ES2192046T3 - Complejos organometalicos que comprenden carbenos heterociclicos cationicos. - Google Patents

Complejos organometalicos que comprenden carbenos heterociclicos cationicos.

Info

Publication number
ES2192046T3
ES2192046T3 ES99918055T ES99918055T ES2192046T3 ES 2192046 T3 ES2192046 T3 ES 2192046T3 ES 99918055 T ES99918055 T ES 99918055T ES 99918055 T ES99918055 T ES 99918055T ES 2192046 T3 ES2192046 T3 ES 2192046T3
Authority
ES
Spain
Prior art keywords
carbens
heterociclic
include cationic
integer
organometal complexes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99918055T
Other languages
English (en)
Inventor
Guy Bertrand
Lutz Stelzig
Olivier Guerret
Christophe Buron
Heinz Gornitzka
Paolo Burattin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Polyamide Intermediates SAS
Original Assignee
Rhodia Polyamide Intermediates SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Polyamide Intermediates SAS filed Critical Rhodia Polyamide Intermediates SAS
Application granted granted Critical
Publication of ES2192046T3 publication Critical patent/ES2192046T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C07F15/045—Nickel compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006—Palladium compounds
    • C07F15/0066—Palladium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Complejos organometálicos que comprenden carbenos heterocíclicos, caracterizados porque responden a la fórmula general (I): [(Z+X~)mMLn] Y (I) en la cual: - Z+ representa un ion 1, 2, 4-triazolio-5-ilideno del que al menos una parte de los átomos del ciclo están sustituidos por radicales hidrocarbonados, - L representa un ligando que puede ser iónico o neutro, - M representa un metal elegido entre los elementos de transición de los grupos 1b, 2b, 3b, 4b, 5b, 7b y 8 de la Clasificación Periódica de los Elementos, - X- representa un anión orgánico o mineral, - m representa un número entero de 1 a 6, - n representa un número entero de 0 a 5, - la suma de m y n es igual o inferior a 6, - Y representa un anión o un catión de tal manera que el complejo metálico sea eléctricamente neutro.
ES99918055T 1998-05-20 1999-05-11 Complejos organometalicos que comprenden carbenos heterociclicos cationicos. Expired - Lifetime ES2192046T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9806558A FR2778916B1 (fr) 1998-05-20 1998-05-20 Nouveaux complexes organometalliques comprenant des carbenes heterocycliques cationiques et leur procede de preparation

Publications (1)

Publication Number Publication Date
ES2192046T3 true ES2192046T3 (es) 2003-09-16

Family

ID=9526677

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99918055T Expired - Lifetime ES2192046T3 (es) 1998-05-20 1999-05-11 Complejos organometalicos que comprenden carbenos heterociclicos cationicos.

Country Status (18)

Country Link
US (1) US6492525B1 (es)
EP (1) EP1080098B1 (es)
JP (1) JP3599669B2 (es)
KR (1) KR100450102B1 (es)
CN (1) CN1152037C (es)
BR (1) BR9910631A (es)
CA (1) CA2333186A1 (es)
CZ (1) CZ20004301A3 (es)
DE (1) DE69906723T2 (es)
ES (1) ES2192046T3 (es)
FR (1) FR2778916B1 (es)
PL (1) PL344286A1 (es)
RU (1) RU2188202C1 (es)
SK (1) SK17572000A3 (es)
TW (1) TWI227714B (es)
UA (1) UA57142C2 (es)
WO (1) WO1999060004A1 (es)
ZA (1) ZA200006724B (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2813081B1 (fr) * 2000-08-17 2005-12-23 Rhodia Chimie Sa Procede de preparation d'huiles silicones par hydrosilylation de synthons contenant au moins un cycle hydrocarbone dans lequel est inclus un atome d'oxygene en presence d'un complexe metallique catalytique
US6843923B2 (en) * 2001-08-03 2005-01-18 Canadus Technologies Llc Compositions for removing metal ions from aqueous process solutions and methods of use thereof
EP1568702A4 (en) * 2002-11-12 2008-08-06 Zakrytoe Aktsionernoe Obschest Palladium Complexes with Heterocyclic Ligands
US6911546B2 (en) * 2002-12-26 2005-06-28 International Business Machines Corporation Catalytic depolymerization of polymers containing electrophilic linkages using nucleophilic reagents
US20080267867A1 (en) * 2003-09-05 2008-10-30 Youngs Wiley J Metal Complexes of N-Heterocyclic Carbenes as Radiopharmaceuticals and Antibiotics
US8519146B2 (en) * 2004-09-07 2013-08-27 The University Of Akron Metal complexes of N-heterocyclic carbenes as antibiotics
US8648205B2 (en) * 2003-09-05 2014-02-11 The University Of Akron Metal complexes of N-heterocyclic carbenes
DE102004060247A1 (de) * 2004-12-15 2006-06-29 Studiengesellschaft Kohle Mbh Neue N-heterocyclische Carbene und ihre Anwendung in der Katalyse
WO2007148334A1 (en) 2006-06-20 2007-12-27 Ben-Gurion University Of The Negev Research And Development Authority Amphiphilic peptides and hydrogel matrices thereof for bone repair
EA010431B1 (ru) * 2006-08-17 2008-08-29 Общество С Ограниченной Ответственностью "Радифенс" Координационное соединение палладия и способ его получения
US20100016621A1 (en) * 2006-09-28 2010-01-21 Yugen Zhang Hydrosilylation
CN102027001A (zh) * 2007-06-20 2011-04-20 新加坡科技研究局 N-杂环卡宾金属环催化剂和方法
US9457056B2 (en) * 2007-12-04 2016-10-04 Ben-Gurion University Of The Negev Research And Development Authority Peptides comprising alternating hydrophobic and anionic amino acids for treatment of osteoporosis
WO2011146155A2 (en) * 2010-02-12 2011-11-24 The Regents Of The University Of California Organo-metallic frameworks derived from carbenophilic metals and method of making same
GB201009656D0 (en) * 2010-06-09 2010-07-21 Univ St Andrews Carboxylation catalysts
CN102503963B (zh) * 2011-09-13 2014-04-23 江西师范大学 一种锌金属-有机配位聚合物及其制备方法
CN103833652A (zh) * 2012-11-26 2014-06-04 海洋王照明科技股份有限公司 三氮唑类离子液体及其制备方法和应用
CN104098607B (zh) * 2014-07-07 2016-04-20 苏州大学 含三环己基膦的单膦单氮杂环卡宾镍(ii)配合物及其应用
JP6515930B2 (ja) 2014-08-12 2019-05-22 国立大学法人九州大学 ヒドロシリル化反応触媒
KR102443609B1 (ko) 2014-08-12 2022-09-15 고쿠리쓰다이가쿠호진 규슈다이가쿠 하이드로실릴화 반응 촉매
JP6761997B2 (ja) 2014-08-19 2020-09-30 国立大学法人九州大学 ヒドロシリル化鉄触媒
JP6620823B2 (ja) 2016-01-22 2019-12-18 信越化学工業株式会社 新規イソシアニド化合物及びヒドロシリル化反応触媒
DE102016206303A1 (de) * 2016-04-14 2017-10-19 Technische Universität Berlin Katalysator zur Hydroformylierung von Olefinen und dessen Verwendung
CN106140299A (zh) * 2016-05-23 2016-11-23 杭州师范大学 一种羧酸金属盐-n-杂环卡宾铑配合物一体化催化剂及其制备方法与应用
FR3058140A1 (fr) * 2016-10-27 2018-05-04 Universite Paris-Sud Catalyseurs supportes cycliques
CN109939737B (zh) * 2019-03-07 2021-02-23 清华大学 卡宾钴催化剂、其制备方法及其在催化氢化醛和酮化合物中的应用

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2847441A1 (de) * 1978-11-02 1980-05-22 Basf Ag Imidazol-kupferkomplexverbindungen
DE4447070A1 (de) * 1994-12-29 1996-07-04 Hoechst Ag Komplexverbindungen der Lanthanoiden mit heterocyclischen Carbenen
DE4447066A1 (de) * 1994-12-29 1996-07-04 Hoechst Ag Heterocyclische Carbene enthaltende Metallkomplexverbindungen
DE19610908A1 (de) * 1996-03-20 1997-09-25 Hoechst Ag Verfahren zur Herstellung heterocyclischer Carbene
DE19611629A1 (de) * 1996-03-25 1997-10-02 Hoechst Ag Heterocyclische Carbene enthaltende Metallkomplexe als Katalysatoren für C-C-Verknüpfungen

Also Published As

Publication number Publication date
EP1080098B1 (fr) 2003-04-09
PL344286A1 (en) 2001-10-22
JP2002515507A (ja) 2002-05-28
UA57142C2 (uk) 2003-06-16
CA2333186A1 (fr) 1999-11-25
FR2778916B1 (fr) 2000-06-30
CN1152037C (zh) 2004-06-02
KR20020005366A (ko) 2002-01-17
US6492525B1 (en) 2002-12-10
DE69906723D1 (de) 2003-05-15
DE69906723T2 (de) 2004-02-05
WO1999060004A1 (fr) 1999-11-25
KR100450102B1 (ko) 2004-09-24
FR2778916A1 (fr) 1999-11-26
CN1306538A (zh) 2001-08-01
SK17572000A3 (sk) 2001-08-06
CZ20004301A3 (cs) 2001-09-12
BR9910631A (pt) 2001-01-30
RU2188202C1 (ru) 2002-08-27
TWI227714B (en) 2005-02-11
JP3599669B2 (ja) 2004-12-08
EP1080098A1 (fr) 2001-03-07
ZA200006724B (en) 2002-10-30

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