ES2239001T3 - Procedimiento para elaborar espumas de baja densidad, composicion poliolica y sistema de reaccion utiles para el mismo. - Google Patents
Procedimiento para elaborar espumas de baja densidad, composicion poliolica y sistema de reaccion utiles para el mismo.Info
- Publication number
- ES2239001T3 ES2239001T3 ES00927144T ES00927144T ES2239001T3 ES 2239001 T3 ES2239001 T3 ES 2239001T3 ES 00927144 T ES00927144 T ES 00927144T ES 00927144 T ES00927144 T ES 00927144T ES 2239001 T3 ES2239001 T3 ES 2239001T3
- Authority
- ES
- Spain
- Prior art keywords
- polyol
- weight
- content
- functionality
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims description 31
- 239000006260 foam Substances 0.000 title claims description 23
- 238000006243 chemical reaction Methods 0.000 title description 6
- 229920005862 polyol Polymers 0.000 claims abstract description 165
- 150000003077 polyols Chemical class 0.000 claims abstract description 165
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 23
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims abstract description 14
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical group C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 26
- 239000005056 polyisocyanate Substances 0.000 claims description 22
- 229920001228 polyisocyanate Polymers 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 7
- -1 polyoxyethylene Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 239000002671 adjuvant Substances 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 description 25
- 150000002513 isocyanates Chemical class 0.000 description 25
- 229920000642 polymer Polymers 0.000 description 11
- 125000005442 diisocyanate group Chemical group 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 7
- 229920000768 polyamine Chemical class 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 229920005830 Polyurethane Foam Polymers 0.000 description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- 239000011496 polyurethane foam Substances 0.000 description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 150000001718 carbodiimides Chemical class 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 241000894007 species Species 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical group NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 2
- 229920000265 Polyparaphenylene Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000012972 dimethylethanolamine Substances 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000005702 oxyalkylene group Chemical group 0.000 description 2
- 125000006353 oxyethylene group Chemical group 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 2
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical class O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241001425800 Pipa Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 210000000497 foam cell Anatomy 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- DYDNPESBYVVLBO-UHFFFAOYSA-N formanilide Chemical compound O=CNC1=CC=CC=C1 DYDNPESBYVVLBO-UHFFFAOYSA-N 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004620 low density foam Substances 0.000 description 1
- 239000013518 molded foam Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyethers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP99110480 | 1999-05-31 | ||
| EP99110480 | 1999-05-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2239001T3 true ES2239001T3 (es) | 2005-09-16 |
Family
ID=8238269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES00927144T Expired - Lifetime ES2239001T3 (es) | 1999-05-31 | 2000-05-05 | Procedimiento para elaborar espumas de baja densidad, composicion poliolica y sistema de reaccion utiles para el mismo. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6590008B1 (enExample) |
| EP (1) | EP1189963B1 (enExample) |
| JP (1) | JP4467219B2 (enExample) |
| CN (1) | CN1138805C (enExample) |
| AR (1) | AR024091A1 (enExample) |
| AT (1) | ATE291047T1 (enExample) |
| AU (1) | AU4561900A (enExample) |
| BR (1) | BR0011065B1 (enExample) |
| CA (1) | CA2374954C (enExample) |
| DE (1) | DE60018745T2 (enExample) |
| ES (1) | ES2239001T3 (enExample) |
| MX (1) | MXPA01012309A (enExample) |
| WO (1) | WO2000073362A2 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1178061A1 (en) | 2000-08-01 | 2002-02-06 | Huntsman International Llc | Process for preparing a polyurethane material |
| EP1234843A1 (en) | 2001-02-26 | 2002-08-28 | Huntsman International Llc | Process for preparing a flexible polyurethane foam |
| JP4122874B2 (ja) * | 2001-07-18 | 2008-07-23 | 旭硝子株式会社 | ポリオールおよびポリマー分散ポリオールの製造方法 |
| EP1456269B1 (en) * | 2001-11-29 | 2016-07-20 | Huntsman International Llc | Viscoelastic polyurethanes |
| US20050131095A1 (en) * | 2002-08-02 | 2005-06-16 | Jianming Yu | Novel polyols |
| WO2004014976A1 (en) * | 2002-08-02 | 2004-02-19 | Huntsman International Llc | Prepolymer, polyol composition and process for making a flexible foam |
| CA2469986A1 (en) | 2003-06-06 | 2004-12-06 | Hagen, Hans T., Iii | Insulated stud panel and method of making such |
| US7168216B2 (en) * | 2003-06-06 | 2007-01-30 | Hans T. Hagen, Jr. | Insulated stud panel and method of making such |
| US7238730B2 (en) * | 2003-06-26 | 2007-07-03 | Basf Corporation | Viscoelastic polyurethane foam |
| US7338983B2 (en) | 2004-02-10 | 2008-03-04 | World Properties, Inc. | Low density polyurethane foam, method of producing, and articles comprising the same |
| EP1612229A1 (en) * | 2004-06-30 | 2006-01-04 | B & T S.p.A. | Expanded polyurethane material for preparing mattresses |
| US20090012195A1 (en) * | 2007-07-05 | 2009-01-08 | Neff Raymond A | Resin composition for use in forming a polyurethane article with increased comfort |
| DE102007061883A1 (de) * | 2007-12-20 | 2009-06-25 | Bayer Materialscience Ag | Viskoelastischer Polyurethanschaumstoff |
| US8901187B1 (en) | 2008-12-19 | 2014-12-02 | Hickory Springs Manufacturing Company | High resilience flexible polyurethane foam using MDI |
| US8604094B2 (en) | 2008-12-23 | 2013-12-10 | Basf Se | Flexible polyurethane foam and method of producing same |
| US8906975B1 (en) | 2009-02-09 | 2014-12-09 | Hickory Springs Manufacturing Company | Conventional flexible polyurethane foam using MDI |
| JP4920051B2 (ja) * | 2009-02-25 | 2012-04-18 | 株式会社日立製作所 | 酸素燃焼ボイラプラント及び酸素燃焼ボイラプラントの運転方法 |
| BR112012015946A2 (pt) | 2009-12-29 | 2020-09-08 | Dow Global Technologies Llc | mistura de óxidos de polipropileno capeados com oxido de etileno, processo para preparar um poliuretano e processo para preparar uma espuma de poliuretano resiliente e flexivel |
| JP5902719B2 (ja) | 2011-02-14 | 2016-04-13 | ダウ グローバル テクノロジーズ エルエルシー | 低密度ポリウレタンフォーム |
| FR2991686B1 (fr) * | 2012-06-08 | 2015-05-01 | Michelin & Cie | Bandage pneumatique dont la paroi interne est pourvue d'une couche de mousse polyurethane specifique |
| MX2021009009A (es) * | 2019-02-07 | 2021-08-24 | Basf Se | Espumas de poliuretano flexibles con capacidad alta de absorcion de agua. |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3806476A1 (de) * | 1988-03-01 | 1989-09-14 | Bayer Ag | Verfahren zur herstellung von kalthaertenden polyurethan-weichformschaumstoffen mit hervorragenden daempfungseigenschaften |
| DE3942330A1 (de) * | 1989-12-21 | 1991-06-27 | Basf Ag | Verfahren zur herstellung von flexiblen polyurethan-weichschaumstoffen mit viskoelastischen, koerperschalldaempfenden eigenschaften und hierzu verwendbare polyoxyalkylen-polyol-mischungen |
| DE4204395A1 (de) * | 1992-02-14 | 1993-08-19 | Bayer Ag | Verfahren zur herstellung von kalthaertenden polyurethan-weichformschaumstoffen |
| DE4318120C5 (de) * | 1993-06-01 | 2005-05-12 | Basf Ag | Verfahren zur Herstellung von offenzelligen Polyurethan-Weichschaumstoffen |
| DE19742012A1 (de) * | 1997-09-24 | 1999-03-25 | Basf Ag | Temperaturstabile Hartschaumstoffe auf Isocyanatbasis mit geringer Sprödigkeit und niedriger Wärmeleitfähigkeit |
| US6034197A (en) * | 1998-07-27 | 2000-03-07 | Sealed Air Corporation | Polyol blend, multi-component system for producing polyurethane foam, and foam produced thereby |
-
2000
- 2000-05-05 AT AT00927144T patent/ATE291047T1/de not_active IP Right Cessation
- 2000-05-05 US US09/979,849 patent/US6590008B1/en not_active Expired - Lifetime
- 2000-05-05 AU AU45619/00A patent/AU4561900A/en not_active Abandoned
- 2000-05-05 DE DE60018745T patent/DE60018745T2/de not_active Expired - Lifetime
- 2000-05-05 CA CA002374954A patent/CA2374954C/en not_active Expired - Lifetime
- 2000-05-05 JP JP2001500686A patent/JP4467219B2/ja not_active Expired - Fee Related
- 2000-05-05 ES ES00927144T patent/ES2239001T3/es not_active Expired - Lifetime
- 2000-05-05 WO PCT/EP2000/004038 patent/WO2000073362A2/en not_active Ceased
- 2000-05-05 CN CNB008082111A patent/CN1138805C/zh not_active Expired - Lifetime
- 2000-05-05 EP EP00927144A patent/EP1189963B1/en not_active Expired - Lifetime
- 2000-05-05 MX MXPA01012309A patent/MXPA01012309A/es active IP Right Grant
- 2000-05-05 BR BRPI0011065-5A patent/BR0011065B1/pt not_active IP Right Cessation
- 2000-05-24 AR ARP000102537A patent/AR024091A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1138805C (zh) | 2004-02-18 |
| MXPA01012309A (es) | 2002-07-30 |
| JP2003501500A (ja) | 2003-01-14 |
| EP1189963A2 (en) | 2002-03-27 |
| ATE291047T1 (de) | 2005-04-15 |
| AU4561900A (en) | 2000-12-18 |
| AR024091A1 (es) | 2002-09-04 |
| EP1189963B1 (en) | 2005-03-16 |
| WO2000073362A3 (en) | 2001-06-21 |
| CA2374954C (en) | 2008-08-26 |
| DE60018745D1 (de) | 2005-04-21 |
| US6590008B1 (en) | 2003-07-08 |
| CA2374954A1 (en) | 2000-12-07 |
| WO2000073362A2 (en) | 2000-12-07 |
| BR0011065A (pt) | 2002-03-19 |
| CN1353729A (zh) | 2002-06-12 |
| BR0011065B1 (pt) | 2010-12-14 |
| JP4467219B2 (ja) | 2010-05-26 |
| DE60018745T2 (de) | 2006-02-02 |
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