ES2191184T3 - Sistemas cataliticos de metales de transicion ultimos soportados. - Google Patents

Sistemas cataliticos de metales de transicion ultimos soportados.

Info

Publication number
ES2191184T3
ES2191184T3 ES97930038T ES97930038T ES2191184T3 ES 2191184 T3 ES2191184 T3 ES 2191184T3 ES 97930038 T ES97930038 T ES 97930038T ES 97930038 T ES97930038 T ES 97930038T ES 2191184 T3 ES2191184 T3 ES 2191184T3
Authority
ES
Spain
Prior art keywords
transition metal
phase polymerization
systems
catalytic systems
metal catalytic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97930038T
Other languages
English (en)
Inventor
George Alan Vaughan
Jo Ann Marie Canich
Phillip T Matsunaga
David Edward Gindelberger
Kevin Richard Squire
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Application granted granted Critical
Publication of ES2191184T3 publication Critical patent/ES2191184T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene

Abstract

LA INVENCION ABARCA SISTEMAS CATALIZADORES DEL TIPO DE METAL DE TRANSICION RETARDADA, INMOVILIZADOS SOBRE SOPORTES SOLIDOS, Y A SU USO EN PROCESOS DE POLIMERIZACION HETEROGENEA, PARTICULARMENTE EN LA POLIMERIZACION EN FASE GASEOSA DE MONOMEROS DE OLEFINA. ENTRE LAS REALIZACIONES PREFERIDAS SE INCLUYEN UN SISTEMA CATALIZADOR DE METAL DE TRANSICION RETARDADA QUE COMPRENDE UN COMPLEJO DE METALES DE LOS GRUPOS 9, 10 U 11, ESTABILIZADOS POR UNA ESTRUCTURA DE LIGANDO BIDENTADO, INMOVILIZADA SOBRE UN SOPORTE DE PARTICULAS SOLIDAS Y POROSAS DE UN METAL O UN METALOIDE, PARTICULARMENTE LOS QUE COMPRENDEN SILICE. EL PROCESO DE POLIMERIZACION EN FASE GASEOSA DE LOS MONOMEROS DE OLEFINA COMPRENDE PONER UNA O MAS OLEFINAS EN CONTACTO CON ESTOS SISTEMAS CATALIZADORES EN CONDICIONES DE POLIMERIZACION EN FASE GASEOSA.
ES97930038T 1996-06-17 1997-06-17 Sistemas cataliticos de metales de transicion ultimos soportados. Expired - Lifetime ES2191184T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2009596P 1996-06-17 1996-06-17

Publications (1)

Publication Number Publication Date
ES2191184T3 true ES2191184T3 (es) 2003-09-01

Family

ID=21796718

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97930038T Expired - Lifetime ES2191184T3 (es) 1996-06-17 1997-06-17 Sistemas cataliticos de metales de transicion ultimos soportados.

Country Status (9)

Country Link
EP (2) EP0907665B1 (es)
JP (1) JP4359658B2 (es)
CN (1) CN1128818C (es)
AU (1) AU721921B2 (es)
CA (1) CA2257796C (es)
DE (1) DE69718642T2 (es)
ES (1) ES2191184T3 (es)
HU (1) HUP0003699A3 (es)
WO (1) WO1997048736A1 (es)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1113900C (zh) 1996-06-17 2003-07-09 埃克森美孚化学专利公司 用于烯烃聚合的混合过渡金属催化剂体系及用其聚合烯属不饱和单体的方法
US6812184B1 (en) 1996-06-17 2004-11-02 Exxonmobil Chemical Patents Inc. Supported late transition metal catalyst systems
JP2000515195A (ja) * 1996-07-23 2000-11-14 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー オレフィンに対する重合法
US6660677B1 (en) 1997-03-10 2003-12-09 Eastman Chemical Company Supported group 8-10 transition metal olefin polymerization catalysts
US6103658A (en) 1997-03-10 2000-08-15 Eastman Chemical Company Olefin polymerization catalysts containing group 8-10 transition metals, processes employing such catalysts and polymers obtained therefrom
US6822062B2 (en) 1997-03-10 2004-11-23 Eastman Chemical Company Supported group 8-10 transition metal olefin polymerization catalysts
US6200925B1 (en) 1997-03-13 2001-03-13 Eastman Chemical Company Catalyst compositions for the polymerization of olefins
US6245871B1 (en) 1997-04-18 2001-06-12 Eastman Chemical Company Group 8-10 transition metal olefin polymerization catalysts
MXPA00006074A (es) * 1997-12-19 2003-08-01 Phillips Petroleum Co Catalizadores de niquel diimina con metilalumoxano como cocatalizador, metodo de polimerizacion de olefinas con los mismos y polimeros producidos.
US6511936B1 (en) * 1998-02-12 2003-01-28 University Of Delaware Catalyst compounds with β-diminate anionic ligands and processes for polymerizing olefins
KR20010012693A (ko) * 1998-03-20 2001-02-26 가즈토 도미나가 올레핀 중합체 제조 촉매 및 올레핀 중합체의 제조 방법
US6117959A (en) * 1998-09-02 2000-09-12 Eastman Chemical Company Polyolefin catalysts
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
KR20010040532A (ko) * 1998-12-02 2001-05-15 가즈토 도미나가 올레핀 중합용 촉매 및 이 촉매를 사용하는 올레핀중합체의 제조 방법
ID30159A (id) 1998-12-09 2001-11-08 Goodrich Co B F Polimerisasi adisi dalam cetakan dari monomer-monomer tipe-norbene menggunakan kompleksi logam golongan-10
KR100368184B1 (ko) * 1998-12-11 2003-01-30 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매 및 올레핀의 중합 방법
US6545108B1 (en) 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
DE60014376T2 (de) 1999-02-22 2005-02-24 Eastman Chemical Co., Kingsport Katalysatoren, die n-pyrrolylsubstituierte stickstoffdonoren enthalten
US6620896B1 (en) 1999-02-23 2003-09-16 Eastman Chemical Company Mixed olefin polymerization catalysts, processes employing such catalysts, and polymers obtained therefrom
DE60006082T2 (de) 1999-03-09 2004-07-22 Basell Polyolefine Gmbh Mehrstufiges verfahren zur (co)polymersation von olefinen
US6197714B1 (en) 1999-03-23 2001-03-06 Cryovac, Inc. Supported catalysts and olefin polymerization processes utilizing same
US6197715B1 (en) 1999-03-23 2001-03-06 Cryovac, Inc. Supported catalysts and olefin polymerization processes utilizing same
US6506704B1 (en) * 1999-03-23 2003-01-14 Cryovac, Inc. Olefin polymerization catalysts and processes for making and using same
US6271325B1 (en) 1999-05-17 2001-08-07 Univation Technologies, Llc Method of polymerization
US6281303B1 (en) 1999-07-27 2001-08-28 Eastman Chemical Company Olefin oligomerization and polymerization catalysts
US6300438B1 (en) 1999-10-22 2001-10-09 Univation Technolgies, Llc Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6624107B2 (en) 1999-10-22 2003-09-23 Univation Technologies, Llc Transition metal catalyst compounds having deuterium substituted ligand and catalyst systems thereof
US6380328B1 (en) 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6271323B1 (en) 1999-10-28 2001-08-07 Univation Technologies, Llc Mixed catalyst compounds, catalyst systems and their use in a polymerization process
US6417304B1 (en) 1999-11-18 2002-07-09 Univation Technologies, Llc Method of polymerization and polymer produced therefrom
US6265505B1 (en) 1999-11-18 2001-07-24 Univation Technologies, Llc Catalyst system and its use in a polymerization process
US6300439B1 (en) * 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6281306B1 (en) * 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
GB0003356D0 (en) * 2000-02-14 2000-04-05 Bp Chem Int Ltd Catalyst preparation method
US7056996B2 (en) 2000-02-18 2006-06-06 E. I. Du Pont De Nemours And Company Productivity catalysts and microstructure control
US6579823B2 (en) 2000-02-18 2003-06-17 Eastman Chemical Company Catalysts containing per-ortho aryl substituted aryl or heteroaryl substituted nitrogen donors
US6605677B2 (en) 2000-02-18 2003-08-12 Eastman Chemical Company Olefin polymerization processes using supported catalysts
EP1134236B1 (en) * 2000-03-13 2003-10-01 Repsol Quimica S.A. Bidentate diimine nickel and palladium complexes and polymerization catalysts obtained therefrom
DE60012878T2 (de) * 2000-03-13 2005-08-11 Repsol Quimica S.A. Diiminverbindungen
US6501000B1 (en) 2000-04-04 2002-12-31 Exxonmobil Research And Engineering Company Late transition metal catalyst complexes and oligomers therefrom
US6689928B2 (en) 2000-04-04 2004-02-10 Exxonmobil Research And Engineering Company Transition metal complexes and oligomers therefrom
US6706891B2 (en) 2000-11-06 2004-03-16 Eastman Chemical Company Process for the preparation of ligands for olefin polymerization catalysts
KR20030090751A (ko) * 2001-04-17 2003-11-28 이 아이 듀폰 디 네모아 앤드 캄파니 올레핀 중합화 촉매
CN1160381C (zh) 2001-09-27 2004-08-04 中国石油化工股份有限公司 含双席夫碱配体的烯烃聚合催化剂及制备方法与应用
US6730757B2 (en) 2002-03-08 2004-05-04 Exxonmobil Research And Engineering Company Sulfur-containing and sulfur-nitrogen-containing catalysts for polymerization of olefins and polar monomers
DE60305500T2 (de) 2002-07-17 2006-11-23 Exxonmobil Chemical Patents Inc., Baytown Katalysatoren mit späten übergangsmetallen zur olefinpolymerisierung und oligomerisierung
EP1493755A1 (en) 2003-06-30 2005-01-05 Henkel KGaA Zero valent metal initiated gas-phase deposition polymerization (GDP)
EP2045273A1 (en) * 2007-10-01 2009-04-08 Total Petrochemicals Research Feluy Patent Dept. Method for Supplying Granulated Material to a Polymerisation Reactor
KR101663184B1 (ko) 2009-12-15 2016-10-06 삼성전자주식회사 하이브리드 다공성 물질 및 그의 제조방법
KR101321028B1 (ko) 2010-08-16 2013-10-25 주식회사 엘지화학 후기 전이금속 화합물을 포함하는 담지 촉매 및 이를 이용한 올레핀계 중합체의 제조방법
CN113278098B (zh) * 2021-06-08 2023-03-14 钦州东辰材料科技有限公司 一种复合载体负载的聚烯烃催化剂及其制备方法和应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3686159A (en) * 1969-12-19 1972-08-22 Shell Oil Co Ethylene polymerization
US3759889A (en) * 1970-01-15 1973-09-18 Shell Oil Co Ethylene polymerization in the presence of complex nickel catalysts containing a glycolic acid thioglycolic or thiolactic acid ligand
US4716205A (en) * 1985-10-15 1987-12-29 E. I. Du Pont De Nemours And Company Nickel-catalyzed polymerization of ethylene
US5055552A (en) * 1989-06-14 1991-10-08 Shell Oil Company Polymerization of co/olefin with phosphorus bidentate ligand-solid support reaction product
US5227464A (en) * 1991-03-21 1993-07-13 Shell Oil Company Gas phase polymerization of co/olefin with particular catalyst support
US5237047A (en) * 1991-05-01 1993-08-17 Shell Oil Company Polymerization of co/olefin wth catalyst chemically bound to particles of support
DE69326463T2 (de) * 1992-07-01 2000-05-04 Exxon Chemical Patents Inc Olefinpolymerisationskatalysatoren auf basis von uebergangsmetallen
AU8062898A (en) * 1997-06-09 1998-12-30 E.I. Du Pont De Nemours And Company Polymerization of olefins

Also Published As

Publication number Publication date
CA2257796C (en) 2006-01-24
JP4359658B2 (ja) 2009-11-04
DE69718642D1 (de) 2003-02-27
CN1128818C (zh) 2003-11-26
EP1287891A2 (en) 2003-03-05
CN1225645A (zh) 1999-08-11
JP2002500681A (ja) 2002-01-08
WO1997048736A1 (en) 1997-12-24
HUP0003699A2 (hu) 2001-02-28
AU3396297A (en) 1998-01-07
AU721921B2 (en) 2000-07-20
DE69718642T2 (de) 2003-11-13
CA2257796A1 (en) 1997-12-24
HUP0003699A3 (en) 2008-09-29
EP0907665B1 (en) 2003-01-22
EP1287891A3 (en) 2003-11-26
EP0907665A1 (en) 1999-04-14

Similar Documents

Publication Publication Date Title
ES2191184T3 (es) Sistemas cataliticos de metales de transicion ultimos soportados.
ES2151720T3 (es) Sistemas mejorados de catalizadores de metalocenos soportados.
ES2183029T3 (es) Hidrogenacion de hidrocarburos y catalizador para ello.
ES2132744T3 (es) Sistemas cataliticos de polimerizacion, su produccion y uso.
ES2082233T3 (es) Catalizadores soportados con monociclopentadienilo de metal de transicion para la polimerizacion de olefinas.
ES2108769T3 (es) Dispersion de revestimiento para catalizadores de gases de escape.
AR025163A1 (es) Un procedimiento para preparar olefinas, un sistema catalizador soportado, el uso de un compuesto catalizador del grupo 15 que contiene hafnio y el uso deun sistema catalizador que comprende un compuesto catalizador
ES2118585T3 (es) Procedimiento para la transicion entre catalizadores de polimerizacion incompatibles.
ES2167336T3 (es) Catalizadores ionicos soportados de metal de transicion para la polimerizacion de olefinas.
ES2151279T3 (es) Procesos de polimerizacion a presion elevada con sistemas de catalizadores de metales de transicion retardada
ES2133888T3 (es) Solido catalitico para la (co)polimerizacion de etileno, procedimiento para su preparacion, sistema catalitico para la (co)polimerizacion de etileno y procedimiento de (co)polimerizacion de etileno.
MX9305274A (es) Sistema de catalizador de carbolinacion polimerica
ES2179420T3 (es) Sistema catalitico.
CA2430215A1 (en) Method for preparing a catalyst support and polymerization with supported catalysts
WO2002051884A3 (en) A catalyst system and its use in a polymerization process
AR019906A2 (es) Proceso para la produccion de acetato de vinilo mediante la reaccion de etileno, oxigeno y acido acetico como reactivos.
ES2111360T3 (es) Sistema catalizador de metaloceno soportado.
DK0643719T3 (da) Nukleinsyresekvenser, som koder for eller er komplementære til nukleinsyresekvenser, som koder for interleukin 9-receptor
NO20013476L (no) Fremgangsmåte for parafinisomerisering og heteropolysyrer stöttet på inerte stöttematerialer som isomeriseringskatalysatorer
EP0097047A3 (en) A process for hydrogenating organic compounds by the use of group viii aluminum-silicate catalysts
ES2116036T3 (es) Sistema catalitico para la polimerizacion de olefinas y procedimiento de polimerizacion de al menos una olefina en presencia de este sistema catalitico.
NL189374C (nl) Steunveer in het bijzonder voor het ondersteunen van een verlichtingsarmatuur.
ES2186962T3 (es) Procedimiento para la hidrogenacion de alquinoles con empleo de un catalizador que muestra macroporos.
NO20001423L (no) Organo-aluminiumforbindelser immobilisert pÕ organopolysiloksanmikrogelpartikler
WO2002059160A3 (en) Support materials for use with polymerization catalysts