 ES02702660T ES02702660T ES2267981T3 ES 2267981 T3 ES2267981 T3 ES 2267981T3 ES 02702660 T ES02702660 T ES 02702660T ES 02702660 T ES02702660 T ES 02702660T ES 2267981 T3 ES2267981 T3 ES 2267981T3
- Authority
- ES
- Spain
- Prior art keywords
- acid
- glycol
- use according
- glycols
- hydroxycarboxylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002253 acid Substances 0.000 title claims abstract description 31
- 239000007859 condensation product Substances 0.000 title claims description 14
- 150000002334 glycols Chemical class 0.000 title abstract description 11
- 150000007513 acids Chemical class 0.000 title abstract description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 39
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000004753 textile Substances 0.000 claims abstract description 21
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000005977 Ethylene Substances 0.000 claims abstract description 6
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 4
- 239000001257 hydrogen Substances 0.000 claims abstract description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 4
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 52
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 34
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 21
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 15
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 14
- 239000004310 lactic acid Substances 0.000 claims description 12
- 235000014655 lactic acid Nutrition 0.000 claims description 12
- 238000004043 dyeing Methods 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 8
- 239000004952 Polyamide Substances 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 210000002268 wool Anatomy 0.000 claims description 2
- 238000007730 finishing process Methods 0.000 claims 1
- 230000001105 regulatory effect Effects 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 abstract description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 abstract description 2
- 239000007795 chemical reaction product Substances 0.000 abstract description 2
- OYBLYDGMPPILJI-UHFFFAOYSA-N glycerol radical Chemical compound OC[C](O)CO OYBLYDGMPPILJI-UHFFFAOYSA-N 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 description 29
- 239000000047 product Substances 0.000 description 23
- 230000007062 hydrolysis Effects 0.000 description 21
- 238000006460 hydrolysis reaction Methods 0.000 description 21
- 150000001875 compounds Chemical class 0.000 description 20
- 229920000728 polyester Polymers 0.000 description 12
- 238000009833 condensation Methods 0.000 description 9
- 230000005494 condensation Effects 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 235000019253 formic acid Nutrition 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- QERGFXLJLZVCDI-UHFFFAOYSA-N (2-hydroxyacetyl) 2-hydroxyacetate;2-(2-hydroxyethoxy)ethanol Chemical compound OCCOCCO.OCC(=O)OC(=O)CO QERGFXLJLZVCDI-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- -1 alkylene glycols Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000004758 synthetic textile Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PBXCSOPVWKVVJT-UHFFFAOYSA-N 2-(carboxymethoxy)acetic acid ethane-1,2-diol Chemical compound OCCO.OC(=O)COCC(O)=O PBXCSOPVWKVVJT-UHFFFAOYSA-N 0.000 description 1
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical class O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- RMOUBSOVHSONPZ-UHFFFAOYSA-N Isopropyl formate Chemical compound CC(C)OC=O RMOUBSOVHSONPZ-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000434 metal complex dye Substances 0.000 description 1
- 150000005830 nonesterified fatty acids Chemical class 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65125—Compounds containing ester groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
- C07C69/68—Lactic acid esters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Fats And Perfumes (AREA)
- Polyethers (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH4282001 | 2001-03-08 | ||
| CH42801/01 | 2001-03-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2267981T3 true ES2267981T3 (es) | 2007-03-16 |
Family
ID=4514874
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES02702660T Expired - Lifetime ES2267981T3 (es) | 2001-03-08 | 2002-03-06 | Productos de condensacion de acidos hidroxicarboxilicos y glicoles o gricerol. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7186272B2 (https=) |
| EP (1) | EP1370511B1 (https=) |
| JP (1) | JP2004531488A (https=) |
| CN (1) | CN1247518C (https=) |
| AT (1) | ATE337290T1 (https=) |
| BR (1) | BRPI0207853B1 (https=) |
| DE (1) | DE60214143T2 (https=) |
| ES (1) | ES2267981T3 (https=) |
| MX (1) | MXPA03008034A (https=) |
| WO (1) | WO2002070453A1 (https=) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5095613A (en) * | 1990-06-29 | 1992-03-17 | Digital Equipment Corporation | Thin film head slider fabrication process |
| US7168272B2 (en) * | 2003-09-30 | 2007-01-30 | Owens Corning Fiberglas Technology, Inc. | Crimp-free infusible reinforcement fabric |
| DK1756353T3 (da) * | 2004-05-03 | 2011-03-07 | Huntsman Adv Mat Switzerland | Syredonorer til farvning af polyamid |
| WO2012037475A1 (en) | 2010-09-17 | 2012-03-22 | Chemsmart, Llc | Novel compositions and methods |
| US9114328B2 (en) | 2012-05-16 | 2015-08-25 | Eastman Chemical Company | Reactive distillation of a carboxylic acid and a glycol |
| US9040748B2 (en) | 2012-06-08 | 2015-05-26 | Eastman Chemical Company | Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration |
| JP6096105B2 (ja) * | 2013-12-20 | 2017-03-15 | 三菱日立パワーシステムズ株式会社 | チャー回収システムおよびチャー搬送方法 |
| EP4031128A4 (en) | 2019-09-16 | 2023-12-13 | Koda Therapeutics, LLC | ANTIMICROBIAL COMPOUNDS AND COMPOSITIONS AND USES THEREOF |
| JP7160426B1 (ja) * | 2022-08-31 | 2022-10-25 | 竹本油脂株式会社 | 合成繊維用処理剤及び合成繊維 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2158107A (en) * | 1936-03-07 | 1939-05-16 | Carbide & Carbon Chem Corp | Esters of glycol and acylated hydroxy acids |
| US2350964A (en) * | 1940-06-14 | 1944-06-06 | Du Pont | Esters |
| US2573701A (en) * | 1948-06-18 | 1951-11-06 | Edward M Filachione | Polyethylene glycol esters of acyloxycarboxylic acids |
| US3600121A (en) * | 1967-11-27 | 1971-08-17 | Dan River Inc | Method for obtaining level dyeing on cellulosic fibers using polyethylene glycol carboxylic acid esters as unstable retarding agent |
| GB8314180D0 (en) | 1983-05-23 | 1983-06-29 | Sandoz Products Ltd | Organic compounds |
| GB9513585D0 (en) * | 1995-07-04 | 1995-09-06 | Sandoz Ltd | Improvements in or relating to organic compounds |
-
2002
- 2002-03-06 ES ES02702660T patent/ES2267981T3/es not_active Expired - Lifetime
- 2002-03-06 BR BRPI0207853A patent/BRPI0207853B1/pt not_active IP Right Cessation
- 2002-03-06 US US10/469,748 patent/US7186272B2/en not_active Expired - Fee Related
- 2002-03-06 MX MXPA03008034A patent/MXPA03008034A/es active IP Right Grant
- 2002-03-06 WO PCT/IB2002/000745 patent/WO2002070453A1/en not_active Ceased
- 2002-03-06 DE DE60214143T patent/DE60214143T2/de not_active Expired - Lifetime
- 2002-03-06 JP JP2002569774A patent/JP2004531488A/ja active Pending
- 2002-03-06 EP EP02702660A patent/EP1370511B1/en not_active Expired - Lifetime
- 2002-03-06 AT AT02702660T patent/ATE337290T1/de not_active IP Right Cessation
- 2002-03-06 CN CN02806026.1A patent/CN1247518C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20040082808A1 (en) | 2004-04-29 |
| CN1247518C (zh) | 2006-03-29 |
| US7186272B2 (en) | 2007-03-06 |
| BR0207853A (pt) | 2004-03-23 |
| DE60214143D1 (de) | 2006-10-05 |
| DE60214143T2 (de) | 2006-12-14 |
| EP1370511B1 (en) | 2006-08-23 |
| WO2002070453A1 (en) | 2002-09-12 |
| CN1561325A (zh) | 2005-01-05 |
| BRPI0207853B1 (pt) | 2016-04-26 |
| ATE337290T1 (de) | 2006-09-15 |
| MXPA03008034A (es) | 2004-05-24 |
| JP2004531488A (ja) | 2004-10-14 |
| EP1370511A1 (en) | 2003-12-17 |
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