DE69612494D1 - Verfahren zur herstellung und anwendung eines geträgerten metallocen-alumoxan katalysators - Google Patents

Verfahren zur herstellung und anwendung eines geträgerten metallocen-alumoxan katalysators

Info

Publication number
DE69612494D1
DE69612494D1 DE69612494T DE69612494T DE69612494D1 DE 69612494 D1 DE69612494 D1 DE 69612494D1 DE 69612494 T DE69612494 T DE 69612494T DE 69612494 T DE69612494 T DE 69612494T DE 69612494 D1 DE69612494 D1 DE 69612494D1
Authority
DE
Germany
Prior art keywords
supported
alumoxane
metallocen
producing
alumoxane catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69612494T
Other languages
English (en)
Other versions
DE69612494T2 (de
Inventor
Abbas Razavi
Guy Debras
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Total Research and Technology Feluy SA
Original Assignee
Fina Research SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Research SA filed Critical Fina Research SA
Publication of DE69612494D1 publication Critical patent/DE69612494D1/de
Application granted granted Critical
Publication of DE69612494T2 publication Critical patent/DE69612494T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69612494T 1995-05-09 1996-05-09 Verfahren zur herstellung und anwendung eines geträgerten metallocen-alumoxan katalysators Expired - Lifetime DE69612494T2 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP95870049 1995-05-09
EP95870050 1995-05-09
EP95870048 1995-05-09
PCT/EP1996/001941 WO1996035729A1 (en) 1995-05-09 1996-05-09 Process for preparing and using a supported metallocene-alumoxane catalyst

Publications (2)

Publication Number Publication Date
DE69612494D1 true DE69612494D1 (de) 2001-05-17
DE69612494T2 DE69612494T2 (de) 2001-09-27

Family

ID=27236998

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69612494T Expired - Lifetime DE69612494T2 (de) 1995-05-09 1996-05-09 Verfahren zur herstellung und anwendung eines geträgerten metallocen-alumoxan katalysators

Country Status (8)

Country Link
EP (1) EP0830395B1 (de)
JP (1) JPH11504970A (de)
AT (1) ATE200496T1 (de)
DE (1) DE69612494T2 (de)
DK (1) DK0830395T3 (de)
ES (1) ES2157445T3 (de)
PT (1) PT830395E (de)
WO (1) WO1996035729A1 (de)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5856255A (en) * 1996-01-22 1999-01-05 Albemarle Corporation Preparation of supported auxiliary catalysts at elevated temperature and pressure in a closed vessel
DE19757563A1 (de) * 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
GB9712663D0 (en) * 1997-06-16 1997-08-20 Borealis As Process
JP2002508025A (ja) * 1997-07-08 2002-03-12 ビーピー ケミカルズ リミテッド 支持重合触媒
EP0969019A1 (de) * 1998-07-02 2000-01-05 Fina Research S.A. Polyolefinenherstellung
EP1041181A1 (de) 1999-03-30 2000-10-04 Fina Research S.A. Polypropylenfasern
US6346586B1 (en) * 1999-10-22 2002-02-12 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
EP1242179B1 (de) * 1999-12-16 2013-05-15 Chevron Phillips Chemical Company LP Organo-metall-verbundkatalysator
JP2004527594A (ja) * 2001-01-12 2004-09-09 アトフイナ・リサーチ・ソシエテ・アノニム メタロセンフィルム樹脂
EP1225201A1 (de) 2001-01-12 2002-07-24 ATOFINA Research Schrumpfbarer Polyethylenfilm
EP1312624A1 (de) * 2001-11-14 2003-05-21 Atofina Research S.A. Metallocene-Filmharz
EP1300240A1 (de) 2001-10-02 2003-04-09 Atofina Research S.A. Glänzende Kunststoffbehälter mit hoher Beständigkeit gegen Rissbildung
EP1357135A1 (de) * 2002-04-26 2003-10-29 ATOFINA Research Rotoverformter Polyäthylen Gegenstand
EP1469104A1 (de) 2003-04-16 2004-10-20 ATOFINA Research Société Anonyme Mit Metallocenkatalysatoren hergestelltes Polyethylen für Faser-Anwendungen
BR112012014851B1 (pt) * 2009-12-18 2019-10-15 Total Petrochemicals Research Feluy Processo para preparar um produto de polietileno bimodal em um único reator de alça
WO2013029767A1 (en) 2011-08-29 2013-03-07 Saudi Basic Industries Corporation Process for preparing di-substituted succinates
RU2015143202A (ru) 2013-03-12 2017-04-17 Сауди Бейсик Индастриз Корпорейшн Бис(2-инденил)металлоценовый комплекс
CN110479377B (zh) * 2019-08-06 2021-11-16 南方医科大学 一种用于4-碘硝基苯和苯乙炔反应的催化剂

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4119343A1 (de) * 1991-06-12 1992-12-17 Basf Ag Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
EP0586167B1 (de) * 1992-09-04 2000-07-12 BP Chemicals Limited Katalysatorzusammensetzung und Verfahren zur Herstellung von Polyolefinen
CA2193882C (en) * 1994-06-24 2005-07-26 Anthony Nicholas Speca Polymerization catalyst systems, their production and use

Also Published As

Publication number Publication date
EP0830395B1 (de) 2001-04-11
WO1996035729A1 (en) 1996-11-14
ES2157445T3 (es) 2001-08-16
DE69612494T2 (de) 2001-09-27
PT830395E (pt) 2001-10-30
JPH11504970A (ja) 1999-05-11
EP0830395A1 (de) 1998-03-25
DK0830395T3 (da) 2001-08-06
ATE200496T1 (de) 2001-04-15

Similar Documents

Publication Publication Date Title
DE69612494T2 (de) Verfahren zur herstellung und anwendung eines geträgerten metallocen-alumoxan katalysators
NO944857L (no) Fluorenyl-inneholdende metallocener, fremgangsmåte for fremstilling derav og fremgangsmåte for polymerisering av olefiner ved anvendelse av metallocenene
DE69603811T2 (de) Träger für Olefinpolymerisationkatalysator, Olefinpolymerisationkatalysator und Verfahren zur Herstellung von Olefinpolymeren
DE68911812D1 (de) Katalysatorbestandteil für Olefinpolymerisation, Verfahren zur Herstellung davon, Olefinpolymerisationskatalysator und Verfahren zur Polymerisation von Olefinen.
CA2124731A1 (en) Metallocenes and Processes Therefor and Therewith
AU3559893A (en) Catalyst for the polymerization of olefins, process for its preparation and its use
ATE162807T1 (de) Verfahren zur gasphasenpolymerisation von alpha- olefinen
HUP0002090A2 (hu) Eljárás blokk-polimer előállítására szabályzott gyökös polimerizációval és az előállított blokk-polimer
ATE258194T1 (de) Katalysatorsysteme und verfahren zur herstellung von polyolefinen mit breiter molekulargewichtverteilung
DE69611554T2 (de) Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten
DE68915616D1 (de) Verfahren zur Herstellung von Ethylen-alpha-Olefin-Elastomeren mit hohem Molekulargewicht unter Anwendung eines Metallocen-Alumoxan-Katalysators.
DE69600892D1 (de) Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren
DE69728677D1 (de) Katalysatorsystem für die (co)polymerisierung von olefinen und verfahren zur herstellung von olefin-(co)polymeren unter verwendung des katalysatorsystems
ATE199018T1 (de) Verfahren zur herstellung von äthylenpolymeren
EP1325926A3 (de) Metallocene
DE69717403D1 (de) Katalysator für die Polymerisation eines Olefins und Verfahren zur Herstellung eines Olefinpolymers
DE59305319D1 (de) Verfahren zur Herstellung eines Trägerkatalysators für die Polymerisation von a-Olefinen
ATE234869T1 (de) Verfahren zur herstellung von geträgertem metallocen-katalysator und olefin- polymerisationsverfahren unter dessen verwendung
ATE132157T1 (de) Verfahren zur herstellung von metallocenen
ATE166077T1 (de) Metallocen(co)polymere, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren; metallocene hierfür.
NO20002319L (no) FremgangsmÕte for fremstilling av fulven-metallkomplekser
DE69014737D1 (de) Katalysator, Verfahren zur Herstellung desselben und Olefinpolymerisation unter Anwendung desselben.
CA2234188A1 (en) Heat treatment of ziegler-natta catalysts to increase activity in solution polymerization process
ATE199247T1 (de) Verfahren zur herstellung von 1-aryl-1- cyanocyclobutan-derivaten
DE69504237D1 (de) Titankatalysator-Feststoff für Olefinpolymerisation, Verfahren zur Herstellung desselben, Olefinpolymerisationskatalysator und Verfahren zur Olefinpolymerisation

Legal Events

Date Code Title Description
8364 No opposition during term of opposition