ES2195173T3 - Procedimiento para la polimerizacion de alfa-olefinas, catalizador utilizado en la polimerizacion y su prepacion. - Google Patents

Procedimiento para la polimerizacion de alfa-olefinas, catalizador utilizado en la polimerizacion y su prepacion.

Info

Publication number
ES2195173T3
ES2195173T3 ES97942046T ES97942046T ES2195173T3 ES 2195173 T3 ES2195173 T3 ES 2195173T3 ES 97942046 T ES97942046 T ES 97942046T ES 97942046 T ES97942046 T ES 97942046T ES 2195173 T3 ES2195173 T3 ES 2195173T3
Authority
ES
Spain
Prior art keywords
support
alpha
contact
bringing
donor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97942046T
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English (en)
Inventor
Thomas Garoff
Timo Leinonen
Sirpa Ala-Huikku
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis Technology Oy
Original Assignee
Borealis Technology Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Technology Oy filed Critical Borealis Technology Oy
Application granted granted Critical
Publication of ES2195173T3 publication Critical patent/ES2195173T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

EN LA POLIMERIZACION DE LAS AL - OLEFINAS C3-C12 , LA ACTIVIDAD DEL CATALIZADOR Y LA ISOTACTICIDAD ASI COMO LA MASA MOLECULAR DEL PRODUCTO POLIMERICO PUEDEN SER AÑADIDAS Y MEJORADAS DE MANERA CONTROLADA POR UN NUEVO PROCEDIMIENTO EN EL QUE (A) SE PREPARA UN SISTEMA DE CATALIZADOR POR PUESTA EN CONTACTO DE UN SOPORTE QUE COMPRENDE CLORURO DE MAGNESIO, UN DERIVADO DE ESTE ULTIMO O UN REACTIVO QUE LO FORMA, CON AL MENOS UN TETRACLORURO DE TITANIO O UN REACTIVO QUE LO FORMA, PARA PRODUCIR UN SOPORTE CON TITANIO; POR PUESTA EN CONTACTO DEL SOPORTE CON TITANIO CON AL MENOS UN COMPUESTO METALICO DE LOS GRUPOS 1, 2 O 3 QUE CONTIENE UN ALQUILO C1-C10 Y AC TIVANDO EL TETRACLORURO DE TITANIO EN UN GRUPO DE TITANIO CON ACTIVIDAD CATALITICA, PARA PRODUCIR UN SOPORTE ACTIVADO Y POR PUESTA EN CONTACTO DE UNA SUSTANCIA SELECCIONADA ENTRE DICHO SOPORTE, EL SOPORTE CON TITANIO Y UN SOPORTE ACTIVADO CON AL MENOS UN DONADOR O UN REACTIVO QUE LO FORMA, PARA PRODUCIR UN SISTEMA DE CATALIZADOR; (B) SE PROCEDE A UNA POLIMERIZACION MEDIANTE EL SISTEMA DE CATALIZADOR POR SU PUESTA EN CONTACTO CON AL MENOS UNA AL OLEFINA C3-C12 , DESPUES DE LO CUAL SE FORMAN CADENAS DE POLI - AL -OLEFINAS C3-C12 EN LOS GRUPOS CON TITANIO CON ACTIVIDAD CATALITICA Y PREFERENTEMENTE POR PUESTA EN CONTACTO DE DICHO SISTEMA DE CATALIZADOR, DE DICHA AL - OLEFINA C3-C12 Y DE DICHAS CADENAS DE POLI - AL - OLEFINAS C3-C12 CON HIDROGENO U OTRO AGENTE DE TRANSFERENCIA DE CADENA SIMILAR, DESPUES DE LO CUAL SE FORMA UNA POLI - AL - OLEFINA C3-CSUB,12 TERMINADA POR HIDROGENO O SIMILAR. EN EL PROCEDIMIENTO, LA MEJORA SE OBTIENE DE MANERA QUE, EN LA ETAPA (A), (I) UNA PRIMERA CANTIDAD REGULADA DE UN DONADOR INTERNO MENOS SOLUBLE Y UNA SEGUNDA CANTIDAD REGULADA DE UN DONADOR INTERNO MAS SOLUBLE SON PUESTAS EN LA SUPERFICIE DE DICHO SOPORTE, DEL SOPORTE CON TITANIO O DEL SOPORTE ACTIVADO, PARA PRODUCIR UN PRODUCTO DONADOR INTERNO Y (II) EL PRODUCTO DONADOR INTERNO SE PONE EN CONTACTO CON AL MENOS UN AGENTE DE ELUCION QUE ELUYE EL DONADOR INTERNO MAS SOLUBLE Y CON AL MENOS UN DONADOR EXTERNO O UN REACTIVO QUE LO FORMA, PARA PRODUCIR UN PRODUCTO DONADOR EXTERNO, PRESENTANDO EL SISTEMA DE CATALIZADOR ASI FORMADO AL MENOS GRUPOS DE TITANIO CON ACTIVIDAD CATALITICA, COMPRENDIENDO DICHA PRIMERA CANTIDAD REGULADA DEL DONADOR INTERNO MENOS SOLUBLE Y DICHA SEGUNDA CANTIDAD REGULADA UN DONADOR EXTERNO.
ES97942046T 1996-09-19 1997-09-19 Procedimiento para la polimerizacion de alfa-olefinas, catalizador utilizado en la polimerizacion y su prepacion. Expired - Lifetime ES2195173T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FI963707A FI963707A0 (fi) 1996-09-19 1996-09-19 Foerfarande foer polymerisering av alfa-olefiner, vid polymerisering anvaendbar katalysator och foerfarande foer framstaellning av densamma

Publications (1)

Publication Number Publication Date
ES2195173T3 true ES2195173T3 (es) 2003-12-01

Family

ID=8546692

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97942046T Expired - Lifetime ES2195173T3 (es) 1996-09-19 1997-09-19 Procedimiento para la polimerizacion de alfa-olefinas, catalizador utilizado en la polimerizacion y su prepacion.

Country Status (17)

Country Link
US (1) US6288180B1 (es)
EP (1) EP0927202B1 (es)
JP (1) JP2001503079A (es)
KR (1) KR20000036218A (es)
CN (1) CN1154667C (es)
AT (1) ATE234871T1 (es)
AU (1) AU730744B2 (es)
BR (1) BR9713468A (es)
CA (1) CA2263660A1 (es)
CZ (1) CZ81399A3 (es)
DE (1) DE69720010T2 (es)
EA (1) EA199900313A1 (es)
ES (1) ES2195173T3 (es)
FI (1) FI963707A0 (es)
IL (1) IL128515A0 (es)
PL (1) PL333375A1 (es)
WO (1) WO1998012234A1 (es)

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Also Published As

Publication number Publication date
JP2001503079A (ja) 2001-03-06
BR9713468A (pt) 2000-04-04
CZ81399A3 (cs) 1999-08-11
DE69720010T2 (de) 2003-12-24
WO1998012234A1 (en) 1998-03-26
CN1230968A (zh) 1999-10-06
CN1154667C (zh) 2004-06-23
ATE234871T1 (de) 2003-04-15
DE69720010D1 (de) 2003-04-24
EP0927202A1 (en) 1999-07-07
AU4386097A (en) 1998-04-14
FI963707A0 (fi) 1996-09-19
EP0927202B1 (en) 2003-03-19
CA2263660A1 (en) 1998-03-26
EA199900313A1 (ru) 1999-12-29
US6288180B1 (en) 2001-09-11
KR20000036218A (ko) 2000-06-26
PL333375A1 (en) 1999-12-06
IL128515A0 (en) 2000-01-31
AU730744B2 (en) 2001-03-15

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